Conjugation of polyunsaturated fats: Activity of some group VIII metal compounds View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

1971-04

AUTHORS

W. J. DeJarlais, L. E. Gast

ABSTRACT

Conjugation of methyl linoleate was studied by treatment with RHC3 orcisCl2[(C6H5)3]P2PtSnCl2. PdCl2 appeared as effective as RhCl3 in hot alcohols in conjugating linolenate but PdCl2 decomposed to metal. Both RhCl3 and the Pt-eomplex catalyzed transesterification in alcohols, especially the latter. When the conjugation is carried out in methanol at 180 C, the Pt-complex yielded as much as 64% conjugated dienes from linoleate in 24 hr. However, typical results inn-butyl carbitol at 150 and 180 C were only 25–35% conjugated dienes as methyl esters with either RhCl3 or the Pt-complex. More... »

PAGES

157-159

References to SciGraph publications

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/bf02544940

DOI

http://dx.doi.org/10.1007/bf02544940

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1040668103


Indexing Status Check whether this publication has been indexed by Scopus and Web Of Science using the SN Indexing Status Tool
Incoming Citations Browse incoming citations for this publication using opencitations.net

JSON-LD is the canonical representation for SciGraph data.

TIP: You can open this SciGraph record using an external JSON-LD service: JSON-LD Playground Google SDTT

[
  {
    "@context": "https://springernature.github.io/scigraph/jsonld/sgcontext.json", 
    "about": [
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/1109", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Neurosciences", 
        "type": "DefinedTerm"
      }, 
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/11", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Medical and Health Sciences", 
        "type": "DefinedTerm"
      }
    ], 
    "author": [
      {
        "familyName": "DeJarlais", 
        "givenName": "W. J.", 
        "id": "sg:person.067302151.67", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.067302151.67"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Agricultural Research Service", 
          "id": "https://www.grid.ac/institutes/grid.463419.d", 
          "name": [
            "Northern Regional Research Laboratory, 61604, Peoria, Illionis"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Gast", 
        "givenName": "L. E.", 
        "id": "sg:person.012611112157.09", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.012611112157.09"
        ], 
        "type": "Person"
      }
    ], 
    "citation": [
      {
        "id": "https://doi.org/10.1039/tf9555100230", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1020048148"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1007/bf02637929", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1021616704", 
          "https://doi.org/10.1007/bf02637929"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1007/bf02908368", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1029810214", 
          "https://doi.org/10.1007/bf02908368"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/ie50470a018", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1055629964"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/ja00967a013", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1055757746"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/ja00983a010", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1055758835"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/ja00990a009", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1055759319"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/jo01280a602", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1056010284"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.3891/acta.chem.scand.16-0323", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1071489774"
        ], 
        "type": "CreativeWork"
      }
    ], 
    "datePublished": "1971-04", 
    "datePublishedReg": "1971-04-01", 
    "description": "Conjugation of methyl linoleate was studied by treatment with RHC3 orcisCl2[(C6H5)3]P2PtSnCl2. PdCl2 appeared as effective as RhCl3 in hot alcohols in conjugating linolenate but PdCl2 decomposed to metal. Both RhCl3 and the Pt-eomplex catalyzed transesterification in alcohols, especially the latter. When the conjugation is carried out in methanol at 180 C, the Pt-complex yielded as much as 64% conjugated dienes from linoleate in 24 hr. However, typical results inn-butyl carbitol at 150 and 180 C were only 25\u201335% conjugated dienes as methyl esters with either RhCl3 or the Pt-complex.", 
    "genre": "research_article", 
    "id": "sg:pub.10.1007/bf02544940", 
    "inLanguage": [
      "en"
    ], 
    "isAccessibleForFree": false, 
    "isPartOf": [
      {
        "id": "sg:journal.1082739", 
        "issn": [
          "0003-021X", 
          "1558-9331"
        ], 
        "name": "Journal of the American Oil Chemists' Society", 
        "type": "Periodical"
      }, 
      {
        "issueNumber": "4", 
        "type": "PublicationIssue"
      }, 
      {
        "type": "PublicationVolume", 
        "volumeNumber": "48"
      }
    ], 
    "name": "Conjugation of polyunsaturated fats: Activity of some group VIII metal compounds", 
    "pagination": "157-159", 
    "productId": [
      {
        "name": "readcube_id", 
        "type": "PropertyValue", 
        "value": [
          "c1ba11d0c53d8e0af2a8c2ff1ea47e1b8d1c005a3567af5fa631b2384f480ac6"
        ]
      }, 
      {
        "name": "doi", 
        "type": "PropertyValue", 
        "value": [
          "10.1007/bf02544940"
        ]
      }, 
      {
        "name": "dimensions_id", 
        "type": "PropertyValue", 
        "value": [
          "pub.1040668103"
        ]
      }
    ], 
    "sameAs": [
      "https://doi.org/10.1007/bf02544940", 
      "https://app.dimensions.ai/details/publication/pub.1040668103"
    ], 
    "sdDataset": "articles", 
    "sdDatePublished": "2019-04-11T00:22", 
    "sdLicense": "https://scigraph.springernature.com/explorer/license/", 
    "sdPublisher": {
      "name": "Springer Nature - SN SciGraph project", 
      "type": "Organization"
    }, 
    "sdSource": "s3://com-uberresearch-data-dimensions-target-20181106-alternative/cleanup/v134/2549eaecd7973599484d7c17b260dba0a4ecb94b/merge/v9/a6c9fde33151104705d4d7ff012ea9563521a3ce/jats-lookup/v90/0000000001_0000000264/records_8695_00000543.jsonl", 
    "type": "ScholarlyArticle", 
    "url": "http://link.springer.com/10.1007%2FBF02544940"
  }
]
 

Download the RDF metadata as:  json-ld nt turtle xml License info

HOW TO GET THIS DATA PROGRAMMATICALLY:

JSON-LD is a popular format for linked data which is fully compatible with JSON.

curl -H 'Accept: application/ld+json' 'https://scigraph.springernature.com/pub.10.1007/bf02544940'

N-Triples is a line-based linked data format ideal for batch operations.

curl -H 'Accept: application/n-triples' 'https://scigraph.springernature.com/pub.10.1007/bf02544940'

Turtle is a human-readable linked data format.

curl -H 'Accept: text/turtle' 'https://scigraph.springernature.com/pub.10.1007/bf02544940'

RDF/XML is a standard XML format for linked data.

curl -H 'Accept: application/rdf+xml' 'https://scigraph.springernature.com/pub.10.1007/bf02544940'


 

This table displays all metadata directly associated to this object as RDF triples.

96 TRIPLES      21 PREDICATES      36 URIs      19 LITERALS      7 BLANK NODES

Subject Predicate Object
1 sg:pub.10.1007/bf02544940 schema:about anzsrc-for:11
2 anzsrc-for:1109
3 schema:author N102cbea9d97e4e849623c09b81ad1ce5
4 schema:citation sg:pub.10.1007/bf02637929
5 sg:pub.10.1007/bf02908368
6 https://doi.org/10.1021/ie50470a018
7 https://doi.org/10.1021/ja00967a013
8 https://doi.org/10.1021/ja00983a010
9 https://doi.org/10.1021/ja00990a009
10 https://doi.org/10.1021/jo01280a602
11 https://doi.org/10.1039/tf9555100230
12 https://doi.org/10.3891/acta.chem.scand.16-0323
13 schema:datePublished 1971-04
14 schema:datePublishedReg 1971-04-01
15 schema:description Conjugation of methyl linoleate was studied by treatment with RHC3 orcisCl2[(C6H5)3]P2PtSnCl2. PdCl2 appeared as effective as RhCl3 in hot alcohols in conjugating linolenate but PdCl2 decomposed to metal. Both RhCl3 and the Pt-eomplex catalyzed transesterification in alcohols, especially the latter. When the conjugation is carried out in methanol at 180 C, the Pt-complex yielded as much as 64% conjugated dienes from linoleate in 24 hr. However, typical results inn-butyl carbitol at 150 and 180 C were only 25–35% conjugated dienes as methyl esters with either RhCl3 or the Pt-complex.
16 schema:genre research_article
17 schema:inLanguage en
18 schema:isAccessibleForFree false
19 schema:isPartOf N500b4f104d4d4465a4be8d193ae22386
20 Na316ea33fffa40e695aad57e8eac9611
21 sg:journal.1082739
22 schema:name Conjugation of polyunsaturated fats: Activity of some group VIII metal compounds
23 schema:pagination 157-159
24 schema:productId N5d94177daeee4162948b81969934c3d2
25 N799a947805ed402292859a4f5d9ada10
26 N9cbd76177e0f4ceb8156c0b732bf9488
27 schema:sameAs https://app.dimensions.ai/details/publication/pub.1040668103
28 https://doi.org/10.1007/bf02544940
29 schema:sdDatePublished 2019-04-11T00:22
30 schema:sdLicense https://scigraph.springernature.com/explorer/license/
31 schema:sdPublisher Na11360e9778a4b1d9a7306e38dd81bd6
32 schema:url http://link.springer.com/10.1007%2FBF02544940
33 sgo:license sg:explorer/license/
34 sgo:sdDataset articles
35 rdf:type schema:ScholarlyArticle
36 N102cbea9d97e4e849623c09b81ad1ce5 rdf:first sg:person.067302151.67
37 rdf:rest N58de376a4ac041c8bd336f1f479be417
38 N500b4f104d4d4465a4be8d193ae22386 schema:volumeNumber 48
39 rdf:type schema:PublicationVolume
40 N58de376a4ac041c8bd336f1f479be417 rdf:first sg:person.012611112157.09
41 rdf:rest rdf:nil
42 N5d94177daeee4162948b81969934c3d2 schema:name readcube_id
43 schema:value c1ba11d0c53d8e0af2a8c2ff1ea47e1b8d1c005a3567af5fa631b2384f480ac6
44 rdf:type schema:PropertyValue
45 N799a947805ed402292859a4f5d9ada10 schema:name dimensions_id
46 schema:value pub.1040668103
47 rdf:type schema:PropertyValue
48 N9cbd76177e0f4ceb8156c0b732bf9488 schema:name doi
49 schema:value 10.1007/bf02544940
50 rdf:type schema:PropertyValue
51 Na11360e9778a4b1d9a7306e38dd81bd6 schema:name Springer Nature - SN SciGraph project
52 rdf:type schema:Organization
53 Na316ea33fffa40e695aad57e8eac9611 schema:issueNumber 4
54 rdf:type schema:PublicationIssue
55 anzsrc-for:11 schema:inDefinedTermSet anzsrc-for:
56 schema:name Medical and Health Sciences
57 rdf:type schema:DefinedTerm
58 anzsrc-for:1109 schema:inDefinedTermSet anzsrc-for:
59 schema:name Neurosciences
60 rdf:type schema:DefinedTerm
61 sg:journal.1082739 schema:issn 0003-021X
62 1558-9331
63 schema:name Journal of the American Oil Chemists' Society
64 rdf:type schema:Periodical
65 sg:person.012611112157.09 schema:affiliation https://www.grid.ac/institutes/grid.463419.d
66 schema:familyName Gast
67 schema:givenName L. E.
68 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.012611112157.09
69 rdf:type schema:Person
70 sg:person.067302151.67 schema:familyName DeJarlais
71 schema:givenName W. J.
72 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.067302151.67
73 rdf:type schema:Person
74 sg:pub.10.1007/bf02637929 schema:sameAs https://app.dimensions.ai/details/publication/pub.1021616704
75 https://doi.org/10.1007/bf02637929
76 rdf:type schema:CreativeWork
77 sg:pub.10.1007/bf02908368 schema:sameAs https://app.dimensions.ai/details/publication/pub.1029810214
78 https://doi.org/10.1007/bf02908368
79 rdf:type schema:CreativeWork
80 https://doi.org/10.1021/ie50470a018 schema:sameAs https://app.dimensions.ai/details/publication/pub.1055629964
81 rdf:type schema:CreativeWork
82 https://doi.org/10.1021/ja00967a013 schema:sameAs https://app.dimensions.ai/details/publication/pub.1055757746
83 rdf:type schema:CreativeWork
84 https://doi.org/10.1021/ja00983a010 schema:sameAs https://app.dimensions.ai/details/publication/pub.1055758835
85 rdf:type schema:CreativeWork
86 https://doi.org/10.1021/ja00990a009 schema:sameAs https://app.dimensions.ai/details/publication/pub.1055759319
87 rdf:type schema:CreativeWork
88 https://doi.org/10.1021/jo01280a602 schema:sameAs https://app.dimensions.ai/details/publication/pub.1056010284
89 rdf:type schema:CreativeWork
90 https://doi.org/10.1039/tf9555100230 schema:sameAs https://app.dimensions.ai/details/publication/pub.1020048148
91 rdf:type schema:CreativeWork
92 https://doi.org/10.3891/acta.chem.scand.16-0323 schema:sameAs https://app.dimensions.ai/details/publication/pub.1071489774
93 rdf:type schema:CreativeWork
94 https://www.grid.ac/institutes/grid.463419.d schema:alternateName Agricultural Research Service
95 schema:name Northern Regional Research Laboratory, 61604, Peoria, Illionis
96 rdf:type schema:Organization
 




Preview window. Press ESC to close (or click here)


...