Conjugation of polyunsaturated fats: Activity of some group VIII metal compounds View Full Text


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Article Info

DATE

1971-04

AUTHORS

W. J. DeJarlais, L. E. Gast

ABSTRACT

Conjugation of methyl linoleate was studied by treatment with RHC3 orcisCl2[(C6H5)3]P2PtSnCl2. PdCl2 appeared as effective as RhCl3 in hot alcohols in conjugating linolenate but PdCl2 decomposed to metal. Both RhCl3 and the Pt-eomplex catalyzed transesterification in alcohols, especially the latter. When the conjugation is carried out in methanol at 180 C, the Pt-complex yielded as much as 64% conjugated dienes from linoleate in 24 hr. However, typical results inn-butyl carbitol at 150 and 180 C were only 25–35% conjugated dienes as methyl esters with either RhCl3 or the Pt-complex. More... »

PAGES

157-159

References to SciGraph publications

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/bf02544940

DOI

http://dx.doi.org/10.1007/bf02544940

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1040668103


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