Positional and geometrical isomers of linoleic acid in partially hydrogenated oils View Full Text


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Article Info

DATE

1992-02

AUTHORS

W. M. N. Ratnayake, G. Pelletier

ABSTRACT

The geometrical and positional isomers of linoleic acid of a partially hydrogenated canola oil-based spread were isolated and identified. Through partial hydrazine reduction and mass spectral studies,cis-9,trans-13 octadecadienoic acid was identified as the major isomer. Other quantitatively important isomers characterized werecis-9,trans-12;trans-9,cis-12 andcis-9,cis-15. These four were also the major isomers in margarine based on common vegetable oils. A number of minor isomers were detected and some structures identified weretrans-9,trans-12;trans-8,cis-12;trans-8,cis-13;cis-8,cis-13;trans-9,cis-15;trans-10,cis-15 andcis-9,cis-13. The proportions of the various isomers are given for some margarines in the Canadian retail market. The amounts oftrans-9,trans-12 isomer in Canadian margarines were generally below 0.5% of the total fatty acids. More... »

PAGES

95-105

References to SciGraph publications

  • 1981-03. Nutritional effects of hydrogenated soya oil in JOURNAL OF THE AMERICAN OIL CHEMISTS' SOCIETY
  • 1986-10. A comparison of pyrrolidide and picolinyl ester derivatives for the identification of fatty acids in natural samples by gas chromatography-mass spectrometry in LIPIDS
  • 1985-04. Lipids in margarines and margarine-like foods in JOURNAL OF THE AMERICAN OIL CHEMISTS' SOCIETY
  • 1987-08. Octadecatrienoic fatty acid isomers of partially hydrogenated soybean oil in JOURNAL OF THE AMERICAN OIL CHEMISTS' SOCIETY
  • 1983. trans- and Positional Isomers of Common Fatty Acids in ADVANCES IN NUTRITIONAL RESEARCH
  • 1987-09. Mass spectra of the picolinyl ester derivatives of some non-methylene-interrupted octadecadienoic acids in LIPIDS
  • 1982-11. cis-trans isomerization of unsaturated fatty acids withp-toluenesulfinic acid in JOURNAL OF THE AMERICAN OIL CHEMISTS' SOCIETY
  • 1967-01. Mechanism of lipoxidase reaction. I. Specificity of hydroperoxidation of linoleic acid in LIPIDS
  • 1990-11. Determination ofcis andtrans-Octadecenoic acids in margarines by gas liquid chromatography-infrared spectrophotometry in JOURNAL OF THE AMERICAN OIL CHEMISTS' SOCIETY
  • 1987-04. Mass spectra of the picolinyl esters of isomeric mono- and dienoic fatty acids in LIPIDS
  • 1990-12. Studies on the mechanism of the hydrazine reduction reaction: Applications to selected monoethylenic, diethylenic and triethylenic fatty acids ofcis configurations in JOURNAL OF THE AMERICAN OIL CHEMISTS' SOCIETY
  • 1979-06. Identification of novel octadecadienoic fatty acids in the seaweedCladophora rupestris through oxidative ozonolysis of the alcohols prepared from the acids in LIPIDS
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    http://scigraph.springernature.com/pub.10.1007/bf02540557

    DOI

    http://dx.doi.org/10.1007/bf02540557

    DIMENSIONS

    https://app.dimensions.ai/details/publication/pub.1029512093


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