Ontology type: schema:ScholarlyArticle
1992-06
AUTHORSE. N. Frankel, E. Selke, W. E. Neff, K. Miyashita
ABSTRACTTrilinoleoylglycerol (LLL), trilinolenoylglycerol (LnLnLn) and four synthetic triacylglycerols were autoxidized and the volatile products were investigated to determine the effect of fatty acid glyceride position on the mechanism of hydroperoxide decomposition. Capillary gas chromatography provided a sensitive method to follow the volatile oxidation products of mixtures of LLL and LnLnLn and of synthetic triacylglycerols containing linoleate and linolenate in different known positions. The relative amount of linoleate oxidation was determined by analyzing for hexanal, 2-heptenal and 2,4-decadienal, and the relative amount of linolenate oxidation by analyzing for 2,4-heptadienal and 2,4,7-decatrienal. The volatiles from pure monohydroperoxides of LLL and LnLnLn were compared with those of the corresponding triacylglycerols by capillary gas chromatography. Significant differences in the distribution of volatile products were observed depending on the triacylglycerols precursor. A 1∶1 mixture of LLL and LnLnLn autoxidized at 40°C showed an equal contribution of linolenate and linoleate volatiles at a peroxide value of 34. The synthetic triacylglycerols LLnL and LLLn (L, linoleic; Ln, linolenic acid) formed initially about the same total volatiles, whereas LnLnL formed more volatiles than LnLLn. The ratio Ln to L volatile products was the same for the diL triacylglycerols, and higher for LnLnL than for LnLLn. This new information should permit us to better understand the influence of triacylglycerol structure on the relative oxidative stability of unsaturated triacylglycerols. More... »
PAGES442-446
http://scigraph.springernature.com/pub.10.1007/bf02536386
DOIhttp://dx.doi.org/10.1007/bf02536386
DIMENSIONShttps://app.dimensions.ai/details/publication/pub.1051227887
PUBMEDhttps://www.ncbi.nlm.nih.gov/pubmed/27519670
JSON-LD is the canonical representation for SciGraph data.
TIP: You can open this SciGraph record using an external JSON-LD service: JSON-LD Playground Google SDTT
[
{
"@context": "https://springernature.github.io/scigraph/jsonld/sgcontext.json",
"about": [
{
"id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/0301",
"inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/",
"name": "Analytical Chemistry",
"type": "DefinedTerm"
},
{
"id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/03",
"inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/",
"name": "Chemical Sciences",
"type": "DefinedTerm"
}
],
"author": [
{
"affiliation": {
"alternateName": "Agricultural Research Service",
"id": "https://www.grid.ac/institutes/grid.463419.d",
"name": [
"National Center for Agricultural Utilization Research, U.S. Department of Agriculture, 61604, Peoria, Illinois"
],
"type": "Organization"
},
"familyName": "Frankel",
"givenName": "E. N.",
"id": "sg:person.015475525615.48",
"sameAs": [
"https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.015475525615.48"
],
"type": "Person"
},
{
"affiliation": {
"alternateName": "Agricultural Research Service",
"id": "https://www.grid.ac/institutes/grid.463419.d",
"name": [
"National Center for Agricultural Utilization Research, U.S. Department of Agriculture, 61604, Peoria, Illinois"
],
"type": "Organization"
},
"familyName": "Selke",
"givenName": "E.",
"id": "sg:person.015110354141.09",
"sameAs": [
"https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.015110354141.09"
],
"type": "Person"
},
{
"affiliation": {
"alternateName": "Agricultural Research Service",
"id": "https://www.grid.ac/institutes/grid.463419.d",
"name": [
"National Center for Agricultural Utilization Research, U.S. Department of Agriculture, 61604, Peoria, Illinois"
],
"type": "Organization"
},
"familyName": "Neff",
"givenName": "W. E.",
"id": "sg:person.07440243115.98",
"sameAs": [
"https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.07440243115.98"
],
"type": "Person"
},
{
"affiliation": {
"alternateName": "Agricultural Research Service",
"id": "https://www.grid.ac/institutes/grid.463419.d",
"name": [
"National Center for Agricultural Utilization Research, U.S. Department of Agriculture, 61604, Peoria, Illinois"
],
"type": "Organization"
},
"familyName": "Miyashita",
"givenName": "K.",
"id": "sg:person.016104703315.20",
"sameAs": [
"https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.016104703315.20"
],
"type": "Person"
}
],
"citation": [
{
"id": "https://doi.org/10.1016/0076-6879(90)86134-h",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1002172657"
],
"type": "CreativeWork"
},
{
"id": "sg:pub.10.1007/bf02562427",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1022739570",
"https://doi.org/10.1007/bf02562427"
],
"type": "CreativeWork"
},
{
"id": "sg:pub.10.1007/bf02562425",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1038257176",
"https://doi.org/10.1007/bf02562425"
],
"type": "CreativeWork"
},
{
"id": "sg:pub.10.1007/bf02535761",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1043260042",
"https://doi.org/10.1007/bf02535761"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.3109/10715768709069786",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1045599852"
],
"type": "CreativeWork"
},
{
"id": "sg:pub.10.1007/bf02673797",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1047867672",
"https://doi.org/10.1007/bf02673797"
],
"type": "CreativeWork"
},
{
"id": "sg:pub.10.1007/bf02651444",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1048617851",
"https://doi.org/10.1007/bf02651444"
],
"type": "CreativeWork"
},
{
"id": "sg:pub.10.1007/bf02562426",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1052371987",
"https://doi.org/10.1007/bf02562426"
],
"type": "CreativeWork"
}
],
"datePublished": "1992-06",
"datePublishedReg": "1992-06-01",
"description": "Trilinoleoylglycerol (LLL), trilinolenoylglycerol (LnLnLn) and four synthetic triacylglycerols were autoxidized and the volatile products were investigated to determine the effect of fatty acid glyceride position on the mechanism of hydroperoxide decomposition. Capillary gas chromatography provided a sensitive method to follow the volatile oxidation products of mixtures of LLL and LnLnLn and of synthetic triacylglycerols containing linoleate and linolenate in different known positions. The relative amount of linoleate oxidation was determined by analyzing for hexanal, 2-heptenal and 2,4-decadienal, and the relative amount of linolenate oxidation by analyzing for 2,4-heptadienal and 2,4,7-decatrienal. The volatiles from pure monohydroperoxides of LLL and LnLnLn were compared with those of the corresponding triacylglycerols by capillary gas chromatography. Significant differences in the distribution of volatile products were observed depending on the triacylglycerols precursor. A 1\u22361 mixture of LLL and LnLnLn autoxidized at 40\u00b0C showed an equal contribution of linolenate and linoleate volatiles at a peroxide value of 34. The synthetic triacylglycerols LLnL and LLLn (L, linoleic; Ln, linolenic acid) formed initially about the same total volatiles, whereas LnLnL formed more volatiles than LnLLn. The ratio Ln to L volatile products was the same for the diL triacylglycerols, and higher for LnLnL than for LnLLn. This new information should permit us to better understand the influence of triacylglycerol structure on the relative oxidative stability of unsaturated triacylglycerols. ",
"genre": "research_article",
"id": "sg:pub.10.1007/bf02536386",
"inLanguage": [
"en"
],
"isAccessibleForFree": false,
"isPartOf": [
{
"id": "sg:journal.1006395",
"issn": [
"0024-4201",
"1558-9307"
],
"name": "Lipids",
"type": "Periodical"
},
{
"issueNumber": "6",
"type": "PublicationIssue"
},
{
"type": "PublicationVolume",
"volumeNumber": "27"
}
],
"name": "Autoxidation of polyunsaturated triacylglycerols. IV. Volatile decomposition products from triacylglycerols containing linoleate and linolenate",
"pagination": "442-446",
"productId": [
{
"name": "readcube_id",
"type": "PropertyValue",
"value": [
"f4075c5c42b8ab70a2e815cbd5f8abfc872bf99e5db466a381ba166e908d551a"
]
},
{
"name": "pubmed_id",
"type": "PropertyValue",
"value": [
"27519670"
]
},
{
"name": "nlm_unique_id",
"type": "PropertyValue",
"value": [
"0060450"
]
},
{
"name": "doi",
"type": "PropertyValue",
"value": [
"10.1007/bf02536386"
]
},
{
"name": "dimensions_id",
"type": "PropertyValue",
"value": [
"pub.1051227887"
]
}
],
"sameAs": [
"https://doi.org/10.1007/bf02536386",
"https://app.dimensions.ai/details/publication/pub.1051227887"
],
"sdDataset": "articles",
"sdDatePublished": "2019-04-10T14:04",
"sdLicense": "https://scigraph.springernature.com/explorer/license/",
"sdPublisher": {
"name": "Springer Nature - SN SciGraph project",
"type": "Organization"
},
"sdSource": "s3://com-uberresearch-data-dimensions-target-20181106-alternative/cleanup/v134/2549eaecd7973599484d7c17b260dba0a4ecb94b/merge/v9/a6c9fde33151104705d4d7ff012ea9563521a3ce/jats-lookup/v90/0000000001_0000000264/records_8660_00000491.jsonl",
"type": "ScholarlyArticle",
"url": "http://link.springer.com/10.1007/BF02536386"
}
]Download the RDF metadata as: json-ld nt turtle xml License info
JSON-LD is a popular format for linked data which is fully compatible with JSON.
curl -H 'Accept: application/ld+json' 'https://scigraph.springernature.com/pub.10.1007/bf02536386'
N-Triples is a line-based linked data format ideal for batch operations.
curl -H 'Accept: application/n-triples' 'https://scigraph.springernature.com/pub.10.1007/bf02536386'
Turtle is a human-readable linked data format.
curl -H 'Accept: text/turtle' 'https://scigraph.springernature.com/pub.10.1007/bf02536386'
RDF/XML is a standard XML format for linked data.
curl -H 'Accept: application/rdf+xml' 'https://scigraph.springernature.com/pub.10.1007/bf02536386'
This table displays all metadata directly associated to this object as RDF triples.
120 TRIPLES
21 PREDICATES
37 URIs
21 LITERALS
9 BLANK NODES