Photooxidation of soybean oils as affected by triacylglycerol composition and structure View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

1993-02

AUTHORS

W. E. Neff, T. L. Mounts, W. M. Rinsch, H. Konishi

ABSTRACT

The photooxidation of soybean oil was determined and correlated with triacylglycerol composition and structure. Purified triacylglycerols were photooxidized at room temperature under fluorescent light. Rates of peroxide formation and total headspace volatiles were related positively (P<0.5 significance) to oxidizability (r=0.75, r=0.76); content of linolenic acid (r=0.80, r=0.85) and linoleic acid (r=0.61, r=0.57); linoleic acid on carbon 2 (r=0.64, r=0.64); and average number of double bonds (r=0.76, r=0.76). Negative correlations were observed with respect to oleic acid (r=−0.70, r=−0.70). Soybean oil stability was decreased by linolenic acid-containing triacylglycerols and increased by oleic acid-containing triacylglycerols. Trilinoleoylglycerol and dilinoleoyl-oleoylglycerol were the most important oxidation product precursors. However, for high-linolenic acid soybean oil, dilinoleoyl-linolenoylglycerol and trilinoleoylglycerol were the most important oxidation product precursors. The most abundant volatile produced from thermal decomposition at 140°C of photooxidized triacylglycerols was 2-heptenal, except for high-linolenic acid oils, where the most abundant volatile was propanal. The photooxidative stability of soybean oil triacylglycerols with respect to composition and structure is of interest for the development of soybean varieties with oils of improved odor and flavor stability. More... »

PAGES

163-168

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/bf02542620

DOI

http://dx.doi.org/10.1007/bf02542620

DIMENSIONS

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140 schema:name Food Quality and Safety Research, National Center for Agricultural Utilization Research, Agricultural Research Service, United States Department of Agriculture, 61604, Peoria, Illinois
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144 schema:name Food Quality and Safety Research, National Center for Agricultural Utilization Research, Agricultural Research Service, United States Department of Agriculture, 61604, Peoria, Illinois
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