Aquadimethylsulfoxide complexes of rare earth elements Pr, Eu, and Tm with the [Mo3S7Br7]3− cluster anion View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

1995-11

AUTHORS

V. E. Fedorov, O. A. Gerasko, Yu. V. Mironov, K. Hegetschweiler, R. Stoop, J. Gallus, F. Gramlich

ABSTRACT

New complexes of rare earth elements [Ln(DMSO)m(H2O)n][Mo3S7Br7], Ln=Pr, Eu, Tm were synthesized and investigated by X-ray diffraction analysis. In [Pr(DMSO)6(H2O)2]3+ and [Eu(DMSO)7(H2O)]3+, the coordination polyhedra of Ln are distorted, square antiprisms (coordination number is 8); in [Tm(DMSO)6(H2O)]3+, the coordination polyhedron of Ln is a distorted pentagonal bipyramid (coordination number is 7). In all complexes, DMSO is coordinated via oxygen atoms. More... »

PAGES

956-978

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/bf02578554

DOI

http://dx.doi.org/10.1007/bf02578554

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1030736733


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