Hydrolytic, reductive and pyrolytic decomposition of selected ozonolysis products. Water as an ozonization medium View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

1968-12

AUTHORS

E. H. Pryde, D. J. Moore, J. C. Cowan

ABSTRACT

Hydrolytic, reductive and pyrolytic decompositions of ozonolysis products formed in water were surveyed as potential preparative routes to aldehydes. Water is an effective ozonolysis medium and reacts with the transient zwitterion formed during ozonolysis in the same manner as participating solvents. Reductive decomposition proved to be superior to either hydrolytic or pyrolytic decomposition for the preparation of aldehydes. Pyrolytic decomposition, as carried out in the injection port of a gas chromatograph, gave varying amounts and types of products depending upon the type of ozonolysis product used. Interconversion of the various types of ozonolysis products, including ozonides, methoxy hydroperoxides, acetoxy hydroperoxides and hydroxy hydroperoxides, does not occur except under acid catalysis. More... »

PAGES

888-894

References to SciGraph publications

  • 1959-09. Linoleic acid from safflower oil by liquid-liquid extraction in JOURNAL OF THE AMERICAN OIL CHEMISTS' SOCIETY
  • 1963-09. Unsaturated aldehyde oils by the partial ozonization of soybean oil in JOURNAL OF THE AMERICAN OIL CHEMISTS' SOCIETY
  • 1961-10. Production of linolenic acid from linseed oil in JOURNAL OF THE AMERICAN OIL CHEMISTS' SOCIETY
  • 1968-02. Laboratory optimization of process variables in reductive ozonolysis of methyl soyate in JOURNAL OF THE AMERICAN OIL CHEMISTS' SOCIETY
  • 1965-10. A comparison of participating solvents during ozonization in JOURNAL OF THE AMERICAN OIL CHEMISTS' SOCIETY
  • 1965-02. Quantitative determination of double bond positions in unsaturated fatty acids after oxidative cleavage in JOURNAL OF THE AMERICAN OIL CHEMISTS' SOCIETY
  • 1966-06. Recent advances in the determination of the structure of fatty acids via ozonolysis in JOURNAL OF THE AMERICAN OIL CHEMISTS' SOCIETY
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    http://scigraph.springernature.com/pub.10.1007/bf02540178

    DOI

    http://dx.doi.org/10.1007/bf02540178

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