Analysis of vegetable oil volatiles by multiple headspace extraction View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

1990-11

AUTHORS

J. M. Snyder, T. L. Mounts

ABSTRACT

Quantitative determination of the volatiles produced from oxidized vegetable oils is an important indicator of oil quality. Five vegetable oils, low-erucic acid rapeseed, corn, soybean, sunflower and high oleic sunflower, were stored at 60°C for four and eight days to yield oils with several levels of oxidation. Peroxide values of the fresh oils ranged from 0.6 to 1.8 while those of the oxidized oils were from 1.6 to 42. Volatile analysis by the multiple headspace extraction (MHE) technique, which includes a pressure and time controlled injection onto the gas chromatography (GC) column (a chemically bonded capillary column), was compared with that obtained by static headspace gas chromatography (SHS-GC). Several volatile compounds indicative of the oxidation of polyunsaturated fatty acids from the vegetable oils were identified and measured by MHE; pure compounds of twelve major volatiles also were measured by MHE, and peak area was determined. Multiple extractions of the oil headspace provided a more reproducible measure of volatile compounds than was obtained by SHS-GC. Concentration of all volatiles increased with increased oxidation as measured by peroxide value of the oil. More... »

PAGES

800-803

References to SciGraph publications

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/bf02540495

DOI

http://dx.doi.org/10.1007/bf02540495

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1027236353


Indexing Status Check whether this publication has been indexed by Scopus and Web Of Science using the SN Indexing Status Tool
Incoming Citations Browse incoming citations for this publication using opencitations.net

JSON-LD is the canonical representation for SciGraph data.

TIP: You can open this SciGraph record using an external JSON-LD service: JSON-LD Playground Google SDTT

[
  {
    "@context": "https://springernature.github.io/scigraph/jsonld/sgcontext.json", 
    "about": [
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/0301", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Analytical Chemistry", 
        "type": "DefinedTerm"
      }, 
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/03", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Chemical Sciences", 
        "type": "DefinedTerm"
      }
    ], 
    "author": [
      {
        "affiliation": {
          "alternateName": "Agricultural Research Service", 
          "id": "https://www.grid.ac/institutes/grid.463419.d", 
          "name": [
            "Vegetable Oil Research, Northern Regional Research Center, Agricultural Research Service, U.S. Department of Agriculture, 1815 N. University Street, 61604, Peoria, IL, USA"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Snyder", 
        "givenName": "J. M.", 
        "id": "sg:person.015510400623.26", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.015510400623.26"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Agricultural Research Service", 
          "id": "https://www.grid.ac/institutes/grid.463419.d", 
          "name": [
            "Vegetable Oil Research, Northern Regional Research Center, Agricultural Research Service, U.S. Department of Agriculture, 1815 N. University Street, 61604, Peoria, IL, USA"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Mounts", 
        "givenName": "T. L.", 
        "id": "sg:person.0110541776.58", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.0110541776.58"
        ], 
        "type": "Person"
      }
    ], 
    "citation": [
      {
        "id": "sg:pub.10.1007/bf02541664", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1001289307", 
          "https://doi.org/10.1007/bf02541664"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1007/bf02639526", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1009441538", 
          "https://doi.org/10.1007/bf02639526"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1007/bf02639526", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1009441538", 
          "https://doi.org/10.1007/bf02639526"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1007/bf02912565", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1019832263", 
          "https://doi.org/10.1007/bf02912565"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1007/bf02280380", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1022149154", 
          "https://doi.org/10.1007/bf02280380"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1007/bf02280380", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1022149154", 
          "https://doi.org/10.1007/bf02280380"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/s0021-9673(01)87670-6", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1032319609"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1111/j.1365-2621.1982.tb12705.x", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1041991475"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1007/bf02912391", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1051765131", 
          "https://doi.org/10.1007/bf02912391"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/ac50160a035", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1055018606"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/jf00082a025", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1055895666"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/jf00109a018", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1055897176"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/jf00125a015", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1055898225"
        ], 
        "type": "CreativeWork"
      }
    ], 
    "datePublished": "1990-11", 
    "datePublishedReg": "1990-11-01", 
    "description": "Quantitative determination of the volatiles produced from oxidized vegetable oils is an important indicator of oil quality. Five vegetable oils, low-erucic acid rapeseed, corn, soybean, sunflower and high oleic sunflower, were stored at 60\u00b0C for four and eight days to yield oils with several levels of oxidation. Peroxide values of the fresh oils ranged from 0.6 to 1.8 while those of the oxidized oils were from 1.6 to 42. Volatile analysis by the multiple headspace extraction (MHE) technique, which includes a pressure and time controlled injection onto the gas chromatography (GC) column (a chemically bonded capillary column), was compared with that obtained by static headspace gas chromatography (SHS-GC). Several volatile compounds indicative of the oxidation of polyunsaturated fatty acids from the vegetable oils were identified and measured by MHE; pure compounds of twelve major volatiles also were measured by MHE, and peak area was determined. Multiple extractions of the oil headspace provided a more reproducible measure of volatile compounds than was obtained by SHS-GC. Concentration of all volatiles increased with increased oxidation as measured by peroxide value of the oil.", 
    "genre": "research_article", 
    "id": "sg:pub.10.1007/bf02540495", 
    "inLanguage": [
      "en"
    ], 
    "isAccessibleForFree": false, 
    "isPartOf": [
      {
        "id": "sg:journal.1082739", 
        "issn": [
          "0003-021X", 
          "1558-9331"
        ], 
        "name": "Journal of the American Oil Chemists' Society", 
        "type": "Periodical"
      }, 
      {
        "issueNumber": "11", 
        "type": "PublicationIssue"
      }, 
      {
        "type": "PublicationVolume", 
        "volumeNumber": "67"
      }
    ], 
    "name": "Analysis of vegetable oil volatiles by multiple headspace extraction", 
    "pagination": "800-803", 
    "productId": [
      {
        "name": "readcube_id", 
        "type": "PropertyValue", 
        "value": [
          "81be5ac3a67db78f5f25ac28f948ff9234df7fea32ab196b671b5f0b0ba507f0"
        ]
      }, 
      {
        "name": "doi", 
        "type": "PropertyValue", 
        "value": [
          "10.1007/bf02540495"
        ]
      }, 
      {
        "name": "dimensions_id", 
        "type": "PropertyValue", 
        "value": [
          "pub.1027236353"
        ]
      }
    ], 
    "sameAs": [
      "https://doi.org/10.1007/bf02540495", 
      "https://app.dimensions.ai/details/publication/pub.1027236353"
    ], 
    "sdDataset": "articles", 
    "sdDatePublished": "2019-04-10T17:30", 
    "sdLicense": "https://scigraph.springernature.com/explorer/license/", 
    "sdPublisher": {
      "name": "Springer Nature - SN SciGraph project", 
      "type": "Organization"
    }, 
    "sdSource": "s3://com-uberresearch-data-dimensions-target-20181106-alternative/cleanup/v134/2549eaecd7973599484d7c17b260dba0a4ecb94b/merge/v9/a6c9fde33151104705d4d7ff012ea9563521a3ce/jats-lookup/v90/0000000001_0000000264/records_8672_00000505.jsonl", 
    "type": "ScholarlyArticle", 
    "url": "http://link.springer.com/10.1007%2FBF02540495"
  }
]
 

Download the RDF metadata as:  json-ld nt turtle xml License info

HOW TO GET THIS DATA PROGRAMMATICALLY:

JSON-LD is a popular format for linked data which is fully compatible with JSON.

curl -H 'Accept: application/ld+json' 'https://scigraph.springernature.com/pub.10.1007/bf02540495'

N-Triples is a line-based linked data format ideal for batch operations.

curl -H 'Accept: application/n-triples' 'https://scigraph.springernature.com/pub.10.1007/bf02540495'

Turtle is a human-readable linked data format.

curl -H 'Accept: text/turtle' 'https://scigraph.springernature.com/pub.10.1007/bf02540495'

RDF/XML is a standard XML format for linked data.

curl -H 'Accept: application/rdf+xml' 'https://scigraph.springernature.com/pub.10.1007/bf02540495'


 

This table displays all metadata directly associated to this object as RDF triples.

106 TRIPLES      21 PREDICATES      38 URIs      19 LITERALS      7 BLANK NODES

Subject Predicate Object
1 sg:pub.10.1007/bf02540495 schema:about anzsrc-for:03
2 anzsrc-for:0301
3 schema:author Nbc951264e4c7465f8ee7494dfa53f6ea
4 schema:citation sg:pub.10.1007/bf02280380
5 sg:pub.10.1007/bf02541664
6 sg:pub.10.1007/bf02639526
7 sg:pub.10.1007/bf02912391
8 sg:pub.10.1007/bf02912565
9 https://doi.org/10.1016/s0021-9673(01)87670-6
10 https://doi.org/10.1021/ac50160a035
11 https://doi.org/10.1021/jf00082a025
12 https://doi.org/10.1021/jf00109a018
13 https://doi.org/10.1021/jf00125a015
14 https://doi.org/10.1111/j.1365-2621.1982.tb12705.x
15 schema:datePublished 1990-11
16 schema:datePublishedReg 1990-11-01
17 schema:description Quantitative determination of the volatiles produced from oxidized vegetable oils is an important indicator of oil quality. Five vegetable oils, low-erucic acid rapeseed, corn, soybean, sunflower and high oleic sunflower, were stored at 60°C for four and eight days to yield oils with several levels of oxidation. Peroxide values of the fresh oils ranged from 0.6 to 1.8 while those of the oxidized oils were from 1.6 to 42. Volatile analysis by the multiple headspace extraction (MHE) technique, which includes a pressure and time controlled injection onto the gas chromatography (GC) column (a chemically bonded capillary column), was compared with that obtained by static headspace gas chromatography (SHS-GC). Several volatile compounds indicative of the oxidation of polyunsaturated fatty acids from the vegetable oils were identified and measured by MHE; pure compounds of twelve major volatiles also were measured by MHE, and peak area was determined. Multiple extractions of the oil headspace provided a more reproducible measure of volatile compounds than was obtained by SHS-GC. Concentration of all volatiles increased with increased oxidation as measured by peroxide value of the oil.
18 schema:genre research_article
19 schema:inLanguage en
20 schema:isAccessibleForFree false
21 schema:isPartOf N9735e49551184d15813729cc209d83fb
22 Naaecbff429ff46509c0f6733bb9f1d51
23 sg:journal.1082739
24 schema:name Analysis of vegetable oil volatiles by multiple headspace extraction
25 schema:pagination 800-803
26 schema:productId N283a1a860fe340878823cfb46261f405
27 N96486bfcfe5b427cba1334a6eef78ed5
28 Nc4b49044c6db4177935e681382fb2fd7
29 schema:sameAs https://app.dimensions.ai/details/publication/pub.1027236353
30 https://doi.org/10.1007/bf02540495
31 schema:sdDatePublished 2019-04-10T17:30
32 schema:sdLicense https://scigraph.springernature.com/explorer/license/
33 schema:sdPublisher N0290a1b961d94c63a62d7e512d932fe2
34 schema:url http://link.springer.com/10.1007%2FBF02540495
35 sgo:license sg:explorer/license/
36 sgo:sdDataset articles
37 rdf:type schema:ScholarlyArticle
38 N0290a1b961d94c63a62d7e512d932fe2 schema:name Springer Nature - SN SciGraph project
39 rdf:type schema:Organization
40 N261ef5e501b7486c872cb6e46b33f490 rdf:first sg:person.0110541776.58
41 rdf:rest rdf:nil
42 N283a1a860fe340878823cfb46261f405 schema:name dimensions_id
43 schema:value pub.1027236353
44 rdf:type schema:PropertyValue
45 N96486bfcfe5b427cba1334a6eef78ed5 schema:name readcube_id
46 schema:value 81be5ac3a67db78f5f25ac28f948ff9234df7fea32ab196b671b5f0b0ba507f0
47 rdf:type schema:PropertyValue
48 N9735e49551184d15813729cc209d83fb schema:issueNumber 11
49 rdf:type schema:PublicationIssue
50 Naaecbff429ff46509c0f6733bb9f1d51 schema:volumeNumber 67
51 rdf:type schema:PublicationVolume
52 Nbc951264e4c7465f8ee7494dfa53f6ea rdf:first sg:person.015510400623.26
53 rdf:rest N261ef5e501b7486c872cb6e46b33f490
54 Nc4b49044c6db4177935e681382fb2fd7 schema:name doi
55 schema:value 10.1007/bf02540495
56 rdf:type schema:PropertyValue
57 anzsrc-for:03 schema:inDefinedTermSet anzsrc-for:
58 schema:name Chemical Sciences
59 rdf:type schema:DefinedTerm
60 anzsrc-for:0301 schema:inDefinedTermSet anzsrc-for:
61 schema:name Analytical Chemistry
62 rdf:type schema:DefinedTerm
63 sg:journal.1082739 schema:issn 0003-021X
64 1558-9331
65 schema:name Journal of the American Oil Chemists' Society
66 rdf:type schema:Periodical
67 sg:person.0110541776.58 schema:affiliation https://www.grid.ac/institutes/grid.463419.d
68 schema:familyName Mounts
69 schema:givenName T. L.
70 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.0110541776.58
71 rdf:type schema:Person
72 sg:person.015510400623.26 schema:affiliation https://www.grid.ac/institutes/grid.463419.d
73 schema:familyName Snyder
74 schema:givenName J. M.
75 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.015510400623.26
76 rdf:type schema:Person
77 sg:pub.10.1007/bf02280380 schema:sameAs https://app.dimensions.ai/details/publication/pub.1022149154
78 https://doi.org/10.1007/bf02280380
79 rdf:type schema:CreativeWork
80 sg:pub.10.1007/bf02541664 schema:sameAs https://app.dimensions.ai/details/publication/pub.1001289307
81 https://doi.org/10.1007/bf02541664
82 rdf:type schema:CreativeWork
83 sg:pub.10.1007/bf02639526 schema:sameAs https://app.dimensions.ai/details/publication/pub.1009441538
84 https://doi.org/10.1007/bf02639526
85 rdf:type schema:CreativeWork
86 sg:pub.10.1007/bf02912391 schema:sameAs https://app.dimensions.ai/details/publication/pub.1051765131
87 https://doi.org/10.1007/bf02912391
88 rdf:type schema:CreativeWork
89 sg:pub.10.1007/bf02912565 schema:sameAs https://app.dimensions.ai/details/publication/pub.1019832263
90 https://doi.org/10.1007/bf02912565
91 rdf:type schema:CreativeWork
92 https://doi.org/10.1016/s0021-9673(01)87670-6 schema:sameAs https://app.dimensions.ai/details/publication/pub.1032319609
93 rdf:type schema:CreativeWork
94 https://doi.org/10.1021/ac50160a035 schema:sameAs https://app.dimensions.ai/details/publication/pub.1055018606
95 rdf:type schema:CreativeWork
96 https://doi.org/10.1021/jf00082a025 schema:sameAs https://app.dimensions.ai/details/publication/pub.1055895666
97 rdf:type schema:CreativeWork
98 https://doi.org/10.1021/jf00109a018 schema:sameAs https://app.dimensions.ai/details/publication/pub.1055897176
99 rdf:type schema:CreativeWork
100 https://doi.org/10.1021/jf00125a015 schema:sameAs https://app.dimensions.ai/details/publication/pub.1055898225
101 rdf:type schema:CreativeWork
102 https://doi.org/10.1111/j.1365-2621.1982.tb12705.x schema:sameAs https://app.dimensions.ai/details/publication/pub.1041991475
103 rdf:type schema:CreativeWork
104 https://www.grid.ac/institutes/grid.463419.d schema:alternateName Agricultural Research Service
105 schema:name Vegetable Oil Research, Northern Regional Research Center, Agricultural Research Service, U.S. Department of Agriculture, 1815 N. University Street, 61604, Peoria, IL, USA
106 rdf:type schema:Organization
 




Preview window. Press ESC to close (or click here)


...