X-ray diffraction study of some normal alkyl thiolesters of long chain acids View Full Text


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Article Info

DATE

1959-04

AUTHORS

D. A. Lutz, L. P. Witnauer, George S. Sasin, Richard Sasin

ABSTRACT

X-ray diffraction-powder data are reported for 39n-alkyl thiolesters comprising four different series, namely, lauric, myristic, palmitic, and stearic acids. All individual compounds can be identified and distinguished by the X-ray diffraction data. Compounds containing the same total number of carbon atoms in the molecule have the same long and side spacings but differ in the relative intensities of the various orders of the long spacings. The esters crystallize in tilted monomolecular layers. The long spacing is a function of the total carbon content of the molecule and forms two series, one for the odd members and one for the even members. A change in the structure-type definitely occurs in the odd series on decreasing alkyl chain-length below 9 carbons. More... »

PAGES

178-180

References to SciGraph publications

  • <error retrieving object. in <ERROR RETRIEVING OBJECT
  • 1931-01. Alternation in Properties of Long Chain Carbon Compounds in NATURE
  • 1958-05. Thiol esters of long-chain acids and long-chain alkanethiols in JOURNAL OF THE AMERICAN OIL CHEMISTS' SOCIETY
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    http://scigraph.springernature.com/pub.10.1007/bf02636972

    DOI

    http://dx.doi.org/10.1007/bf02636972

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