The kinetics of the autoxidation of polyunsaturated fatty acids View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

1987-05

AUTHORS

John P. Cosgrove, Daniel F. Church, William A. Pryor

ABSTRACT

The kinetics of the autoxidation of a series of polyunsaturated fatty acids (PUFA) with increasing degrees of unsaturation and the mono-, di- and triglycerides of linoleate have been studied in homogeneous chlorobenzene solution at 37 C under 760 torr of oxygen. The autoxidations were initiated by thermal decomposition of azo initiators and followed by measuring the rate of oxygen uptake. The rate of chain initiation was determined by the induction period method using alpha-tocopherol as the chain-breaking antioxidant. The measured oxidizabilities of the PUFA are linearly dependent on the number of doubly allylic positions present in the molecule. Thus, the oxidizability of linoleate is 2.03 X 10(-2) M-1/2 sec-1/2, and the value for docosahexaenoate is five times greater, 10.15 X 10(-2) M-1/2 sec-1/2. The rate of autoxidation for all PUFA studied and for the mono- and diglyceride is proportional to the substrate concentration and to the square root of the rate of chain initiation, implying that the autoxidation of these compounds follows the usual kinetic rate law. The autoxidation of the triglyceride is more complex and does not appear to follow the same rate law at all substrate concentrations. This deviation from the usual kinetic rate expression may be due to lipid aggregation at low concentrations of the triglyceride. More... »

PAGES

299-304

References to SciGraph publications

  • 1947-04. The rates of oxidation of unsaturated fatty acids and esters in JOURNAL OF THE AMERICAN OIL CHEMISTS' SOCIETY
  • Identifiers

    URI

    http://scigraph.springernature.com/pub.10.1007/bf02533996

    DOI

    http://dx.doi.org/10.1007/bf02533996

    DIMENSIONS

    https://app.dimensions.ai/details/publication/pub.1050763736

    PUBMED

    https://www.ncbi.nlm.nih.gov/pubmed/3600206


    Indexing Status Check whether this publication has been indexed by Scopus and Web Of Science using the SN Indexing Status Tool
    Incoming Citations Browse incoming citations for this publication using opencitations.net

    JSON-LD is the canonical representation for SciGraph data.

    TIP: You can open this SciGraph record using an external JSON-LD service: JSON-LD Playground Google SDTT

    [
      {
        "@context": "https://springernature.github.io/scigraph/jsonld/sgcontext.json", 
        "about": [
          {
            "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/1101", 
            "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
            "name": "Medical Biochemistry and Metabolomics", 
            "type": "DefinedTerm"
          }, 
          {
            "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/11", 
            "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
            "name": "Medical and Health Sciences", 
            "type": "DefinedTerm"
          }, 
          {
            "inDefinedTermSet": "https://www.nlm.nih.gov/mesh/", 
            "name": "Chemical Phenomena", 
            "type": "DefinedTerm"
          }, 
          {
            "inDefinedTermSet": "https://www.nlm.nih.gov/mesh/", 
            "name": "Chemistry", 
            "type": "DefinedTerm"
          }, 
          {
            "inDefinedTermSet": "https://www.nlm.nih.gov/mesh/", 
            "name": "Fatty Acids, Unsaturated", 
            "type": "DefinedTerm"
          }, 
          {
            "inDefinedTermSet": "https://www.nlm.nih.gov/mesh/", 
            "name": "Kinetics", 
            "type": "DefinedTerm"
          }, 
          {
            "inDefinedTermSet": "https://www.nlm.nih.gov/mesh/", 
            "name": "Mathematics", 
            "type": "DefinedTerm"
          }, 
          {
            "inDefinedTermSet": "https://www.nlm.nih.gov/mesh/", 
            "name": "Oxidation-Reduction", 
            "type": "DefinedTerm"
          }, 
          {
            "inDefinedTermSet": "https://www.nlm.nih.gov/mesh/", 
            "name": "Triglycerides", 
            "type": "DefinedTerm"
          }, 
          {
            "inDefinedTermSet": "https://www.nlm.nih.gov/mesh/", 
            "name": "Vitamin E", 
            "type": "DefinedTerm"
          }
        ], 
        "author": [
          {
            "affiliation": {
              "alternateName": "Louisiana State University", 
              "id": "https://www.grid.ac/institutes/grid.64337.35", 
              "name": [
                "Department of Chemistry and Biochemistry, Louisiana State University, 70803, Baton Rouge, LA", 
                "The Biodynamics Institute, Louisiana State University, 70803, Baton Rouge, LA"
              ], 
              "type": "Organization"
            }, 
            "familyName": "Cosgrove", 
            "givenName": "John P.", 
            "id": "sg:person.0776175323.42", 
            "sameAs": [
              "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.0776175323.42"
            ], 
            "type": "Person"
          }, 
          {
            "affiliation": {
              "alternateName": "Louisiana State University", 
              "id": "https://www.grid.ac/institutes/grid.64337.35", 
              "name": [
                "Department of Chemistry and Biochemistry, Louisiana State University, 70803, Baton Rouge, LA", 
                "The Biodynamics Institute, Louisiana State University, 70803, Baton Rouge, LA"
              ], 
              "type": "Organization"
            }, 
            "familyName": "Church", 
            "givenName": "Daniel F.", 
            "id": "sg:person.01112423723.36", 
            "sameAs": [
              "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01112423723.36"
            ], 
            "type": "Person"
          }, 
          {
            "affiliation": {
              "alternateName": "Louisiana State University", 
              "id": "https://www.grid.ac/institutes/grid.64337.35", 
              "name": [
                "Department of Chemistry and Biochemistry, Louisiana State University, 70803, Baton Rouge, LA", 
                "The Biodynamics Institute, Louisiana State University, 70803, Baton Rouge, LA"
              ], 
              "type": "Organization"
            }, 
            "familyName": "Pryor", 
            "givenName": "William A.", 
            "id": "sg:person.01364324304.17", 
            "sameAs": [
              "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01364324304.17"
            ], 
            "type": "Person"
          }
        ], 
        "citation": [
          {
            "id": "https://doi.org/10.1016/b978-0-12-566501-8.50008-0", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1011663641"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "https://doi.org/10.1246/bcsj.57.1260", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1013262700"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "sg:pub.10.1007/bf02643258", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1016324062", 
              "https://doi.org/10.1007/bf02643258"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "https://doi.org/10.1016/s8755-9668(86)80024-2", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1016812592"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "https://doi.org/10.3109/02713688508999969", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1018488701"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "https://doi.org/10.1139/v66-169", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1031072026"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "https://doi.org/10.1139/v69-635", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1031400197"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "https://doi.org/10.1016/0005-2736(85)90192-0", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1034930791"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "https://doi.org/10.1016/0005-2736(85)90192-0", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1034930791"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "https://doi.org/10.1016/s0040-4039(00)70159-6", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1034955974"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "https://doi.org/10.1016/b978-0-12-566504-9.50008-8", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1038036543"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "https://doi.org/10.1139/v62-281", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1038950845"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "https://doi.org/10.1246/bcsj.59.497", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1045807940"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "https://doi.org/10.1139/v67-132", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1048639173"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "https://doi.org/10.1016/8755-9668(86)90016-5", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1054570642"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "https://doi.org/10.1016/8755-9668(86)90016-5", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1054570642"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "https://doi.org/10.1021/ja00334a045", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1055724271"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "https://doi.org/10.1021/ja00353a039", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1055725861"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "https://doi.org/10.1021/ja00411a035", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1055730410"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "https://doi.org/10.1021/ja00411a036", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1055730411"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "https://doi.org/10.1021/ja01066a014", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1055765441"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "https://doi.org/10.1021/ja01537a006", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1055805471"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "https://doi.org/10.1021/ja01617a026", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1055812986"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "https://doi.org/10.1021/ja01617a028", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1055812988"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "https://doi.org/10.1021/jo00202a028", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1055972758"
            ], 
            "type": "CreativeWork"
          }
        ], 
        "datePublished": "1987-05", 
        "datePublishedReg": "1987-05-01", 
        "description": "The kinetics of the autoxidation of a series of polyunsaturated fatty acids (PUFA) with increasing degrees of unsaturation and the mono-, di- and triglycerides of linoleate have been studied in homogeneous chlorobenzene solution at 37 C under 760 torr of oxygen. The autoxidations were initiated by thermal decomposition of azo initiators and followed by measuring the rate of oxygen uptake. The rate of chain initiation was determined by the induction period method using alpha-tocopherol as the chain-breaking antioxidant. The measured oxidizabilities of the PUFA are linearly dependent on the number of doubly allylic positions present in the molecule. Thus, the oxidizability of linoleate is 2.03 X 10(-2) M-1/2 sec-1/2, and the value for docosahexaenoate is five times greater, 10.15 X 10(-2) M-1/2 sec-1/2. The rate of autoxidation for all PUFA studied and for the mono- and diglyceride is proportional to the substrate concentration and to the square root of the rate of chain initiation, implying that the autoxidation of these compounds follows the usual kinetic rate law. The autoxidation of the triglyceride is more complex and does not appear to follow the same rate law at all substrate concentrations. This deviation from the usual kinetic rate expression may be due to lipid aggregation at low concentrations of the triglyceride.", 
        "genre": "research_article", 
        "id": "sg:pub.10.1007/bf02533996", 
        "inLanguage": [
          "en"
        ], 
        "isAccessibleForFree": false, 
        "isPartOf": [
          {
            "id": "sg:journal.1006395", 
            "issn": [
              "0024-4201", 
              "1558-9307"
            ], 
            "name": "Lipids", 
            "type": "Periodical"
          }, 
          {
            "issueNumber": "5", 
            "type": "PublicationIssue"
          }, 
          {
            "type": "PublicationVolume", 
            "volumeNumber": "22"
          }
        ], 
        "name": "The kinetics of the autoxidation of polyunsaturated fatty acids", 
        "pagination": "299-304", 
        "productId": [
          {
            "name": "readcube_id", 
            "type": "PropertyValue", 
            "value": [
              "f1d1669288bdd7d0386b4f7edf517a0f3d8d6d41f4b7e6329a96917f7f361b89"
            ]
          }, 
          {
            "name": "pubmed_id", 
            "type": "PropertyValue", 
            "value": [
              "3600206"
            ]
          }, 
          {
            "name": "nlm_unique_id", 
            "type": "PropertyValue", 
            "value": [
              "0060450"
            ]
          }, 
          {
            "name": "doi", 
            "type": "PropertyValue", 
            "value": [
              "10.1007/bf02533996"
            ]
          }, 
          {
            "name": "dimensions_id", 
            "type": "PropertyValue", 
            "value": [
              "pub.1050763736"
            ]
          }
        ], 
        "sameAs": [
          "https://doi.org/10.1007/bf02533996", 
          "https://app.dimensions.ai/details/publication/pub.1050763736"
        ], 
        "sdDataset": "articles", 
        "sdDatePublished": "2019-04-10T16:35", 
        "sdLicense": "https://scigraph.springernature.com/explorer/license/", 
        "sdPublisher": {
          "name": "Springer Nature - SN SciGraph project", 
          "type": "Organization"
        }, 
        "sdSource": "s3://com-uberresearch-data-dimensions-target-20181106-alternative/cleanup/v134/2549eaecd7973599484d7c17b260dba0a4ecb94b/merge/v9/a6c9fde33151104705d4d7ff012ea9563521a3ce/jats-lookup/v90/0000000001_0000000264/records_8669_00000483.jsonl", 
        "type": "ScholarlyArticle", 
        "url": "http://link.springer.com/10.1007/BF02533996"
      }
    ]
     

    Download the RDF metadata as:  json-ld nt turtle xml License info

    HOW TO GET THIS DATA PROGRAMMATICALLY:

    JSON-LD is a popular format for linked data which is fully compatible with JSON.

    curl -H 'Accept: application/ld+json' 'https://scigraph.springernature.com/pub.10.1007/bf02533996'

    N-Triples is a line-based linked data format ideal for batch operations.

    curl -H 'Accept: application/n-triples' 'https://scigraph.springernature.com/pub.10.1007/bf02533996'

    Turtle is a human-readable linked data format.

    curl -H 'Accept: text/turtle' 'https://scigraph.springernature.com/pub.10.1007/bf02533996'

    RDF/XML is a standard XML format for linked data.

    curl -H 'Accept: application/rdf+xml' 'https://scigraph.springernature.com/pub.10.1007/bf02533996'


     

    This table displays all metadata directly associated to this object as RDF triples.

    186 TRIPLES      21 PREDICATES      60 URIs      29 LITERALS      17 BLANK NODES

    Subject Predicate Object
    1 sg:pub.10.1007/bf02533996 schema:about N04341ccc06444b6ebf9905aee45f966f
    2 N11100c70008649bca729bce54eecda81
    3 N5fd348bfc3dd45d4aa0e63013a76b106
    4 N6e588f6eba2445dc824533b0f49dadb5
    5 N88658d287d264c60b772822c23cea8a6
    6 Na4b3349a2a06441dba334cfe3a8169f4
    7 Na64bf7d8d9ee44bc94d17f76b26dde73
    8 Nd22d21fc82a541aeb4f3a28a6136962b
    9 anzsrc-for:11
    10 anzsrc-for:1101
    11 schema:author N81ec4f1e91844f6788b7be2e38798e24
    12 schema:citation sg:pub.10.1007/bf02643258
    13 https://doi.org/10.1016/0005-2736(85)90192-0
    14 https://doi.org/10.1016/8755-9668(86)90016-5
    15 https://doi.org/10.1016/b978-0-12-566501-8.50008-0
    16 https://doi.org/10.1016/b978-0-12-566504-9.50008-8
    17 https://doi.org/10.1016/s0040-4039(00)70159-6
    18 https://doi.org/10.1016/s8755-9668(86)80024-2
    19 https://doi.org/10.1021/ja00334a045
    20 https://doi.org/10.1021/ja00353a039
    21 https://doi.org/10.1021/ja00411a035
    22 https://doi.org/10.1021/ja00411a036
    23 https://doi.org/10.1021/ja01066a014
    24 https://doi.org/10.1021/ja01537a006
    25 https://doi.org/10.1021/ja01617a026
    26 https://doi.org/10.1021/ja01617a028
    27 https://doi.org/10.1021/jo00202a028
    28 https://doi.org/10.1139/v62-281
    29 https://doi.org/10.1139/v66-169
    30 https://doi.org/10.1139/v67-132
    31 https://doi.org/10.1139/v69-635
    32 https://doi.org/10.1246/bcsj.57.1260
    33 https://doi.org/10.1246/bcsj.59.497
    34 https://doi.org/10.3109/02713688508999969
    35 schema:datePublished 1987-05
    36 schema:datePublishedReg 1987-05-01
    37 schema:description The kinetics of the autoxidation of a series of polyunsaturated fatty acids (PUFA) with increasing degrees of unsaturation and the mono-, di- and triglycerides of linoleate have been studied in homogeneous chlorobenzene solution at 37 C under 760 torr of oxygen. The autoxidations were initiated by thermal decomposition of azo initiators and followed by measuring the rate of oxygen uptake. The rate of chain initiation was determined by the induction period method using alpha-tocopherol as the chain-breaking antioxidant. The measured oxidizabilities of the PUFA are linearly dependent on the number of doubly allylic positions present in the molecule. Thus, the oxidizability of linoleate is 2.03 X 10(-2) M-1/2 sec-1/2, and the value for docosahexaenoate is five times greater, 10.15 X 10(-2) M-1/2 sec-1/2. The rate of autoxidation for all PUFA studied and for the mono- and diglyceride is proportional to the substrate concentration and to the square root of the rate of chain initiation, implying that the autoxidation of these compounds follows the usual kinetic rate law. The autoxidation of the triglyceride is more complex and does not appear to follow the same rate law at all substrate concentrations. This deviation from the usual kinetic rate expression may be due to lipid aggregation at low concentrations of the triglyceride.
    38 schema:genre research_article
    39 schema:inLanguage en
    40 schema:isAccessibleForFree false
    41 schema:isPartOf N0292cbe41ac2474e9166af9972af5df3
    42 N834b7a7dac8742faaf17d9212988d21b
    43 sg:journal.1006395
    44 schema:name The kinetics of the autoxidation of polyunsaturated fatty acids
    45 schema:pagination 299-304
    46 schema:productId N3760b4f6c82143c3a24133b19437c7b5
    47 N5322b78715874d348cd6be3602d19c13
    48 N84b745a444a8416cab4ff7a01af1e393
    49 N85496a47e06d4b2ba5f58cc9c2c9f27b
    50 Naa9396fd24cf401db92a133ae6f142ab
    51 schema:sameAs https://app.dimensions.ai/details/publication/pub.1050763736
    52 https://doi.org/10.1007/bf02533996
    53 schema:sdDatePublished 2019-04-10T16:35
    54 schema:sdLicense https://scigraph.springernature.com/explorer/license/
    55 schema:sdPublisher N34f6c24ea8a746fcae9ba316e458a0cd
    56 schema:url http://link.springer.com/10.1007/BF02533996
    57 sgo:license sg:explorer/license/
    58 sgo:sdDataset articles
    59 rdf:type schema:ScholarlyArticle
    60 N0292cbe41ac2474e9166af9972af5df3 schema:volumeNumber 22
    61 rdf:type schema:PublicationVolume
    62 N04341ccc06444b6ebf9905aee45f966f schema:inDefinedTermSet https://www.nlm.nih.gov/mesh/
    63 schema:name Mathematics
    64 rdf:type schema:DefinedTerm
    65 N11100c70008649bca729bce54eecda81 schema:inDefinedTermSet https://www.nlm.nih.gov/mesh/
    66 schema:name Triglycerides
    67 rdf:type schema:DefinedTerm
    68 N15a7d26ef54f4579bc92bb5c5b8c013b rdf:first sg:person.01364324304.17
    69 rdf:rest rdf:nil
    70 N34f6c24ea8a746fcae9ba316e458a0cd schema:name Springer Nature - SN SciGraph project
    71 rdf:type schema:Organization
    72 N3760b4f6c82143c3a24133b19437c7b5 schema:name readcube_id
    73 schema:value f1d1669288bdd7d0386b4f7edf517a0f3d8d6d41f4b7e6329a96917f7f361b89
    74 rdf:type schema:PropertyValue
    75 N5322b78715874d348cd6be3602d19c13 schema:name dimensions_id
    76 schema:value pub.1050763736
    77 rdf:type schema:PropertyValue
    78 N5fd348bfc3dd45d4aa0e63013a76b106 schema:inDefinedTermSet https://www.nlm.nih.gov/mesh/
    79 schema:name Chemistry
    80 rdf:type schema:DefinedTerm
    81 N6e588f6eba2445dc824533b0f49dadb5 schema:inDefinedTermSet https://www.nlm.nih.gov/mesh/
    82 schema:name Fatty Acids, Unsaturated
    83 rdf:type schema:DefinedTerm
    84 N81ec4f1e91844f6788b7be2e38798e24 rdf:first sg:person.0776175323.42
    85 rdf:rest Na56cbb5383dc4d0eaf50b70159dc7b38
    86 N834b7a7dac8742faaf17d9212988d21b schema:issueNumber 5
    87 rdf:type schema:PublicationIssue
    88 N84b745a444a8416cab4ff7a01af1e393 schema:name doi
    89 schema:value 10.1007/bf02533996
    90 rdf:type schema:PropertyValue
    91 N85496a47e06d4b2ba5f58cc9c2c9f27b schema:name pubmed_id
    92 schema:value 3600206
    93 rdf:type schema:PropertyValue
    94 N88658d287d264c60b772822c23cea8a6 schema:inDefinedTermSet https://www.nlm.nih.gov/mesh/
    95 schema:name Chemical Phenomena
    96 rdf:type schema:DefinedTerm
    97 Na4b3349a2a06441dba334cfe3a8169f4 schema:inDefinedTermSet https://www.nlm.nih.gov/mesh/
    98 schema:name Kinetics
    99 rdf:type schema:DefinedTerm
    100 Na56cbb5383dc4d0eaf50b70159dc7b38 rdf:first sg:person.01112423723.36
    101 rdf:rest N15a7d26ef54f4579bc92bb5c5b8c013b
    102 Na64bf7d8d9ee44bc94d17f76b26dde73 schema:inDefinedTermSet https://www.nlm.nih.gov/mesh/
    103 schema:name Oxidation-Reduction
    104 rdf:type schema:DefinedTerm
    105 Naa9396fd24cf401db92a133ae6f142ab schema:name nlm_unique_id
    106 schema:value 0060450
    107 rdf:type schema:PropertyValue
    108 Nd22d21fc82a541aeb4f3a28a6136962b schema:inDefinedTermSet https://www.nlm.nih.gov/mesh/
    109 schema:name Vitamin E
    110 rdf:type schema:DefinedTerm
    111 anzsrc-for:11 schema:inDefinedTermSet anzsrc-for:
    112 schema:name Medical and Health Sciences
    113 rdf:type schema:DefinedTerm
    114 anzsrc-for:1101 schema:inDefinedTermSet anzsrc-for:
    115 schema:name Medical Biochemistry and Metabolomics
    116 rdf:type schema:DefinedTerm
    117 sg:journal.1006395 schema:issn 0024-4201
    118 1558-9307
    119 schema:name Lipids
    120 rdf:type schema:Periodical
    121 sg:person.01112423723.36 schema:affiliation https://www.grid.ac/institutes/grid.64337.35
    122 schema:familyName Church
    123 schema:givenName Daniel F.
    124 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01112423723.36
    125 rdf:type schema:Person
    126 sg:person.01364324304.17 schema:affiliation https://www.grid.ac/institutes/grid.64337.35
    127 schema:familyName Pryor
    128 schema:givenName William A.
    129 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01364324304.17
    130 rdf:type schema:Person
    131 sg:person.0776175323.42 schema:affiliation https://www.grid.ac/institutes/grid.64337.35
    132 schema:familyName Cosgrove
    133 schema:givenName John P.
    134 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.0776175323.42
    135 rdf:type schema:Person
    136 sg:pub.10.1007/bf02643258 schema:sameAs https://app.dimensions.ai/details/publication/pub.1016324062
    137 https://doi.org/10.1007/bf02643258
    138 rdf:type schema:CreativeWork
    139 https://doi.org/10.1016/0005-2736(85)90192-0 schema:sameAs https://app.dimensions.ai/details/publication/pub.1034930791
    140 rdf:type schema:CreativeWork
    141 https://doi.org/10.1016/8755-9668(86)90016-5 schema:sameAs https://app.dimensions.ai/details/publication/pub.1054570642
    142 rdf:type schema:CreativeWork
    143 https://doi.org/10.1016/b978-0-12-566501-8.50008-0 schema:sameAs https://app.dimensions.ai/details/publication/pub.1011663641
    144 rdf:type schema:CreativeWork
    145 https://doi.org/10.1016/b978-0-12-566504-9.50008-8 schema:sameAs https://app.dimensions.ai/details/publication/pub.1038036543
    146 rdf:type schema:CreativeWork
    147 https://doi.org/10.1016/s0040-4039(00)70159-6 schema:sameAs https://app.dimensions.ai/details/publication/pub.1034955974
    148 rdf:type schema:CreativeWork
    149 https://doi.org/10.1016/s8755-9668(86)80024-2 schema:sameAs https://app.dimensions.ai/details/publication/pub.1016812592
    150 rdf:type schema:CreativeWork
    151 https://doi.org/10.1021/ja00334a045 schema:sameAs https://app.dimensions.ai/details/publication/pub.1055724271
    152 rdf:type schema:CreativeWork
    153 https://doi.org/10.1021/ja00353a039 schema:sameAs https://app.dimensions.ai/details/publication/pub.1055725861
    154 rdf:type schema:CreativeWork
    155 https://doi.org/10.1021/ja00411a035 schema:sameAs https://app.dimensions.ai/details/publication/pub.1055730410
    156 rdf:type schema:CreativeWork
    157 https://doi.org/10.1021/ja00411a036 schema:sameAs https://app.dimensions.ai/details/publication/pub.1055730411
    158 rdf:type schema:CreativeWork
    159 https://doi.org/10.1021/ja01066a014 schema:sameAs https://app.dimensions.ai/details/publication/pub.1055765441
    160 rdf:type schema:CreativeWork
    161 https://doi.org/10.1021/ja01537a006 schema:sameAs https://app.dimensions.ai/details/publication/pub.1055805471
    162 rdf:type schema:CreativeWork
    163 https://doi.org/10.1021/ja01617a026 schema:sameAs https://app.dimensions.ai/details/publication/pub.1055812986
    164 rdf:type schema:CreativeWork
    165 https://doi.org/10.1021/ja01617a028 schema:sameAs https://app.dimensions.ai/details/publication/pub.1055812988
    166 rdf:type schema:CreativeWork
    167 https://doi.org/10.1021/jo00202a028 schema:sameAs https://app.dimensions.ai/details/publication/pub.1055972758
    168 rdf:type schema:CreativeWork
    169 https://doi.org/10.1139/v62-281 schema:sameAs https://app.dimensions.ai/details/publication/pub.1038950845
    170 rdf:type schema:CreativeWork
    171 https://doi.org/10.1139/v66-169 schema:sameAs https://app.dimensions.ai/details/publication/pub.1031072026
    172 rdf:type schema:CreativeWork
    173 https://doi.org/10.1139/v67-132 schema:sameAs https://app.dimensions.ai/details/publication/pub.1048639173
    174 rdf:type schema:CreativeWork
    175 https://doi.org/10.1139/v69-635 schema:sameAs https://app.dimensions.ai/details/publication/pub.1031400197
    176 rdf:type schema:CreativeWork
    177 https://doi.org/10.1246/bcsj.57.1260 schema:sameAs https://app.dimensions.ai/details/publication/pub.1013262700
    178 rdf:type schema:CreativeWork
    179 https://doi.org/10.1246/bcsj.59.497 schema:sameAs https://app.dimensions.ai/details/publication/pub.1045807940
    180 rdf:type schema:CreativeWork
    181 https://doi.org/10.3109/02713688508999969 schema:sameAs https://app.dimensions.ai/details/publication/pub.1018488701
    182 rdf:type schema:CreativeWork
    183 https://www.grid.ac/institutes/grid.64337.35 schema:alternateName Louisiana State University
    184 schema:name Department of Chemistry and Biochemistry, Louisiana State University, 70803, Baton Rouge, LA
    185 The Biodynamics Institute, Louisiana State University, 70803, Baton Rouge, LA
    186 rdf:type schema:Organization
     




    Preview window. Press ESC to close (or click here)


    ...