Sperm oil replacements from selectively hydrogenated soybean and linseed esters: Special lubricants View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

1976-07

AUTHORS

E. W. Bell, J. C. Cowan, L. E. Gast, R. E. Koos

ABSTRACT

Soybean and linseed oils were selectively hydroenated with copper-on-silica gel catalyst. The linolenate content of the oils was reduced to diene and monoene with no appreciable increase in saturates. Hydrogenated soybean oils contained 68–76% monoene, 11–18% diene, 0% conjugated diene and triene, 1–6% conjugatable diene, 0–0.3% conjugatable triene, and 23–40% isolatedtrans double bonds. Hydrogenated linseed oils contained 44–54% monoene, 35–45% diene, 0% conjugated diene and triene, 0–7% conjugatable diene, 0–02% conjugatable triene, and 44–59% isoaltedtrans double bonds. Esters of fatty acids, derived from these selectively hydrogenated oils, were prepared with trimethylolethane, trimethylolpropane, trimethylolbutane, pentaerythritol, ethylene glycol, C18 saturated cyclic alcohols, primary C12–C18 saturated (nC12, nC14, nC16, nC18) alcohol, and primary C16–C18 saturated (nC16, nC18) alcohol blends. Measurements of viscosities and of smoke, flash, and fire points indicate that these esters are possible replacements for sperm oil. Certain of them, after sulfurization, also have potential as extreme pressure lubricant additives. More... »

PAGES

511-517

References to SciGraph publications

  • 1965-05. Selective Hydrogenation of Linolenate Groups in Soya-Bean Oil in NATURE
  • 1972-01. Selective hydrogenation of soybean oil. VI. Copper-on-silica gel catalysts in JOURNAL OF THE AMERICAN OIL CHEMISTS' SOCIETY
  • 1970-03. Selective hydrogenation of soybean oil: V. A Novel copper catalyst with excellent re-use properties in JOURNAL OF THE AMERICAN OIL CHEMISTS' SOCIETY
  • 1968-10. Stereospecific hydrogenation of stearolate with copper catalysts in JOURNAL OF THE AMERICAN OIL CHEMISTS' SOCIETY
  • 1969-02. High oleic oils by selective hydrogenation of soybean oil in JOURNAL OF THE AMERICAN OIL CHEMISTS' SOCIETY
  • 1966-09. Selective hydrogenation of soybean oil. II. Copper-chromium catalysts in JOURNAL OF THE AMERICAN OIL CHEMISTS' SOCIETY
  • 1965-04. Similarity of Repair of Ionizing and Ultra-Violet Radiation Damage in Micrococcus radiodurans in NATURE
  • 1965-10. Preparation of alcohols from cyclic fatty acids in JOURNAL OF THE AMERICAN OIL CHEMISTS' SOCIETY
  • 1967-02. Selective hydrogenation of soybean oil in the presence of copper catalysts in JOURNAL OF THE AMERICAN OIL CHEMISTS' SOCIETY
  • 1972-10. Potential lubricants for continuous casting of steel: polyol esters of partially hydrogenated soybean acids in JOURNAL OF THE AMERICAN OIL CHEMISTS' SOCIETY
  • Identifiers

    URI

    http://scigraph.springernature.com/pub.10.1007/bf02636825

    DOI

    http://dx.doi.org/10.1007/bf02636825

    DIMENSIONS

    https://app.dimensions.ai/details/publication/pub.1012725309


    Indexing Status Check whether this publication has been indexed by Scopus and Web Of Science using the SN Indexing Status Tool
    Incoming Citations Browse incoming citations for this publication using opencitations.net

    JSON-LD is the canonical representation for SciGraph data.

    TIP: You can open this SciGraph record using an external JSON-LD service: JSON-LD Playground Google SDTT

    [
      {
        "@context": "https://springernature.github.io/scigraph/jsonld/sgcontext.json", 
        "about": [
          {
            "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/1117", 
            "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
            "name": "Public Health and Health Services", 
            "type": "DefinedTerm"
          }, 
          {
            "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/11", 
            "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
            "name": "Medical and Health Sciences", 
            "type": "DefinedTerm"
          }
        ], 
        "author": [
          {
            "affiliation": {
              "name": [
                "Northern Regional Research Center, ARS, USDA, 61604, Peoria, Illinois"
              ], 
              "type": "Organization"
            }, 
            "familyName": "Bell", 
            "givenName": "E. W.", 
            "id": "sg:person.015034154213.63", 
            "sameAs": [
              "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.015034154213.63"
            ], 
            "type": "Person"
          }, 
          {
            "affiliation": {
              "name": [
                "Northern Regional Research Center, ARS, USDA, 61604, Peoria, Illinois"
              ], 
              "type": "Organization"
            }, 
            "familyName": "Cowan", 
            "givenName": "J. C.", 
            "id": "sg:person.010137462221.36", 
            "sameAs": [
              "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.010137462221.36"
            ], 
            "type": "Person"
          }, 
          {
            "affiliation": {
              "name": [
                "Northern Regional Research Center, ARS, USDA, 61604, Peoria, Illinois"
              ], 
              "type": "Organization"
            }, 
            "familyName": "Gast", 
            "givenName": "L. E.", 
            "id": "sg:person.012611112157.09", 
            "sameAs": [
              "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.012611112157.09"
            ], 
            "type": "Person"
          }, 
          {
            "affiliation": {
              "name": [
                "Eastern Regional Research Center, ARS, USDA, 19118, Philadelphia, Pennsylvania"
              ], 
              "type": "Organization"
            }, 
            "familyName": "Koos", 
            "givenName": "R. E.", 
            "id": "sg:person.012514767437.06", 
            "sameAs": [
              "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.012514767437.06"
            ], 
            "type": "Person"
          }
        ], 
        "citation": [
          {
            "id": "sg:pub.10.1007/bf02612948", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1004006953", 
              "https://doi.org/10.1007/bf02612948"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "sg:pub.10.1007/bf02545148", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1011971266", 
              "https://doi.org/10.1007/bf02545148"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "sg:pub.10.1007/bf02558177", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1013666315", 
              "https://doi.org/10.1007/bf02558177"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "sg:pub.10.1038/206573a0", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1034831078", 
              "https://doi.org/10.1038/206573a0"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "sg:pub.10.1007/bf02541182", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1035746325", 
              "https://doi.org/10.1007/bf02541182"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "sg:pub.10.1007/bf02609224", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1039419524", 
              "https://doi.org/10.1007/bf02609224"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "sg:pub.10.1007/bf02679872", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1040768014", 
              "https://doi.org/10.1007/bf02679872"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "https://doi.org/10.1039/an9477200157", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1040804022"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "sg:pub.10.1007/bf02541263", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1044888357", 
              "https://doi.org/10.1007/bf02541263"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "sg:pub.10.1007/bf02541217", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1047705970", 
              "https://doi.org/10.1007/bf02541217"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "sg:pub.10.1038/206373a0", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1053592672", 
              "https://doi.org/10.1038/206373a0"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "sg:pub.10.1038/206373a0", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1053592672", 
              "https://doi.org/10.1038/206373a0"
            ], 
            "type": "CreativeWork"
          }
        ], 
        "datePublished": "1976-07", 
        "datePublishedReg": "1976-07-01", 
        "description": "Soybean and linseed oils were selectively hydroenated with copper-on-silica gel catalyst. The linolenate content of the oils was reduced to diene and monoene with no appreciable increase in saturates. Hydrogenated soybean oils contained 68\u201376% monoene, 11\u201318% diene, 0% conjugated diene and triene, 1\u20136% conjugatable diene, 0\u20130.3% conjugatable triene, and 23\u201340% isolatedtrans double bonds. Hydrogenated linseed oils contained 44\u201354% monoene, 35\u201345% diene, 0% conjugated diene and triene, 0\u20137% conjugatable diene, 0\u201302% conjugatable triene, and 44\u201359% isoaltedtrans double bonds. Esters of fatty acids, derived from these selectively hydrogenated oils, were prepared with trimethylolethane, trimethylolpropane, trimethylolbutane, pentaerythritol, ethylene glycol, C18 saturated cyclic alcohols, primary C12\u2013C18 saturated (nC12, nC14, nC16, nC18) alcohol, and primary C16\u2013C18 saturated (nC16, nC18) alcohol blends. Measurements of viscosities and of smoke, flash, and fire points indicate that these esters are possible replacements for sperm oil. Certain of them, after sulfurization, also have potential as extreme pressure lubricant additives.", 
        "genre": "research_article", 
        "id": "sg:pub.10.1007/bf02636825", 
        "inLanguage": [
          "en"
        ], 
        "isAccessibleForFree": false, 
        "isPartOf": [
          {
            "id": "sg:journal.1082739", 
            "issn": [
              "0003-021X", 
              "1558-9331"
            ], 
            "name": "Journal of the American Oil Chemists' Society", 
            "type": "Periodical"
          }, 
          {
            "issueNumber": "7", 
            "type": "PublicationIssue"
          }, 
          {
            "type": "PublicationVolume", 
            "volumeNumber": "53"
          }
        ], 
        "name": "Sperm oil replacements from selectively hydrogenated soybean and linseed esters: Special lubricants", 
        "pagination": "511-517", 
        "productId": [
          {
            "name": "readcube_id", 
            "type": "PropertyValue", 
            "value": [
              "3c9f008bf2077b8f3c5888ca9e65344e0eca23d2d2605e888f0e945122c89cef"
            ]
          }, 
          {
            "name": "doi", 
            "type": "PropertyValue", 
            "value": [
              "10.1007/bf02636825"
            ]
          }, 
          {
            "name": "dimensions_id", 
            "type": "PropertyValue", 
            "value": [
              "pub.1012725309"
            ]
          }
        ], 
        "sameAs": [
          "https://doi.org/10.1007/bf02636825", 
          "https://app.dimensions.ai/details/publication/pub.1012725309"
        ], 
        "sdDataset": "articles", 
        "sdDatePublished": "2019-04-11T00:14", 
        "sdLicense": "https://scigraph.springernature.com/explorer/license/", 
        "sdPublisher": {
          "name": "Springer Nature - SN SciGraph project", 
          "type": "Organization"
        }, 
        "sdSource": "s3://com-uberresearch-data-dimensions-target-20181106-alternative/cleanup/v134/2549eaecd7973599484d7c17b260dba0a4ecb94b/merge/v9/a6c9fde33151104705d4d7ff012ea9563521a3ce/jats-lookup/v90/0000000001_0000000264/records_8695_00000504.jsonl", 
        "type": "ScholarlyArticle", 
        "url": "http://link.springer.com/10.1007%2FBF02636825"
      }
    ]
     

    Download the RDF metadata as:  json-ld nt turtle xml License info

    HOW TO GET THIS DATA PROGRAMMATICALLY:

    JSON-LD is a popular format for linked data which is fully compatible with JSON.

    curl -H 'Accept: application/ld+json' 'https://scigraph.springernature.com/pub.10.1007/bf02636825'

    N-Triples is a line-based linked data format ideal for batch operations.

    curl -H 'Accept: application/n-triples' 'https://scigraph.springernature.com/pub.10.1007/bf02636825'

    Turtle is a human-readable linked data format.

    curl -H 'Accept: text/turtle' 'https://scigraph.springernature.com/pub.10.1007/bf02636825'

    RDF/XML is a standard XML format for linked data.

    curl -H 'Accept: application/rdf+xml' 'https://scigraph.springernature.com/pub.10.1007/bf02636825'


     

    This table displays all metadata directly associated to this object as RDF triples.

    130 TRIPLES      21 PREDICATES      38 URIs      19 LITERALS      7 BLANK NODES

    Subject Predicate Object
    1 sg:pub.10.1007/bf02636825 schema:about anzsrc-for:11
    2 anzsrc-for:1117
    3 schema:author N8d1efd135b41479ba2a8501d58fb7884
    4 schema:citation sg:pub.10.1007/bf02541182
    5 sg:pub.10.1007/bf02541217
    6 sg:pub.10.1007/bf02541263
    7 sg:pub.10.1007/bf02545148
    8 sg:pub.10.1007/bf02558177
    9 sg:pub.10.1007/bf02609224
    10 sg:pub.10.1007/bf02612948
    11 sg:pub.10.1007/bf02679872
    12 sg:pub.10.1038/206373a0
    13 sg:pub.10.1038/206573a0
    14 https://doi.org/10.1039/an9477200157
    15 schema:datePublished 1976-07
    16 schema:datePublishedReg 1976-07-01
    17 schema:description Soybean and linseed oils were selectively hydroenated with copper-on-silica gel catalyst. The linolenate content of the oils was reduced to diene and monoene with no appreciable increase in saturates. Hydrogenated soybean oils contained 68–76% monoene, 11–18% diene, 0% conjugated diene and triene, 1–6% conjugatable diene, 0–0.3% conjugatable triene, and 23–40% isolatedtrans double bonds. Hydrogenated linseed oils contained 44–54% monoene, 35–45% diene, 0% conjugated diene and triene, 0–7% conjugatable diene, 0–02% conjugatable triene, and 44–59% isoaltedtrans double bonds. Esters of fatty acids, derived from these selectively hydrogenated oils, were prepared with trimethylolethane, trimethylolpropane, trimethylolbutane, pentaerythritol, ethylene glycol, C18 saturated cyclic alcohols, primary C12–C18 saturated (nC12, nC14, nC16, nC18) alcohol, and primary C16–C18 saturated (nC16, nC18) alcohol blends. Measurements of viscosities and of smoke, flash, and fire points indicate that these esters are possible replacements for sperm oil. Certain of them, after sulfurization, also have potential as extreme pressure lubricant additives.
    18 schema:genre research_article
    19 schema:inLanguage en
    20 schema:isAccessibleForFree false
    21 schema:isPartOf N754a22558bd940c286c3e4e3e52a886e
    22 Naef0ddafed5e406d8ff9192ba3eb16ce
    23 sg:journal.1082739
    24 schema:name Sperm oil replacements from selectively hydrogenated soybean and linseed esters: Special lubricants
    25 schema:pagination 511-517
    26 schema:productId N58c928cdbc7344bfbbf57e9b408f9674
    27 Nf15162a7527d4ddb909f5a829b8d1467
    28 Nf3262d55ca41400a83a44838b054bda0
    29 schema:sameAs https://app.dimensions.ai/details/publication/pub.1012725309
    30 https://doi.org/10.1007/bf02636825
    31 schema:sdDatePublished 2019-04-11T00:14
    32 schema:sdLicense https://scigraph.springernature.com/explorer/license/
    33 schema:sdPublisher N2b3e5c5a5f534636a41040e061df3320
    34 schema:url http://link.springer.com/10.1007%2FBF02636825
    35 sgo:license sg:explorer/license/
    36 sgo:sdDataset articles
    37 rdf:type schema:ScholarlyArticle
    38 N1bd31758a4ce4645810c06eb34db04c4 rdf:first sg:person.012514767437.06
    39 rdf:rest rdf:nil
    40 N2b3e5c5a5f534636a41040e061df3320 schema:name Springer Nature - SN SciGraph project
    41 rdf:type schema:Organization
    42 N37865cb536a842539e78a85bb7676c18 schema:name Eastern Regional Research Center, ARS, USDA, 19118, Philadelphia, Pennsylvania
    43 rdf:type schema:Organization
    44 N3da9af523b1e492585f2b4ce2847cd39 rdf:first sg:person.012611112157.09
    45 rdf:rest N1bd31758a4ce4645810c06eb34db04c4
    46 N4eefb91d884e41c18fd324cf1eb1a88c rdf:first sg:person.010137462221.36
    47 rdf:rest N3da9af523b1e492585f2b4ce2847cd39
    48 N58c928cdbc7344bfbbf57e9b408f9674 schema:name dimensions_id
    49 schema:value pub.1012725309
    50 rdf:type schema:PropertyValue
    51 N754a22558bd940c286c3e4e3e52a886e schema:issueNumber 7
    52 rdf:type schema:PublicationIssue
    53 N7bc85feac58543b4b1695ac178777ea9 schema:name Northern Regional Research Center, ARS, USDA, 61604, Peoria, Illinois
    54 rdf:type schema:Organization
    55 N8d1efd135b41479ba2a8501d58fb7884 rdf:first sg:person.015034154213.63
    56 rdf:rest N4eefb91d884e41c18fd324cf1eb1a88c
    57 Na8c1381659654a1fabd094c0b075f1bb schema:name Northern Regional Research Center, ARS, USDA, 61604, Peoria, Illinois
    58 rdf:type schema:Organization
    59 Naef0ddafed5e406d8ff9192ba3eb16ce schema:volumeNumber 53
    60 rdf:type schema:PublicationVolume
    61 Nb447aa0eaa3a4d6f8ca360c16101eb38 schema:name Northern Regional Research Center, ARS, USDA, 61604, Peoria, Illinois
    62 rdf:type schema:Organization
    63 Nf15162a7527d4ddb909f5a829b8d1467 schema:name doi
    64 schema:value 10.1007/bf02636825
    65 rdf:type schema:PropertyValue
    66 Nf3262d55ca41400a83a44838b054bda0 schema:name readcube_id
    67 schema:value 3c9f008bf2077b8f3c5888ca9e65344e0eca23d2d2605e888f0e945122c89cef
    68 rdf:type schema:PropertyValue
    69 anzsrc-for:11 schema:inDefinedTermSet anzsrc-for:
    70 schema:name Medical and Health Sciences
    71 rdf:type schema:DefinedTerm
    72 anzsrc-for:1117 schema:inDefinedTermSet anzsrc-for:
    73 schema:name Public Health and Health Services
    74 rdf:type schema:DefinedTerm
    75 sg:journal.1082739 schema:issn 0003-021X
    76 1558-9331
    77 schema:name Journal of the American Oil Chemists' Society
    78 rdf:type schema:Periodical
    79 sg:person.010137462221.36 schema:affiliation Nb447aa0eaa3a4d6f8ca360c16101eb38
    80 schema:familyName Cowan
    81 schema:givenName J. C.
    82 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.010137462221.36
    83 rdf:type schema:Person
    84 sg:person.012514767437.06 schema:affiliation N37865cb536a842539e78a85bb7676c18
    85 schema:familyName Koos
    86 schema:givenName R. E.
    87 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.012514767437.06
    88 rdf:type schema:Person
    89 sg:person.012611112157.09 schema:affiliation Na8c1381659654a1fabd094c0b075f1bb
    90 schema:familyName Gast
    91 schema:givenName L. E.
    92 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.012611112157.09
    93 rdf:type schema:Person
    94 sg:person.015034154213.63 schema:affiliation N7bc85feac58543b4b1695ac178777ea9
    95 schema:familyName Bell
    96 schema:givenName E. W.
    97 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.015034154213.63
    98 rdf:type schema:Person
    99 sg:pub.10.1007/bf02541182 schema:sameAs https://app.dimensions.ai/details/publication/pub.1035746325
    100 https://doi.org/10.1007/bf02541182
    101 rdf:type schema:CreativeWork
    102 sg:pub.10.1007/bf02541217 schema:sameAs https://app.dimensions.ai/details/publication/pub.1047705970
    103 https://doi.org/10.1007/bf02541217
    104 rdf:type schema:CreativeWork
    105 sg:pub.10.1007/bf02541263 schema:sameAs https://app.dimensions.ai/details/publication/pub.1044888357
    106 https://doi.org/10.1007/bf02541263
    107 rdf:type schema:CreativeWork
    108 sg:pub.10.1007/bf02545148 schema:sameAs https://app.dimensions.ai/details/publication/pub.1011971266
    109 https://doi.org/10.1007/bf02545148
    110 rdf:type schema:CreativeWork
    111 sg:pub.10.1007/bf02558177 schema:sameAs https://app.dimensions.ai/details/publication/pub.1013666315
    112 https://doi.org/10.1007/bf02558177
    113 rdf:type schema:CreativeWork
    114 sg:pub.10.1007/bf02609224 schema:sameAs https://app.dimensions.ai/details/publication/pub.1039419524
    115 https://doi.org/10.1007/bf02609224
    116 rdf:type schema:CreativeWork
    117 sg:pub.10.1007/bf02612948 schema:sameAs https://app.dimensions.ai/details/publication/pub.1004006953
    118 https://doi.org/10.1007/bf02612948
    119 rdf:type schema:CreativeWork
    120 sg:pub.10.1007/bf02679872 schema:sameAs https://app.dimensions.ai/details/publication/pub.1040768014
    121 https://doi.org/10.1007/bf02679872
    122 rdf:type schema:CreativeWork
    123 sg:pub.10.1038/206373a0 schema:sameAs https://app.dimensions.ai/details/publication/pub.1053592672
    124 https://doi.org/10.1038/206373a0
    125 rdf:type schema:CreativeWork
    126 sg:pub.10.1038/206573a0 schema:sameAs https://app.dimensions.ai/details/publication/pub.1034831078
    127 https://doi.org/10.1038/206573a0
    128 rdf:type schema:CreativeWork
    129 https://doi.org/10.1039/an9477200157 schema:sameAs https://app.dimensions.ai/details/publication/pub.1040804022
    130 rdf:type schema:CreativeWork
     




    Preview window. Press ESC to close (or click here)


    ...