Catalytic effects in the ammonolysis of vegetable oils View Full Text


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Article Info

DATE

1971-06

AUTHORS

W. L. Kohlhase, E. H. Pryde, J. C. Cowan

ABSTRACT

Catalysts for the ammonolysis of soybean oil are, in order of decreasing overall effectiveness, ammonium acetate, sodium methoxide, 9-amino-nonanoic acid, sodium soyate, ammonium nitrate, alanine, sodium acetate and glycerol. At 125 C, a reaction time of 1 hr and a 30:1 mole ratio of ammonia to ester, ammonium acetate achieved ammonolysis in 16%, 61% and 84% conversions at the respective concentrations of 0.0, 0.1 and 1.0 mole per mole ester groups. Conversion was 98% complete in 4 hr with 1.0 mole. The ammonolysis generally exhibited the expected first order kinetics up to about 80% reaction. More... »

PAGES

265-270

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/bf02638459

DOI

http://dx.doi.org/10.1007/bf02638459

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1044846324


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