Preparation of alcohols from cyclic fatty acids View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

1965-10

AUTHORS

E. W. Bell, J. P. Friedrich, L. E. Gast, J. C. Cowan

ABSTRACT

Saturated C18- and C20-cyclic alcohols have been prepared by catalytic hydrogenation of methyl esters from cyclized linseed monomeric acids, purified saturated C18-cyclic acids, ethylene adduct of conjugated soybean fatty acids, and ethylene adduct of conjugated octadecadienoic acids. The cyclic alcohols have also been prepared from free acids of crude cyclic linseed, cyclic linseed monomeric, and ethylene adduct of 9,11,t,t,-octadecadienoic. Conversion of esters and acids was 88–99% by hydroxyl determination; by gas-liquid chromatographic analysis, almost quantitative Hydrogenations were carried out with 10%, by weight, copper chromite catalyst, an initial hydrogen pressure of 2,100 psi, and a temperature of 280C for 3–5 hr. Preliminary evaluations indicate that saturated C18- and C20-cyclic alcohols have a potential use in cosmetic formulations. More... »

PAGES

876-878

References to SciGraph publications

  • 1961-07. Liquid C-18 saturated acids derived from linseed oil in JOURNAL OF THE AMERICAN OIL CHEMISTS' SOCIETY
  • 1962-12. Liquid C-18 saturated monocarboxylic acids-their preparation, characteristics, and potential uses in JOURNAL OF THE AMERICAN OIL CHEMISTS' SOCIETY
  • 1963-10. Methods for improving yields of cyclic acid from linseed oil in JOURNAL OF THE AMERICAN OIL CHEMISTS' SOCIETY
  • 1962-09. Reaction of ethylene with C18 monocarboxylic dienoic acids in JOURNAL OF THE AMERICAN OIL CHEMISTS' SOCIETY
  • Identifiers

    URI

    http://scigraph.springernature.com/pub.10.1007/bf02541182

    DOI

    http://dx.doi.org/10.1007/bf02541182

    DIMENSIONS

    https://app.dimensions.ai/details/publication/pub.1035746325


    Indexing Status Check whether this publication has been indexed by Scopus and Web Of Science using the SN Indexing Status Tool
    Incoming Citations Browse incoming citations for this publication using opencitations.net

    JSON-LD is the canonical representation for SciGraph data.

    TIP: You can open this SciGraph record using an external JSON-LD service: JSON-LD Playground Google SDTT

    [
      {
        "@context": "https://springernature.github.io/scigraph/jsonld/sgcontext.json", 
        "about": [
          {
            "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/0306", 
            "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
            "name": "Physical Chemistry (incl. Structural)", 
            "type": "DefinedTerm"
          }, 
          {
            "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/03", 
            "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
            "name": "Chemical Sciences", 
            "type": "DefinedTerm"
          }
        ], 
        "author": [
          {
            "affiliation": {
              "alternateName": "Agricultural Research Service", 
              "id": "https://www.grid.ac/institutes/grid.463419.d", 
              "name": [
                "Northern Regional Research Laboratory, Peoria, Illinois"
              ], 
              "type": "Organization"
            }, 
            "familyName": "Bell", 
            "givenName": "E. W.", 
            "id": "sg:person.015034154213.63", 
            "sameAs": [
              "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.015034154213.63"
            ], 
            "type": "Person"
          }, 
          {
            "affiliation": {
              "alternateName": "Agricultural Research Service", 
              "id": "https://www.grid.ac/institutes/grid.463419.d", 
              "name": [
                "Northern Regional Research Laboratory, Peoria, Illinois"
              ], 
              "type": "Organization"
            }, 
            "familyName": "Friedrich", 
            "givenName": "J. P.", 
            "id": "sg:person.07724044013.86", 
            "sameAs": [
              "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.07724044013.86"
            ], 
            "type": "Person"
          }, 
          {
            "affiliation": {
              "alternateName": "Agricultural Research Service", 
              "id": "https://www.grid.ac/institutes/grid.463419.d", 
              "name": [
                "Northern Regional Research Laboratory, Peoria, Illinois"
              ], 
              "type": "Organization"
            }, 
            "familyName": "Gast", 
            "givenName": "L. E.", 
            "id": "sg:person.012611112157.09", 
            "sameAs": [
              "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.012611112157.09"
            ], 
            "type": "Person"
          }, 
          {
            "affiliation": {
              "alternateName": "Agricultural Research Service", 
              "id": "https://www.grid.ac/institutes/grid.463419.d", 
              "name": [
                "Northern Regional Research Laboratory, Peoria, Illinois"
              ], 
              "type": "Organization"
            }, 
            "familyName": "Cowan", 
            "givenName": "J. C.", 
            "id": "sg:person.010137462221.36", 
            "sameAs": [
              "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.010137462221.36"
            ], 
            "type": "Person"
          }
        ], 
        "citation": [
          {
            "id": "sg:pub.10.1007/bf02632865", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1014088398", 
              "https://doi.org/10.1007/bf02632865"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "sg:pub.10.1007/bf02822472", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1027031804", 
              "https://doi.org/10.1007/bf02822472"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "sg:pub.10.1007/bf02633576", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1028032453", 
              "https://doi.org/10.1007/bf02633576"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "sg:pub.10.1007/bf02672545", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1046619005", 
              "https://doi.org/10.1007/bf02672545"
            ], 
            "type": "CreativeWork"
          }
        ], 
        "datePublished": "1965-10", 
        "datePublishedReg": "1965-10-01", 
        "description": "Saturated C18- and C20-cyclic alcohols have been prepared by catalytic hydrogenation of methyl esters from cyclized linseed monomeric acids, purified saturated C18-cyclic acids, ethylene adduct of conjugated soybean fatty acids, and ethylene adduct of conjugated octadecadienoic acids. The cyclic alcohols have also been prepared from free acids of crude cyclic linseed, cyclic linseed monomeric, and ethylene adduct of 9,11,t,t,-octadecadienoic. Conversion of esters and acids was 88\u201399% by hydroxyl determination; by gas-liquid chromatographic analysis, almost quantitative Hydrogenations were carried out with 10%, by weight, copper chromite catalyst, an initial hydrogen pressure of 2,100 psi, and a temperature of 280C for 3\u20135 hr. Preliminary evaluations indicate that saturated C18- and C20-cyclic alcohols have a potential use in cosmetic formulations.", 
        "genre": "non_research_article", 
        "id": "sg:pub.10.1007/bf02541182", 
        "inLanguage": [
          "en"
        ], 
        "isAccessibleForFree": false, 
        "isPartOf": [
          {
            "id": "sg:journal.1082739", 
            "issn": [
              "0003-021X", 
              "1558-9331"
            ], 
            "name": "Journal of the American Oil Chemists' Society", 
            "type": "Periodical"
          }, 
          {
            "issueNumber": "10", 
            "type": "PublicationIssue"
          }, 
          {
            "type": "PublicationVolume", 
            "volumeNumber": "42"
          }
        ], 
        "name": "Preparation of alcohols from cyclic fatty acids", 
        "pagination": "876-878", 
        "productId": [
          {
            "name": "readcube_id", 
            "type": "PropertyValue", 
            "value": [
              "aa485889f364b82924b57e1743a6fc4fcaa03c027078eaf679e12522255e03f5"
            ]
          }, 
          {
            "name": "doi", 
            "type": "PropertyValue", 
            "value": [
              "10.1007/bf02541182"
            ]
          }, 
          {
            "name": "dimensions_id", 
            "type": "PropertyValue", 
            "value": [
              "pub.1035746325"
            ]
          }
        ], 
        "sameAs": [
          "https://doi.org/10.1007/bf02541182", 
          "https://app.dimensions.ai/details/publication/pub.1035746325"
        ], 
        "sdDataset": "articles", 
        "sdDatePublished": "2019-04-10T19:56", 
        "sdLicense": "https://scigraph.springernature.com/explorer/license/", 
        "sdPublisher": {
          "name": "Springer Nature - SN SciGraph project", 
          "type": "Organization"
        }, 
        "sdSource": "s3://com-uberresearch-data-dimensions-target-20181106-alternative/cleanup/v134/2549eaecd7973599484d7c17b260dba0a4ecb94b/merge/v9/a6c9fde33151104705d4d7ff012ea9563521a3ce/jats-lookup/v90/0000000001_0000000264/records_8681_00000506.jsonl", 
        "type": "ScholarlyArticle", 
        "url": "http://link.springer.com/10.1007%2FBF02541182"
      }
    ]
     

    Download the RDF metadata as:  json-ld nt turtle xml License info

    HOW TO GET THIS DATA PROGRAMMATICALLY:

    JSON-LD is a popular format for linked data which is fully compatible with JSON.

    curl -H 'Accept: application/ld+json' 'https://scigraph.springernature.com/pub.10.1007/bf02541182'

    N-Triples is a line-based linked data format ideal for batch operations.

    curl -H 'Accept: application/n-triples' 'https://scigraph.springernature.com/pub.10.1007/bf02541182'

    Turtle is a human-readable linked data format.

    curl -H 'Accept: text/turtle' 'https://scigraph.springernature.com/pub.10.1007/bf02541182'

    RDF/XML is a standard XML format for linked data.

    curl -H 'Accept: application/rdf+xml' 'https://scigraph.springernature.com/pub.10.1007/bf02541182'


     

    This table displays all metadata directly associated to this object as RDF triples.

    98 TRIPLES      21 PREDICATES      31 URIs      19 LITERALS      7 BLANK NODES

    Subject Predicate Object
    1 sg:pub.10.1007/bf02541182 schema:about anzsrc-for:03
    2 anzsrc-for:0306
    3 schema:author N82fd3673f7674987bee66b4d1c51feeb
    4 schema:citation sg:pub.10.1007/bf02632865
    5 sg:pub.10.1007/bf02633576
    6 sg:pub.10.1007/bf02672545
    7 sg:pub.10.1007/bf02822472
    8 schema:datePublished 1965-10
    9 schema:datePublishedReg 1965-10-01
    10 schema:description Saturated C18- and C20-cyclic alcohols have been prepared by catalytic hydrogenation of methyl esters from cyclized linseed monomeric acids, purified saturated C18-cyclic acids, ethylene adduct of conjugated soybean fatty acids, and ethylene adduct of conjugated octadecadienoic acids. The cyclic alcohols have also been prepared from free acids of crude cyclic linseed, cyclic linseed monomeric, and ethylene adduct of 9,11,t,t,-octadecadienoic. Conversion of esters and acids was 88–99% by hydroxyl determination; by gas-liquid chromatographic analysis, almost quantitative Hydrogenations were carried out with 10%, by weight, copper chromite catalyst, an initial hydrogen pressure of 2,100 psi, and a temperature of 280C for 3–5 hr. Preliminary evaluations indicate that saturated C18- and C20-cyclic alcohols have a potential use in cosmetic formulations.
    11 schema:genre non_research_article
    12 schema:inLanguage en
    13 schema:isAccessibleForFree false
    14 schema:isPartOf N2686c2d83d5c4b48ba9a97b9793df175
    15 N97b2fde2f0744e6f8f5322633e98183a
    16 sg:journal.1082739
    17 schema:name Preparation of alcohols from cyclic fatty acids
    18 schema:pagination 876-878
    19 schema:productId N2c2d72f178464db8b9cd58930d1e8770
    20 N6e3326c950f04dee8713eebe9659fede
    21 Nb481d59bdb904cc1ba1b6cad37d87f15
    22 schema:sameAs https://app.dimensions.ai/details/publication/pub.1035746325
    23 https://doi.org/10.1007/bf02541182
    24 schema:sdDatePublished 2019-04-10T19:56
    25 schema:sdLicense https://scigraph.springernature.com/explorer/license/
    26 schema:sdPublisher Nafec46ee47a740ababdf7c7d53a444d3
    27 schema:url http://link.springer.com/10.1007%2FBF02541182
    28 sgo:license sg:explorer/license/
    29 sgo:sdDataset articles
    30 rdf:type schema:ScholarlyArticle
    31 N2686c2d83d5c4b48ba9a97b9793df175 schema:issueNumber 10
    32 rdf:type schema:PublicationIssue
    33 N2c2d72f178464db8b9cd58930d1e8770 schema:name dimensions_id
    34 schema:value pub.1035746325
    35 rdf:type schema:PropertyValue
    36 N58eeec99a1a74f63a509c745dcdfb100 rdf:first sg:person.010137462221.36
    37 rdf:rest rdf:nil
    38 N6e3326c950f04dee8713eebe9659fede schema:name doi
    39 schema:value 10.1007/bf02541182
    40 rdf:type schema:PropertyValue
    41 N82fd3673f7674987bee66b4d1c51feeb rdf:first sg:person.015034154213.63
    42 rdf:rest Nc1c2e2c22680467b9a3e34f246af9dfa
    43 N91ded110d39e432c9fc200f922ef967f rdf:first sg:person.012611112157.09
    44 rdf:rest N58eeec99a1a74f63a509c745dcdfb100
    45 N97b2fde2f0744e6f8f5322633e98183a schema:volumeNumber 42
    46 rdf:type schema:PublicationVolume
    47 Nafec46ee47a740ababdf7c7d53a444d3 schema:name Springer Nature - SN SciGraph project
    48 rdf:type schema:Organization
    49 Nb481d59bdb904cc1ba1b6cad37d87f15 schema:name readcube_id
    50 schema:value aa485889f364b82924b57e1743a6fc4fcaa03c027078eaf679e12522255e03f5
    51 rdf:type schema:PropertyValue
    52 Nc1c2e2c22680467b9a3e34f246af9dfa rdf:first sg:person.07724044013.86
    53 rdf:rest N91ded110d39e432c9fc200f922ef967f
    54 anzsrc-for:03 schema:inDefinedTermSet anzsrc-for:
    55 schema:name Chemical Sciences
    56 rdf:type schema:DefinedTerm
    57 anzsrc-for:0306 schema:inDefinedTermSet anzsrc-for:
    58 schema:name Physical Chemistry (incl. Structural)
    59 rdf:type schema:DefinedTerm
    60 sg:journal.1082739 schema:issn 0003-021X
    61 1558-9331
    62 schema:name Journal of the American Oil Chemists' Society
    63 rdf:type schema:Periodical
    64 sg:person.010137462221.36 schema:affiliation https://www.grid.ac/institutes/grid.463419.d
    65 schema:familyName Cowan
    66 schema:givenName J. C.
    67 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.010137462221.36
    68 rdf:type schema:Person
    69 sg:person.012611112157.09 schema:affiliation https://www.grid.ac/institutes/grid.463419.d
    70 schema:familyName Gast
    71 schema:givenName L. E.
    72 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.012611112157.09
    73 rdf:type schema:Person
    74 sg:person.015034154213.63 schema:affiliation https://www.grid.ac/institutes/grid.463419.d
    75 schema:familyName Bell
    76 schema:givenName E. W.
    77 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.015034154213.63
    78 rdf:type schema:Person
    79 sg:person.07724044013.86 schema:affiliation https://www.grid.ac/institutes/grid.463419.d
    80 schema:familyName Friedrich
    81 schema:givenName J. P.
    82 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.07724044013.86
    83 rdf:type schema:Person
    84 sg:pub.10.1007/bf02632865 schema:sameAs https://app.dimensions.ai/details/publication/pub.1014088398
    85 https://doi.org/10.1007/bf02632865
    86 rdf:type schema:CreativeWork
    87 sg:pub.10.1007/bf02633576 schema:sameAs https://app.dimensions.ai/details/publication/pub.1028032453
    88 https://doi.org/10.1007/bf02633576
    89 rdf:type schema:CreativeWork
    90 sg:pub.10.1007/bf02672545 schema:sameAs https://app.dimensions.ai/details/publication/pub.1046619005
    91 https://doi.org/10.1007/bf02672545
    92 rdf:type schema:CreativeWork
    93 sg:pub.10.1007/bf02822472 schema:sameAs https://app.dimensions.ai/details/publication/pub.1027031804
    94 https://doi.org/10.1007/bf02822472
    95 rdf:type schema:CreativeWork
    96 https://www.grid.ac/institutes/grid.463419.d schema:alternateName Agricultural Research Service
    97 schema:name Northern Regional Research Laboratory, Peoria, Illinois
    98 rdf:type schema:Organization
     




    Preview window. Press ESC to close (or click here)


    ...