Conjugation of polyunsaturated fats with dimsylsodium View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

1973-04

AUTHORS

W. J. Dejarlais, L. E. Gast, J. C. Cowan

ABSTRACT

The conjugation of polyunsaturated fatty esters, including soybean oil, trilinolein, soybean methyl esters, and methyl linolenate and linoleate, with the sodium salt of dimethyl sulfoxide (dimsylsodium) as catalyst has been investigated. Methyl esters are ca. 95% conjugated within 2 hr. Glycerides react more slowly but are similarly conjugated within 24 hr. The glyceride linkages are not destroyed as they would be with aqueous or alcoholic alkali. Highly conjugated oils can thus be prepared. More... »

PAGES

108-109

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/bf02633559

DOI

http://dx.doi.org/10.1007/bf02633559

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1036568491


Indexing Status Check whether this publication has been indexed by Scopus and Web Of Science using the SN Indexing Status Tool
Incoming Citations Browse incoming citations for this publication using opencitations.net

JSON-LD is the canonical representation for SciGraph data.

TIP: You can open this SciGraph record using an external JSON-LD service: JSON-LD Playground Google SDTT

[
  {
    "@context": "https://springernature.github.io/scigraph/jsonld/sgcontext.json", 
    "about": [
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/0306", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Physical Chemistry (incl. Structural)", 
        "type": "DefinedTerm"
      }, 
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/03", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Chemical Sciences", 
        "type": "DefinedTerm"
      }
    ], 
    "author": [
      {
        "affiliation": {
          "alternateName": "Agricultural Research Service", 
          "id": "https://www.grid.ac/institutes/grid.463419.d", 
          "name": [
            "Northern Regional Research Laboratory, 61604, Peoria, Illinois"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Dejarlais", 
        "givenName": "W. J.", 
        "id": "sg:person.067302151.67", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.067302151.67"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Agricultural Research Service", 
          "id": "https://www.grid.ac/institutes/grid.463419.d", 
          "name": [
            "Northern Regional Research Laboratory, 61604, Peoria, Illinois"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Gast", 
        "givenName": "L. E.", 
        "id": "sg:person.012611112157.09", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.012611112157.09"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Agricultural Research Service", 
          "id": "https://www.grid.ac/institutes/grid.463419.d", 
          "name": [
            "Northern Regional Research Laboratory, 61604, Peoria, Illinois"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Cowan", 
        "givenName": "J. C.", 
        "id": "sg:person.010137462221.36", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.010137462221.36"
        ], 
        "type": "Person"
      }
    ], 
    "citation": [
      {
        "id": "sg:pub.10.1007/bf02673236", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1026075600", 
          "https://doi.org/10.1007/bf02673236"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1007/bf02531932", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1028138407", 
          "https://doi.org/10.1007/bf02531932"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1002/cber.19660990543", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1038277984"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1007/bf02544940", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1040668103", 
          "https://doi.org/10.1007/bf02544940"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/ac60155a034", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1055038180"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/ja00864a039", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1055753661"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/ja01062a039", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1055765168"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/jo01261a004", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1056008113"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.3891/acta.chem.scand.16-0323", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1071489774"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.3891/acta.chem.scand.17-0208", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1071490147"
        ], 
        "type": "CreativeWork"
      }
    ], 
    "datePublished": "1973-04", 
    "datePublishedReg": "1973-04-01", 
    "description": "The conjugation of polyunsaturated fatty esters, including soybean oil, trilinolein, soybean methyl esters, and methyl linolenate and linoleate, with the sodium salt of dimethyl sulfoxide (dimsylsodium) as catalyst has been investigated. Methyl esters are ca. 95% conjugated within 2 hr. Glycerides react more slowly but are similarly conjugated within 24 hr. The glyceride linkages are not destroyed as they would be with aqueous or alcoholic alkali. Highly conjugated oils can thus be prepared.", 
    "genre": "research_article", 
    "id": "sg:pub.10.1007/bf02633559", 
    "inLanguage": [
      "en"
    ], 
    "isAccessibleForFree": false, 
    "isPartOf": [
      {
        "id": "sg:journal.1082739", 
        "issn": [
          "0003-021X", 
          "1558-9331"
        ], 
        "name": "Journal of the American Oil Chemists' Society", 
        "type": "Periodical"
      }, 
      {
        "issueNumber": "4", 
        "type": "PublicationIssue"
      }, 
      {
        "type": "PublicationVolume", 
        "volumeNumber": "50"
      }
    ], 
    "name": "Conjugation of polyunsaturated fats with dimsylsodium", 
    "pagination": "108-109", 
    "productId": [
      {
        "name": "readcube_id", 
        "type": "PropertyValue", 
        "value": [
          "ae32c2460e459c2abd3e37d162dee765b252d949b4665962f50799e79fba1214"
        ]
      }, 
      {
        "name": "doi", 
        "type": "PropertyValue", 
        "value": [
          "10.1007/bf02633559"
        ]
      }, 
      {
        "name": "dimensions_id", 
        "type": "PropertyValue", 
        "value": [
          "pub.1036568491"
        ]
      }
    ], 
    "sameAs": [
      "https://doi.org/10.1007/bf02633559", 
      "https://app.dimensions.ai/details/publication/pub.1036568491"
    ], 
    "sdDataset": "articles", 
    "sdDatePublished": "2019-04-10T19:07", 
    "sdLicense": "https://scigraph.springernature.com/explorer/license/", 
    "sdPublisher": {
      "name": "Springer Nature - SN SciGraph project", 
      "type": "Organization"
    }, 
    "sdSource": "s3://com-uberresearch-data-dimensions-target-20181106-alternative/cleanup/v134/2549eaecd7973599484d7c17b260dba0a4ecb94b/merge/v9/a6c9fde33151104705d4d7ff012ea9563521a3ce/jats-lookup/v90/0000000001_0000000264/records_8678_00000506.jsonl", 
    "type": "ScholarlyArticle", 
    "url": "http://link.springer.com/10.1007%2FBF02633559"
  }
]
 

Download the RDF metadata as:  json-ld nt turtle xml License info

HOW TO GET THIS DATA PROGRAMMATICALLY:

JSON-LD is a popular format for linked data which is fully compatible with JSON.

curl -H 'Accept: application/ld+json' 'https://scigraph.springernature.com/pub.10.1007/bf02633559'

N-Triples is a line-based linked data format ideal for batch operations.

curl -H 'Accept: application/n-triples' 'https://scigraph.springernature.com/pub.10.1007/bf02633559'

Turtle is a human-readable linked data format.

curl -H 'Accept: text/turtle' 'https://scigraph.springernature.com/pub.10.1007/bf02633559'

RDF/XML is a standard XML format for linked data.

curl -H 'Accept: application/rdf+xml' 'https://scigraph.springernature.com/pub.10.1007/bf02633559'


 

This table displays all metadata directly associated to this object as RDF triples.

108 TRIPLES      21 PREDICATES      37 URIs      19 LITERALS      7 BLANK NODES

Subject Predicate Object
1 sg:pub.10.1007/bf02633559 schema:about anzsrc-for:03
2 anzsrc-for:0306
3 schema:author N49072a40c42d47da91595e9962ca7723
4 schema:citation sg:pub.10.1007/bf02531932
5 sg:pub.10.1007/bf02544940
6 sg:pub.10.1007/bf02673236
7 https://doi.org/10.1002/cber.19660990543
8 https://doi.org/10.1021/ac60155a034
9 https://doi.org/10.1021/ja00864a039
10 https://doi.org/10.1021/ja01062a039
11 https://doi.org/10.1021/jo01261a004
12 https://doi.org/10.3891/acta.chem.scand.16-0323
13 https://doi.org/10.3891/acta.chem.scand.17-0208
14 schema:datePublished 1973-04
15 schema:datePublishedReg 1973-04-01
16 schema:description The conjugation of polyunsaturated fatty esters, including soybean oil, trilinolein, soybean methyl esters, and methyl linolenate and linoleate, with the sodium salt of dimethyl sulfoxide (dimsylsodium) as catalyst has been investigated. Methyl esters are ca. 95% conjugated within 2 hr. Glycerides react more slowly but are similarly conjugated within 24 hr. The glyceride linkages are not destroyed as they would be with aqueous or alcoholic alkali. Highly conjugated oils can thus be prepared.
17 schema:genre research_article
18 schema:inLanguage en
19 schema:isAccessibleForFree false
20 schema:isPartOf N9ca1ca2d9de24244bc0bd61bae6156fc
21 Nd14b432442d843edbdb16d236c3f9f6b
22 sg:journal.1082739
23 schema:name Conjugation of polyunsaturated fats with dimsylsodium
24 schema:pagination 108-109
25 schema:productId N59d9ae9a3d14472b83a0e2f52d83cc6b
26 N753b626909094335ab7f4620fb417552
27 Nae49323426b44efba7c5ca440fb7c402
28 schema:sameAs https://app.dimensions.ai/details/publication/pub.1036568491
29 https://doi.org/10.1007/bf02633559
30 schema:sdDatePublished 2019-04-10T19:07
31 schema:sdLicense https://scigraph.springernature.com/explorer/license/
32 schema:sdPublisher N0c39b5a3f81e45dfa5dfdd62b53a89c0
33 schema:url http://link.springer.com/10.1007%2FBF02633559
34 sgo:license sg:explorer/license/
35 sgo:sdDataset articles
36 rdf:type schema:ScholarlyArticle
37 N0c39b5a3f81e45dfa5dfdd62b53a89c0 schema:name Springer Nature - SN SciGraph project
38 rdf:type schema:Organization
39 N49072a40c42d47da91595e9962ca7723 rdf:first sg:person.067302151.67
40 rdf:rest Nfad950a73cad4ea889f2279fc430c297
41 N59d9ae9a3d14472b83a0e2f52d83cc6b schema:name readcube_id
42 schema:value ae32c2460e459c2abd3e37d162dee765b252d949b4665962f50799e79fba1214
43 rdf:type schema:PropertyValue
44 N60e9bc627461460fa4adacaeec2cd05d rdf:first sg:person.010137462221.36
45 rdf:rest rdf:nil
46 N753b626909094335ab7f4620fb417552 schema:name doi
47 schema:value 10.1007/bf02633559
48 rdf:type schema:PropertyValue
49 N9ca1ca2d9de24244bc0bd61bae6156fc schema:issueNumber 4
50 rdf:type schema:PublicationIssue
51 Nae49323426b44efba7c5ca440fb7c402 schema:name dimensions_id
52 schema:value pub.1036568491
53 rdf:type schema:PropertyValue
54 Nd14b432442d843edbdb16d236c3f9f6b schema:volumeNumber 50
55 rdf:type schema:PublicationVolume
56 Nfad950a73cad4ea889f2279fc430c297 rdf:first sg:person.012611112157.09
57 rdf:rest N60e9bc627461460fa4adacaeec2cd05d
58 anzsrc-for:03 schema:inDefinedTermSet anzsrc-for:
59 schema:name Chemical Sciences
60 rdf:type schema:DefinedTerm
61 anzsrc-for:0306 schema:inDefinedTermSet anzsrc-for:
62 schema:name Physical Chemistry (incl. Structural)
63 rdf:type schema:DefinedTerm
64 sg:journal.1082739 schema:issn 0003-021X
65 1558-9331
66 schema:name Journal of the American Oil Chemists' Society
67 rdf:type schema:Periodical
68 sg:person.010137462221.36 schema:affiliation https://www.grid.ac/institutes/grid.463419.d
69 schema:familyName Cowan
70 schema:givenName J. C.
71 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.010137462221.36
72 rdf:type schema:Person
73 sg:person.012611112157.09 schema:affiliation https://www.grid.ac/institutes/grid.463419.d
74 schema:familyName Gast
75 schema:givenName L. E.
76 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.012611112157.09
77 rdf:type schema:Person
78 sg:person.067302151.67 schema:affiliation https://www.grid.ac/institutes/grid.463419.d
79 schema:familyName Dejarlais
80 schema:givenName W. J.
81 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.067302151.67
82 rdf:type schema:Person
83 sg:pub.10.1007/bf02531932 schema:sameAs https://app.dimensions.ai/details/publication/pub.1028138407
84 https://doi.org/10.1007/bf02531932
85 rdf:type schema:CreativeWork
86 sg:pub.10.1007/bf02544940 schema:sameAs https://app.dimensions.ai/details/publication/pub.1040668103
87 https://doi.org/10.1007/bf02544940
88 rdf:type schema:CreativeWork
89 sg:pub.10.1007/bf02673236 schema:sameAs https://app.dimensions.ai/details/publication/pub.1026075600
90 https://doi.org/10.1007/bf02673236
91 rdf:type schema:CreativeWork
92 https://doi.org/10.1002/cber.19660990543 schema:sameAs https://app.dimensions.ai/details/publication/pub.1038277984
93 rdf:type schema:CreativeWork
94 https://doi.org/10.1021/ac60155a034 schema:sameAs https://app.dimensions.ai/details/publication/pub.1055038180
95 rdf:type schema:CreativeWork
96 https://doi.org/10.1021/ja00864a039 schema:sameAs https://app.dimensions.ai/details/publication/pub.1055753661
97 rdf:type schema:CreativeWork
98 https://doi.org/10.1021/ja01062a039 schema:sameAs https://app.dimensions.ai/details/publication/pub.1055765168
99 rdf:type schema:CreativeWork
100 https://doi.org/10.1021/jo01261a004 schema:sameAs https://app.dimensions.ai/details/publication/pub.1056008113
101 rdf:type schema:CreativeWork
102 https://doi.org/10.3891/acta.chem.scand.16-0323 schema:sameAs https://app.dimensions.ai/details/publication/pub.1071489774
103 rdf:type schema:CreativeWork
104 https://doi.org/10.3891/acta.chem.scand.17-0208 schema:sameAs https://app.dimensions.ai/details/publication/pub.1071490147
105 rdf:type schema:CreativeWork
106 https://www.grid.ac/institutes/grid.463419.d schema:alternateName Agricultural Research Service
107 schema:name Northern Regional Research Laboratory, 61604, Peoria, Illinois
108 rdf:type schema:Organization
 




Preview window. Press ESC to close (or click here)


...