Parameter determination of a thermal desorption model View Full Text


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Article Info

DATE

1994-04

AUTHORS

S. Zhou, G. Schulz-Ekloff, D. Popovic

ABSTRACT

A new method for the analysis of thermal desorption spectra is presented, based on the experimental peak maximum functions for temperatureTm(β) and pressurePm(β) and a rigorous mathematical treatment. The resonant heating rate βr is determined, satisfyingTm(βr)=Tr, whereTr is the resonant temperature defined byA exp(−Ed/(RTr))=1. Desorption energyEd and frequency factorA can be determined simultaneously with relatively high robustness towards statistical experimental errors as demonstrated by computer-simulated thermal desorption spectra. More... »

PAGES

767-788

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/bf02547158

DOI

http://dx.doi.org/10.1007/bf02547158

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1003642500


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