The use of thiobarbituric acid as a measure of fat oxidation View Full Text


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Article Info

DATE

1954-12

AUTHORS

C. G. Sidwell, Harold Salwin, Milada Benca, J. H. Mitchell

ABSTRACT

An evaluation of thiobarbituric acid (TBA) as an agent for the measurement of fat oxidation was made by the application of several empirical procedures to animal and vegetable fats. An extraction procedure was used for removing the products of oxidation. The reaction with TBA was conducted in a boiling water bath to produce a red color, which was then estimated spectrophotometrically. Fats stored at −20, 0, 72, and 100°F. (−29, −18, 22, and 38°C.) and fats oxidized by the active oxygen method (A.O.M.) and by ultraviolet irradiation were examined. It was found that the TBA test might be of value in following the course of oxidation of cottonseed oil and soybean oil in the A.O.M. apparatus. Higher TBA values were obtained for soybean oil than cottonseed oil at comparable peroxide values. This is of interest because of the greater tendency of soybean oil to develop oxidized flavors. The volatile reaction products of oxidation were collected in toluene, and a comparison of the TBA values at comparable peroxide values of lard, cottonseed and soybean oils showed that the soybean oil volatiles developed the greatest intensity of color. More... »

PAGES

603-606

References to SciGraph publications

  • 1933-06. An accelerated stability test using the peroxide value as an index in JOURNAL OF THE AMERICAN OIL CHEMISTS' SOCIETY
  • 1952-01. A comparative evaluation of several antioxidants in edible fats in JOURNAL OF THE AMERICAN OIL CHEMISTS' SOCIETY
  • 1954-03. Estimating carbonyl compounds in rancid fats and foods in JOURNAL OF THE AMERICAN OIL CHEMISTS' SOCIETY
  • 1945-04. Report of the committee on analysis of commercial fats and oils October, 1944 in JOURNAL OF THE AMERICAN OIL CHEMISTS' SOCIETY
  • 1951-03. The flavor problem of soybean oil. VIII. Linolenic acid in JOURNAL OF THE AMERICAN OIL CHEMISTS' SOCIETY
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    http://scigraph.springernature.com/pub.10.1007/bf02545589

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    http://dx.doi.org/10.1007/bf02545589

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