Ontology type: schema:ScholarlyArticle
1989-03
AUTHORSF. J. Callens, R. M. H. Verbeeck, D. E. Naessens, P. F. A. Matthys, E. R. Boesman
ABSTRACTThe ESR spectrum of X-irradiated carbonated apatites synthesized at low temperature was studied as a function of their carbonate content. Using13C-enriched samples, four different carbonate-derived radicals and a surface O− ion could be identified. Isotropic CO3− and CO2− ions are present at a B site in the apatite lattice, and anisotropic CO3− and CO2− radicals are located at the surface of the crystallites. Only the isotropic ESR signals increase with increasing carbonate content. The anisotropic signal ascribed to a surface CO2− radical is mainly responsible for the so-called asymmetric ESR signal near g=2. It is argued that this surface signal may still be composite and caused by several very similar CO2− ions. The consequences for phenomenological ESR studies of calcified tissues are discussed. More... »
PAGES114-124
http://scigraph.springernature.com/pub.10.1007/bf02556470
DOIhttp://dx.doi.org/10.1007/bf02556470
DIMENSIONShttps://app.dimensions.ai/details/publication/pub.1021964152
PUBMEDhttps://www.ncbi.nlm.nih.gov/pubmed/2537133
JSON-LD is the canonical representation for SciGraph data.
TIP: You can open this SciGraph record using an external JSON-LD service: JSON-LD Playground Google SDTT
[
{
"@context": "https://springernature.github.io/scigraph/jsonld/sgcontext.json",
"about": [
{
"id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/09",
"inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/",
"name": "Engineering",
"type": "DefinedTerm"
},
{
"id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/0912",
"inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/",
"name": "Materials Engineering",
"type": "DefinedTerm"
},
{
"inDefinedTermSet": "https://www.nlm.nih.gov/mesh/",
"name": "Apatites",
"type": "DefinedTerm"
},
{
"inDefinedTermSet": "https://www.nlm.nih.gov/mesh/",
"name": "Carbon Dioxide",
"type": "DefinedTerm"
},
{
"inDefinedTermSet": "https://www.nlm.nih.gov/mesh/",
"name": "Carbonates",
"type": "DefinedTerm"
},
{
"inDefinedTermSet": "https://www.nlm.nih.gov/mesh/",
"name": "Dental Enamel",
"type": "DefinedTerm"
},
{
"inDefinedTermSet": "https://www.nlm.nih.gov/mesh/",
"name": "Electron Spin Resonance Spectroscopy",
"type": "DefinedTerm"
},
{
"inDefinedTermSet": "https://www.nlm.nih.gov/mesh/",
"name": "Free Radicals",
"type": "DefinedTerm"
},
{
"inDefinedTermSet": "https://www.nlm.nih.gov/mesh/",
"name": "Humans",
"type": "DefinedTerm"
},
{
"inDefinedTermSet": "https://www.nlm.nih.gov/mesh/",
"name": "Oxygen",
"type": "DefinedTerm"
},
{
"inDefinedTermSet": "https://www.nlm.nih.gov/mesh/",
"name": "Singlet Oxygen",
"type": "DefinedTerm"
}
],
"author": [
{
"affiliation": {
"alternateName": "Laboratory of Crystallography and Study of the Solid State, State University Gent, Belgium",
"id": "http://www.grid.ac/institutes/grid.5342.0",
"name": [
"Laboratory of Crystallography and Study of the Solid State, State University Gent, Belgium"
],
"type": "Organization"
},
"familyName": "Callens",
"givenName": "F. J.",
"id": "sg:person.0711714601.87",
"sameAs": [
"https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.0711714601.87"
],
"type": "Person"
},
{
"affiliation": {
"alternateName": "Research Associate of the N.F.S.R. (Belgium), Laboratory for Analytical Chemistry, State University Gent, Krijgslaan 281-S12, B-9000, Gent, Belgium",
"id": "http://www.grid.ac/institutes/grid.5342.0",
"name": [
"Research Associate of the N.F.S.R. (Belgium), Laboratory for Analytical Chemistry, State University Gent, Krijgslaan 281-S12, B-9000, Gent, Belgium"
],
"type": "Organization"
},
"familyName": "Verbeeck",
"givenName": "R. M. H.",
"id": "sg:person.012464542134.27",
"sameAs": [
"https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.012464542134.27"
],
"type": "Person"
},
{
"affiliation": {
"alternateName": "Research Associate of the N.F.S.R. (Belgium), Laboratory for Analytical Chemistry, State University Gent, Krijgslaan 281-S12, B-9000, Gent, Belgium",
"id": "http://www.grid.ac/institutes/grid.5342.0",
"name": [
"Research Associate of the N.F.S.R. (Belgium), Laboratory for Analytical Chemistry, State University Gent, Krijgslaan 281-S12, B-9000, Gent, Belgium"
],
"type": "Organization"
},
"familyName": "Naessens",
"givenName": "D. E.",
"id": "sg:person.012301703367.81",
"sameAs": [
"https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.012301703367.81"
],
"type": "Person"
},
{
"affiliation": {
"alternateName": "Laboratory of Crystallography and Study of the Solid State, State University Gent, Belgium",
"id": "http://www.grid.ac/institutes/grid.5342.0",
"name": [
"Laboratory of Crystallography and Study of the Solid State, State University Gent, Belgium"
],
"type": "Organization"
},
"familyName": "Matthys",
"givenName": "P. F. A.",
"id": "sg:person.013511773553.17",
"sameAs": [
"https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.013511773553.17"
],
"type": "Person"
},
{
"affiliation": {
"alternateName": "Laboratory of Crystallography and Study of the Solid State, State University Gent, Belgium",
"id": "http://www.grid.ac/institutes/grid.5342.0",
"name": [
"Laboratory of Crystallography and Study of the Solid State, State University Gent, Belgium"
],
"type": "Organization"
},
"familyName": "Boesman",
"givenName": "E. R.",
"id": "sg:person.012025432205.53",
"sameAs": [
"https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.012025432205.53"
],
"type": "Person"
}
],
"citation": [
{
"id": "sg:pub.10.1007/bf02409421",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1035911825",
"https://doi.org/10.1007/bf02409421"
],
"type": "CreativeWork"
},
{
"id": "sg:pub.10.1007/bf02441228",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1004907708",
"https://doi.org/10.1007/bf02441228"
],
"type": "CreativeWork"
},
{
"id": "sg:pub.10.1007/bf02563791",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1023952744",
"https://doi.org/10.1007/bf02563791"
],
"type": "CreativeWork"
},
{
"id": "sg:pub.10.1038/286425a0",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1034254499",
"https://doi.org/10.1038/286425a0"
],
"type": "CreativeWork"
}
],
"datePublished": "1989-03",
"datePublishedReg": "1989-03-01",
"description": "The ESR spectrum of X-irradiated carbonated apatites synthesized at low temperature was studied as a function of their carbonate content. Using13C-enriched samples, four different carbonate-derived radicals and a surface O\u2212 ion could be identified. Isotropic CO3\u2212 and CO2\u2212 ions are present at a B site in the apatite lattice, and anisotropic CO3\u2212 and CO2\u2212 radicals are located at the surface of the crystallites. Only the isotropic ESR signals increase with increasing carbonate content. The anisotropic signal ascribed to a surface CO2\u2212 radical is mainly responsible for the so-called asymmetric ESR signal near g=2. It is argued that this surface signal may still be composite and caused by several very similar CO2\u2212 ions. The consequences for phenomenological ESR studies of calcified tissues are discussed.",
"genre": "article",
"id": "sg:pub.10.1007/bf02556470",
"isAccessibleForFree": false,
"isPartOf": [
{
"id": "sg:journal.1089641",
"issn": [
"0171-967X",
"1432-0827"
],
"name": "Calcified Tissue International",
"publisher": "Springer Nature",
"type": "Periodical"
},
{
"issueNumber": "2",
"type": "PublicationIssue"
},
{
"type": "PublicationVolume",
"volumeNumber": "44"
}
],
"keywords": [
"carbonate content",
"low temperature",
"surface",
"surface signals",
"carbonated apatite",
"B-site",
"apatite lattice",
"signals",
"anisotropic signal",
"asymmetric ESR signal",
"aqueous media",
"apatite",
"temperature",
"ions",
"isotropic",
"crystallites",
"content",
"isotropic ESR signal",
"ESR signal",
"calcified tissues",
"spectra",
"sites",
"lattice",
"samples",
"radicals",
"effect",
"medium",
"ESR spectra",
"function",
"consequences",
"study",
"calciumapatites",
"ESR study",
"tissue"
],
"name": "Effect of carbonate content on the ESR spectrum near g=2 of carbonated calciumapatites synthesized from aqueous media",
"pagination": "114-124",
"productId": [
{
"name": "dimensions_id",
"type": "PropertyValue",
"value": [
"pub.1021964152"
]
},
{
"name": "doi",
"type": "PropertyValue",
"value": [
"10.1007/bf02556470"
]
},
{
"name": "pubmed_id",
"type": "PropertyValue",
"value": [
"2537133"
]
}
],
"sameAs": [
"https://doi.org/10.1007/bf02556470",
"https://app.dimensions.ai/details/publication/pub.1021964152"
],
"sdDataset": "articles",
"sdDatePublished": "2022-08-04T16:51",
"sdLicense": "https://scigraph.springernature.com/explorer/license/",
"sdPublisher": {
"name": "Springer Nature - SN SciGraph project",
"type": "Organization"
},
"sdSource": "s3://com-springernature-scigraph/baseset/20220804/entities/gbq_results/article/article_217.jsonl",
"type": "ScholarlyArticle",
"url": "https://doi.org/10.1007/bf02556470"
}
]Download the RDF metadata as: json-ld nt turtle xml License info
JSON-LD is a popular format for linked data which is fully compatible with JSON.
curl -H 'Accept: application/ld+json' 'https://scigraph.springernature.com/pub.10.1007/bf02556470'
N-Triples is a line-based linked data format ideal for batch operations.
curl -H 'Accept: application/n-triples' 'https://scigraph.springernature.com/pub.10.1007/bf02556470'
Turtle is a human-readable linked data format.
curl -H 'Accept: text/turtle' 'https://scigraph.springernature.com/pub.10.1007/bf02556470'
RDF/XML is a standard XML format for linked data.
curl -H 'Accept: application/rdf+xml' 'https://scigraph.springernature.com/pub.10.1007/bf02556470'
This table displays all metadata directly associated to this object as RDF triples.
177 TRIPLES
21 PREDICATES
73 URIs
61 LITERALS
16 BLANK NODES