Reactions of azelaaldehydic esters View Full Text


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Article Info

DATE

1969-04

AUTHORS

E. H. Pryde, J. C. Cowan

ABSTRACT

Alkyl azelaaldehydates and their acetals can undergo reactions at either the aldehyde or the ester group to form a variety of novel and reactive monomers and polymers. Pertinent reactions of the aldehyde group (and resultant products) include acetalization with pentaerythritol (diester-acetal), acetalization with glycerol (hydroxy ester-acetal), hydrogenation (hydroxy ester), reductive alkylation of ammonia (amino acid and imino diester), aldolization (dibasic acid) and hydrazone formation (azine dibasic acids). Reactions at the ester group include aminolysis (diacid amides) and hydrazinolysis (hydrazide acetal). These various products can undergo self-condensation or condensation with glycols or diamines to form polyesters, polyamides, poly (ester-acetals) and poly (amideacetals). Polymers with cyclic acetal structures in the polymer backbone have latent crosslinking capabilities. More... »

PAGES

213-218

References to SciGraph publications

  • 1965-10. Amines from aldehydes derived from the ozonization of soybean esters in JOURNAL OF THE AMERICAN OIL CHEMISTS' SOCIETY
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    http://scigraph.springernature.com/pub.10.1007/bf02632508

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    http://dx.doi.org/10.1007/bf02632508

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