The effect of carbonate content and drying temperature on the ESR-spectrum near g=2 of carbonated calciumapatites synthesized from aqueous media View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

1991-04

AUTHORS

F. J. Callens, R. M. H. Verbeeck, D. E. Naessens, P. F. A. Matthys, E. R. Boesman

ABSTRACT

The ESR spectrum of X-irradiated carbonated apatites precipitated from aqueous solutions was studied as a function of their carbonate content and drying temperature. When the latter increases from 25 to 400°C, the ESR spectrum is gradually modified and becomes similar to the spectrum of carbonated apatites, synthesized at high temperatures by solid state reactions. The latter ESR spectrum is dominated by CO33−-contributions whereas the spectrum of precipitated samples dried at 25°C can mainly be interpreted in terms of CO2−, CO3−, and O− ions. The behavior of these earlierreported CO2−, CO3−, and O− centers is now studied as a function of drying temperature. In addition, the Spin Hamiltonian parameters of the CO33− centers are determined and some other new paramagnetic radicals are discussed. It is shown that a CO32− ion at a phosphate lattice site (B-type substitution) may give rise to either a CO2−, CO3−, or CO33− radical on X-irradiation, depending on the sample preparation conditions. A surface CO32− ion may cause a surface CO2−, CO3−, or O− radical. From the reported results it is not unambiguously clear whether the CO33− ion detected in the samples with the relatively lowest carbonate content should be located on the surface or on a hydroxyl lattice site (A-type substitution). An important result is that the absolute concentration of the B-type CO33− ion increases with increasing carbonate content as was also the case for the earlier reported B-type radicals (isotropic CO2− and CO3−). On the other hand, the absolute concentration of the surface radicals decreases with increasing carbonate content. The reported results show that similar deconvolution techniques can be applied in the future for the study of ESR spectra of calcified tissues. This will allow a more efficient phenomenological investigation of the latter. More... »

PAGES

249-259

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/bf02556376

DOI

http://dx.doi.org/10.1007/bf02556376

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1019969163

PUBMED

https://www.ncbi.nlm.nih.gov/pubmed/1647844


Indexing Status Check whether this publication has been indexed by Scopus and Web Of Science using the SN Indexing Status Tool
Incoming Citations Browse incoming citations for this publication using opencitations.net

JSON-LD is the canonical representation for SciGraph data.

TIP: You can open this SciGraph record using an external JSON-LD service: JSON-LD Playground Google SDTT

[
  {
    "@context": "https://springernature.github.io/scigraph/jsonld/sgcontext.json", 
    "about": [
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/06", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Biological Sciences", 
        "type": "DefinedTerm"
      }, 
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/09", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Engineering", 
        "type": "DefinedTerm"
      }, 
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/11", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Medical and Health Sciences", 
        "type": "DefinedTerm"
      }, 
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/0601", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Biochemistry and Cell Biology", 
        "type": "DefinedTerm"
      }, 
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/0903", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Biomedical Engineering", 
        "type": "DefinedTerm"
      }, 
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/1103", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Clinical Sciences", 
        "type": "DefinedTerm"
      }, 
      {
        "inDefinedTermSet": "https://www.nlm.nih.gov/mesh/", 
        "name": "Apatites", 
        "type": "DefinedTerm"
      }, 
      {
        "inDefinedTermSet": "https://www.nlm.nih.gov/mesh/", 
        "name": "Calcium", 
        "type": "DefinedTerm"
      }, 
      {
        "inDefinedTermSet": "https://www.nlm.nih.gov/mesh/", 
        "name": "Calcium Carbonate", 
        "type": "DefinedTerm"
      }, 
      {
        "inDefinedTermSet": "https://www.nlm.nih.gov/mesh/", 
        "name": "Carbonates", 
        "type": "DefinedTerm"
      }, 
      {
        "inDefinedTermSet": "https://www.nlm.nih.gov/mesh/", 
        "name": "Chemical Precipitation", 
        "type": "DefinedTerm"
      }, 
      {
        "inDefinedTermSet": "https://www.nlm.nih.gov/mesh/", 
        "name": "Electron Spin Resonance Spectroscopy", 
        "type": "DefinedTerm"
      }, 
      {
        "inDefinedTermSet": "https://www.nlm.nih.gov/mesh/", 
        "name": "Oxygen", 
        "type": "DefinedTerm"
      }, 
      {
        "inDefinedTermSet": "https://www.nlm.nih.gov/mesh/", 
        "name": "Phosphates", 
        "type": "DefinedTerm"
      }, 
      {
        "inDefinedTermSet": "https://www.nlm.nih.gov/mesh/", 
        "name": "Temperature", 
        "type": "DefinedTerm"
      }, 
      {
        "inDefinedTermSet": "https://www.nlm.nih.gov/mesh/", 
        "name": "Water", 
        "type": "DefinedTerm"
      }
    ], 
    "author": [
      {
        "affiliation": {
          "alternateName": "Laboratory of Crystallography and Study of the Solid State, State University Gent, Belgium", 
          "id": "http://www.grid.ac/institutes/grid.5342.0", 
          "name": [
            "Laboratory of Crystallography and Study of the Solid State, State University Gent, Belgium"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Callens", 
        "givenName": "F. J.", 
        "id": "sg:person.0711714601.87", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.0711714601.87"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Laboratory for Analytical Chemistry, State University Gent, Krijgslaan 281-S12, B-9000, Gent, Belgium", 
          "id": "http://www.grid.ac/institutes/grid.5342.0", 
          "name": [
            "Laboratory for Analytical Chemistry, State University Gent, Krijgslaan 281-S12, B-9000, Gent, Belgium"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Verbeeck", 
        "givenName": "R. M. H.", 
        "id": "sg:person.012464542134.27", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.012464542134.27"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Laboratory for Analytical Chemistry, State University Gent, Krijgslaan 281-S12, B-9000, Gent, Belgium", 
          "id": "http://www.grid.ac/institutes/grid.5342.0", 
          "name": [
            "Laboratory for Analytical Chemistry, State University Gent, Krijgslaan 281-S12, B-9000, Gent, Belgium"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Naessens", 
        "givenName": "D. E.", 
        "id": "sg:person.012301703367.81", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.012301703367.81"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Laboratory of Crystallography and Study of the Solid State, State University Gent, Belgium", 
          "id": "http://www.grid.ac/institutes/grid.5342.0", 
          "name": [
            "Laboratory of Crystallography and Study of the Solid State, State University Gent, Belgium"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Matthys", 
        "givenName": "P. F. A.", 
        "id": "sg:person.013511773553.17", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.013511773553.17"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Laboratory of Crystallography and Study of the Solid State, State University Gent, Belgium", 
          "id": "http://www.grid.ac/institutes/grid.5342.0", 
          "name": [
            "Laboratory of Crystallography and Study of the Solid State, State University Gent, Belgium"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Boesman", 
        "givenName": "E. R.", 
        "id": "sg:person.012025432205.53", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.012025432205.53"
        ], 
        "type": "Person"
      }
    ], 
    "citation": [
      {
        "id": "sg:pub.10.1007/bf02563791", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1023952744", 
          "https://doi.org/10.1007/bf02563791"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1007/bf02556470", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1021964152", 
          "https://doi.org/10.1007/bf02556470"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1007/bf02441228", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1004907708", 
          "https://doi.org/10.1007/bf02441228"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1007/bf02409416", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1000704373", 
          "https://doi.org/10.1007/bf02409416"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1038/286425a0", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1034254499", 
          "https://doi.org/10.1038/286425a0"
        ], 
        "type": "CreativeWork"
      }
    ], 
    "datePublished": "1991-04", 
    "datePublishedReg": "1991-04-01", 
    "description": "The ESR spectrum of X-irradiated carbonated apatites precipitated from aqueous solutions was studied as a function of their carbonate content and drying temperature. When the latter increases from 25 to 400\u00b0C, the ESR spectrum is gradually modified and becomes similar to the spectrum of carbonated apatites, synthesized at high temperatures by solid state reactions. The latter ESR spectrum is dominated by CO33\u2212-contributions whereas the spectrum of precipitated samples dried at 25\u00b0C can mainly be interpreted in terms of CO2\u2212, CO3\u2212, and O\u2212 ions. The behavior of these earlierreported CO2\u2212, CO3\u2212, and O\u2212 centers is now studied as a function of drying temperature. In addition, the Spin Hamiltonian parameters of the CO33\u2212 centers are determined and some other new paramagnetic radicals are discussed. It is shown that a CO32\u2212 ion at a phosphate lattice site (B-type substitution) may give rise to either a CO2\u2212, CO3\u2212, or CO33\u2212 radical on X-irradiation, depending on the sample preparation conditions. A surface CO32\u2212 ion may cause a surface CO2\u2212, CO3\u2212, or O\u2212 radical. From the reported results it is not unambiguously clear whether the CO33\u2212 ion detected in the samples with the relatively lowest carbonate content should be located on the surface or on a hydroxyl lattice site (A-type substitution). An important result is that the absolute concentration of the B-type CO33\u2212 ion increases with increasing carbonate content as was also the case for the earlier reported B-type radicals (isotropic CO2\u2212 and CO3\u2212). On the other hand, the absolute concentration of the surface radicals decreases with increasing carbonate content. The reported results show that similar deconvolution techniques can be applied in the future for the study of ESR spectra of calcified tissues. This will allow a more efficient phenomenological investigation of the latter.", 
    "genre": "article", 
    "id": "sg:pub.10.1007/bf02556376", 
    "isAccessibleForFree": false, 
    "isPartOf": [
      {
        "id": "sg:journal.1089641", 
        "issn": [
          "0171-967X", 
          "1432-0827"
        ], 
        "name": "Calcified Tissue International", 
        "publisher": "Springer Nature", 
        "type": "Periodical"
      }, 
      {
        "issueNumber": "4", 
        "type": "PublicationIssue"
      }, 
      {
        "type": "PublicationVolume", 
        "volumeNumber": "48"
      }
    ], 
    "keywords": [
      "ESR spectra", 
      "carbonated apatite", 
      "aqueous solution", 
      "solid-state reaction", 
      "state reaction", 
      "ions", 
      "spin-Hamiltonian parameters", 
      "paramagnetic radicals", 
      "radicals", 
      "X-irradiation", 
      "sample preparation conditions", 
      "preparation conditions", 
      "absolute concentrations", 
      "ions increases", 
      "surface radicals", 
      "aqueous media", 
      "spectra", 
      "apatite", 
      "function", 
      "carbonate content", 
      "temperature", 
      "latter increases", 
      "increase", 
      "high temperature", 
      "reaction", 
      "samples", 
      "center", 
      "Hamiltonian parameters", 
      "lattice sites", 
      "sites", 
      "surface", 
      "results", 
      "low carbonate content", 
      "concentration", 
      "B-type", 
      "cases", 
      "reported results", 
      "study", 
      "tissue", 
      "effect", 
      "solution", 
      "content", 
      "contribution", 
      "terms", 
      "behavior", 
      "addition", 
      "parameters", 
      "conditions", 
      "important results", 
      "hand", 
      "deconvolution technique", 
      "technique", 
      "future", 
      "phenomenological investigation", 
      "investigation", 
      "medium", 
      "calciumapatites"
    ], 
    "name": "The effect of carbonate content and drying temperature on the ESR-spectrum near g=2 of carbonated calciumapatites synthesized from aqueous media", 
    "pagination": "249-259", 
    "productId": [
      {
        "name": "dimensions_id", 
        "type": "PropertyValue", 
        "value": [
          "pub.1019969163"
        ]
      }, 
      {
        "name": "doi", 
        "type": "PropertyValue", 
        "value": [
          "10.1007/bf02556376"
        ]
      }, 
      {
        "name": "pubmed_id", 
        "type": "PropertyValue", 
        "value": [
          "1647844"
        ]
      }
    ], 
    "sameAs": [
      "https://doi.org/10.1007/bf02556376", 
      "https://app.dimensions.ai/details/publication/pub.1019969163"
    ], 
    "sdDataset": "articles", 
    "sdDatePublished": "2022-08-04T16:52", 
    "sdLicense": "https://scigraph.springernature.com/explorer/license/", 
    "sdPublisher": {
      "name": "Springer Nature - SN SciGraph project", 
      "type": "Organization"
    }, 
    "sdSource": "s3://com-springernature-scigraph/baseset/20220804/entities/gbq_results/article/article_245.jsonl", 
    "type": "ScholarlyArticle", 
    "url": "https://doi.org/10.1007/bf02556376"
  }
]
 

Download the RDF metadata as:  json-ld nt turtle xml License info

HOW TO GET THIS DATA PROGRAMMATICALLY:

JSON-LD is a popular format for linked data which is fully compatible with JSON.

curl -H 'Accept: application/ld+json' 'https://scigraph.springernature.com/pub.10.1007/bf02556376'

N-Triples is a line-based linked data format ideal for batch operations.

curl -H 'Accept: application/n-triples' 'https://scigraph.springernature.com/pub.10.1007/bf02556376'

Turtle is a human-readable linked data format.

curl -H 'Accept: text/turtle' 'https://scigraph.springernature.com/pub.10.1007/bf02556376'

RDF/XML is a standard XML format for linked data.

curl -H 'Accept: application/rdf+xml' 'https://scigraph.springernature.com/pub.10.1007/bf02556376'


 

This table displays all metadata directly associated to this object as RDF triples.

224 TRIPLES      21 PREDICATES      102 URIs      85 LITERALS      17 BLANK NODES

Subject Predicate Object
1 sg:pub.10.1007/bf02556376 schema:about N0677add0d25e4f0eacf8abb2d2efbd6e
2 N09ebf99cf1494398aa48900eab7ff086
3 N49e28cab39fe449695a0280b712092fb
4 N553f06e058b0481699097db748f546d3
5 N8c11151d3a454a9ab987146c29efbcb2
6 N9756dc5991ff42ab83c85af63c6124d8
7 Nb0999e6bf50c4a70bb24efdf1472a813
8 Ncac1b097366b4210a2eb2f4f5a86345f
9 Ncde18fd196054ceeb5eb12b5f4f3df64
10 Nd806c29b6c544955ab4f0ec54ca5f930
11 anzsrc-for:06
12 anzsrc-for:0601
13 anzsrc-for:09
14 anzsrc-for:0903
15 anzsrc-for:11
16 anzsrc-for:1103
17 schema:author Nd0f99997b463458d9fcccf0940084eaf
18 schema:citation sg:pub.10.1007/bf02409416
19 sg:pub.10.1007/bf02441228
20 sg:pub.10.1007/bf02556470
21 sg:pub.10.1007/bf02563791
22 sg:pub.10.1038/286425a0
23 schema:datePublished 1991-04
24 schema:datePublishedReg 1991-04-01
25 schema:description The ESR spectrum of X-irradiated carbonated apatites precipitated from aqueous solutions was studied as a function of their carbonate content and drying temperature. When the latter increases from 25 to 400°C, the ESR spectrum is gradually modified and becomes similar to the spectrum of carbonated apatites, synthesized at high temperatures by solid state reactions. The latter ESR spectrum is dominated by CO33−-contributions whereas the spectrum of precipitated samples dried at 25°C can mainly be interpreted in terms of CO2−, CO3−, and O− ions. The behavior of these earlierreported CO2−, CO3−, and O− centers is now studied as a function of drying temperature. In addition, the Spin Hamiltonian parameters of the CO33− centers are determined and some other new paramagnetic radicals are discussed. It is shown that a CO32− ion at a phosphate lattice site (B-type substitution) may give rise to either a CO2−, CO3−, or CO33− radical on X-irradiation, depending on the sample preparation conditions. A surface CO32− ion may cause a surface CO2−, CO3−, or O− radical. From the reported results it is not unambiguously clear whether the CO33− ion detected in the samples with the relatively lowest carbonate content should be located on the surface or on a hydroxyl lattice site (A-type substitution). An important result is that the absolute concentration of the B-type CO33− ion increases with increasing carbonate content as was also the case for the earlier reported B-type radicals (isotropic CO2− and CO3−). On the other hand, the absolute concentration of the surface radicals decreases with increasing carbonate content. The reported results show that similar deconvolution techniques can be applied in the future for the study of ESR spectra of calcified tissues. This will allow a more efficient phenomenological investigation of the latter.
26 schema:genre article
27 schema:isAccessibleForFree false
28 schema:isPartOf N07bef721f4334ed9951d43273009b72c
29 N120417afe11f4319aa3b2c388c4dfefb
30 sg:journal.1089641
31 schema:keywords B-type
32 ESR spectra
33 Hamiltonian parameters
34 X-irradiation
35 absolute concentrations
36 addition
37 apatite
38 aqueous media
39 aqueous solution
40 behavior
41 calciumapatites
42 carbonate content
43 carbonated apatite
44 cases
45 center
46 concentration
47 conditions
48 content
49 contribution
50 deconvolution technique
51 effect
52 function
53 future
54 hand
55 high temperature
56 important results
57 increase
58 investigation
59 ions
60 ions increases
61 latter increases
62 lattice sites
63 low carbonate content
64 medium
65 paramagnetic radicals
66 parameters
67 phenomenological investigation
68 preparation conditions
69 radicals
70 reaction
71 reported results
72 results
73 sample preparation conditions
74 samples
75 sites
76 solid-state reaction
77 solution
78 spectra
79 spin-Hamiltonian parameters
80 state reaction
81 study
82 surface
83 surface radicals
84 technique
85 temperature
86 terms
87 tissue
88 schema:name The effect of carbonate content and drying temperature on the ESR-spectrum near g=2 of carbonated calciumapatites synthesized from aqueous media
89 schema:pagination 249-259
90 schema:productId N74846fc9b22743fe9dbf0cc4a31fbc44
91 N89144d8c85214bab854fe8ea6219dd2b
92 Nd949263752854792810c132c38964738
93 schema:sameAs https://app.dimensions.ai/details/publication/pub.1019969163
94 https://doi.org/10.1007/bf02556376
95 schema:sdDatePublished 2022-08-04T16:52
96 schema:sdLicense https://scigraph.springernature.com/explorer/license/
97 schema:sdPublisher N0fd25fade5374f16a87adce4709cd545
98 schema:url https://doi.org/10.1007/bf02556376
99 sgo:license sg:explorer/license/
100 sgo:sdDataset articles
101 rdf:type schema:ScholarlyArticle
102 N05dc16824e1340368db3386a89ce5679 rdf:first sg:person.012025432205.53
103 rdf:rest rdf:nil
104 N0677add0d25e4f0eacf8abb2d2efbd6e schema:inDefinedTermSet https://www.nlm.nih.gov/mesh/
105 schema:name Phosphates
106 rdf:type schema:DefinedTerm
107 N07bef721f4334ed9951d43273009b72c schema:volumeNumber 48
108 rdf:type schema:PublicationVolume
109 N09ebf99cf1494398aa48900eab7ff086 schema:inDefinedTermSet https://www.nlm.nih.gov/mesh/
110 schema:name Carbonates
111 rdf:type schema:DefinedTerm
112 N0fd25fade5374f16a87adce4709cd545 schema:name Springer Nature - SN SciGraph project
113 rdf:type schema:Organization
114 N120417afe11f4319aa3b2c388c4dfefb schema:issueNumber 4
115 rdf:type schema:PublicationIssue
116 N49e28cab39fe449695a0280b712092fb schema:inDefinedTermSet https://www.nlm.nih.gov/mesh/
117 schema:name Chemical Precipitation
118 rdf:type schema:DefinedTerm
119 N553f06e058b0481699097db748f546d3 schema:inDefinedTermSet https://www.nlm.nih.gov/mesh/
120 schema:name Oxygen
121 rdf:type schema:DefinedTerm
122 N5f7a28da41d343e7b036f2368136bfa2 rdf:first sg:person.012464542134.27
123 rdf:rest Ne3ab446def3e427d92ae642dea3196e3
124 N74846fc9b22743fe9dbf0cc4a31fbc44 schema:name dimensions_id
125 schema:value pub.1019969163
126 rdf:type schema:PropertyValue
127 N89144d8c85214bab854fe8ea6219dd2b schema:name doi
128 schema:value 10.1007/bf02556376
129 rdf:type schema:PropertyValue
130 N8c11151d3a454a9ab987146c29efbcb2 schema:inDefinedTermSet https://www.nlm.nih.gov/mesh/
131 schema:name Temperature
132 rdf:type schema:DefinedTerm
133 N9756dc5991ff42ab83c85af63c6124d8 schema:inDefinedTermSet https://www.nlm.nih.gov/mesh/
134 schema:name Apatites
135 rdf:type schema:DefinedTerm
136 Nb0999e6bf50c4a70bb24efdf1472a813 schema:inDefinedTermSet https://www.nlm.nih.gov/mesh/
137 schema:name Water
138 rdf:type schema:DefinedTerm
139 Nbd3a5f4f69d9445b925f83994e8af12a rdf:first sg:person.013511773553.17
140 rdf:rest N05dc16824e1340368db3386a89ce5679
141 Ncac1b097366b4210a2eb2f4f5a86345f schema:inDefinedTermSet https://www.nlm.nih.gov/mesh/
142 schema:name Electron Spin Resonance Spectroscopy
143 rdf:type schema:DefinedTerm
144 Ncde18fd196054ceeb5eb12b5f4f3df64 schema:inDefinedTermSet https://www.nlm.nih.gov/mesh/
145 schema:name Calcium
146 rdf:type schema:DefinedTerm
147 Nd0f99997b463458d9fcccf0940084eaf rdf:first sg:person.0711714601.87
148 rdf:rest N5f7a28da41d343e7b036f2368136bfa2
149 Nd806c29b6c544955ab4f0ec54ca5f930 schema:inDefinedTermSet https://www.nlm.nih.gov/mesh/
150 schema:name Calcium Carbonate
151 rdf:type schema:DefinedTerm
152 Nd949263752854792810c132c38964738 schema:name pubmed_id
153 schema:value 1647844
154 rdf:type schema:PropertyValue
155 Ne3ab446def3e427d92ae642dea3196e3 rdf:first sg:person.012301703367.81
156 rdf:rest Nbd3a5f4f69d9445b925f83994e8af12a
157 anzsrc-for:06 schema:inDefinedTermSet anzsrc-for:
158 schema:name Biological Sciences
159 rdf:type schema:DefinedTerm
160 anzsrc-for:0601 schema:inDefinedTermSet anzsrc-for:
161 schema:name Biochemistry and Cell Biology
162 rdf:type schema:DefinedTerm
163 anzsrc-for:09 schema:inDefinedTermSet anzsrc-for:
164 schema:name Engineering
165 rdf:type schema:DefinedTerm
166 anzsrc-for:0903 schema:inDefinedTermSet anzsrc-for:
167 schema:name Biomedical Engineering
168 rdf:type schema:DefinedTerm
169 anzsrc-for:11 schema:inDefinedTermSet anzsrc-for:
170 schema:name Medical and Health Sciences
171 rdf:type schema:DefinedTerm
172 anzsrc-for:1103 schema:inDefinedTermSet anzsrc-for:
173 schema:name Clinical Sciences
174 rdf:type schema:DefinedTerm
175 sg:journal.1089641 schema:issn 0171-967X
176 1432-0827
177 schema:name Calcified Tissue International
178 schema:publisher Springer Nature
179 rdf:type schema:Periodical
180 sg:person.012025432205.53 schema:affiliation grid-institutes:grid.5342.0
181 schema:familyName Boesman
182 schema:givenName E. R.
183 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.012025432205.53
184 rdf:type schema:Person
185 sg:person.012301703367.81 schema:affiliation grid-institutes:grid.5342.0
186 schema:familyName Naessens
187 schema:givenName D. E.
188 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.012301703367.81
189 rdf:type schema:Person
190 sg:person.012464542134.27 schema:affiliation grid-institutes:grid.5342.0
191 schema:familyName Verbeeck
192 schema:givenName R. M. H.
193 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.012464542134.27
194 rdf:type schema:Person
195 sg:person.013511773553.17 schema:affiliation grid-institutes:grid.5342.0
196 schema:familyName Matthys
197 schema:givenName P. F. A.
198 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.013511773553.17
199 rdf:type schema:Person
200 sg:person.0711714601.87 schema:affiliation grid-institutes:grid.5342.0
201 schema:familyName Callens
202 schema:givenName F. J.
203 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.0711714601.87
204 rdf:type schema:Person
205 sg:pub.10.1007/bf02409416 schema:sameAs https://app.dimensions.ai/details/publication/pub.1000704373
206 https://doi.org/10.1007/bf02409416
207 rdf:type schema:CreativeWork
208 sg:pub.10.1007/bf02441228 schema:sameAs https://app.dimensions.ai/details/publication/pub.1004907708
209 https://doi.org/10.1007/bf02441228
210 rdf:type schema:CreativeWork
211 sg:pub.10.1007/bf02556470 schema:sameAs https://app.dimensions.ai/details/publication/pub.1021964152
212 https://doi.org/10.1007/bf02556470
213 rdf:type schema:CreativeWork
214 sg:pub.10.1007/bf02563791 schema:sameAs https://app.dimensions.ai/details/publication/pub.1023952744
215 https://doi.org/10.1007/bf02563791
216 rdf:type schema:CreativeWork
217 sg:pub.10.1038/286425a0 schema:sameAs https://app.dimensions.ai/details/publication/pub.1034254499
218 https://doi.org/10.1038/286425a0
219 rdf:type schema:CreativeWork
220 grid-institutes:grid.5342.0 schema:alternateName Laboratory for Analytical Chemistry, State University Gent, Krijgslaan 281-S12, B-9000, Gent, Belgium
221 Laboratory of Crystallography and Study of the Solid State, State University Gent, Belgium
222 schema:name Laboratory for Analytical Chemistry, State University Gent, Krijgslaan 281-S12, B-9000, Gent, Belgium
223 Laboratory of Crystallography and Study of the Solid State, State University Gent, Belgium
224 rdf:type schema:Organization
 




Preview window. Press ESC to close (or click here)


...