N-2-mercaptoethyl amides of fatty acids—A new class of derivatives View Full Text


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Article Info

DATE

1966-01

AUTHORS

A. W. Schwab, J. A. Stolp, L. E. Gast, J. C. Cowan

ABSTRACT

Twelve N-2-mercaptoethyl amides have been prepared by reacting 2-aminoethyl mercaptan with a carboxylic acid in refluxing xylene or toluene. All products were well-defined crystalline compounds except for the dimer acid derivatives. Addition of dithiol amides, prepared from dimer acids and 2-aminoethyl mercaptan, to diolefins gave a new class of potential protective coatings, a polyamide of a dimerized fatty acid with a β-thio linkage. Oxidation of the dithiols gave the corresponding disulfides, another new class of compounds, a polyamide with a β-disulfide structure. Film properties have been obtained with both classes of polymers. Air-dried films were soft and tacky, but baking the films improved hardness. Dry-to-touch times of less than 2 hr at 150C and good alkali resistance were obtained. More... »

PAGES

30-32

References to SciGraph publications

  • 1964-05. The elaidinization of methyl oleate with mercaptans in JOURNAL OF THE AMERICAN OIL CHEMISTS' SOCIETY
  • 1959-07. Device to establish drying conditions for protective coatings at elevated temperatures in JOURNAL OF THE AMERICAN OIL CHEMISTS' SOCIETY
  • Identifiers

    URI

    http://scigraph.springernature.com/pub.10.1007/bf02637274

    DOI

    http://dx.doi.org/10.1007/bf02637274

    DIMENSIONS

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