Ontology type: schema:ScholarlyArticle
1995-11
AUTHORSV. E. Fedorov, O. A. Gerasko, Yu. V. Mironov, K. Hegetschweiler, R. Stoop, J. Gallus, F. Gramlich
ABSTRACTNew complexes of rare earth elements [Ln(DMSO)m(H2O)n][Mo3S7Br7], Ln=Pr, Eu, Tm were synthesized and investigated by X-ray diffraction analysis. In [Pr(DMSO)6(H2O)2]3+ and [Eu(DMSO)7(H2O)]3+, the coordination polyhedra of Ln are distorted, square antiprisms (coordination number is 8); in [Tm(DMSO)6(H2O)]3+, the coordination polyhedron of Ln is a distorted pentagonal bipyramid (coordination number is 7). In all complexes, DMSO is coordinated via oxygen atoms. More... »
PAGES956-978
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DOIhttp://dx.doi.org/10.1007/bf02578554
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