The kinetics of the autoxidation of polyunsaturated fatty acids View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

1987-05

AUTHORS

John P. Cosgrove, Daniel F. Church, William A. Pryor

ABSTRACT

The kinetics of the autoxidation of a series of polyunsaturated fatty acids (PUFA) with increasing degrees of unsaturation and the mono-, di- and triglycerides of linoleate have been studied in homogeneous chlorobenzene solution at 37 C under 760 torr of oxygen. The autoxidations were initiated by thermal decomposition of azo initiators and followed by measuring the rate of oxygen uptake. The rate of chain initiation was determined by the induction period method using alpha-tocopherol as the chain-breaking antioxidant. The measured oxidizabilities of the PUFA are linearly dependent on the number of doubly allylic positions present in the molecule. Thus, the oxidizability of linoleate is 2.03 X 10(-2) M-1/2 sec-1/2, and the value for docosahexaenoate is five times greater, 10.15 X 10(-2) M-1/2 sec-1/2. The rate of autoxidation for all PUFA studied and for the mono- and diglyceride is proportional to the substrate concentration and to the square root of the rate of chain initiation, implying that the autoxidation of these compounds follows the usual kinetic rate law. The autoxidation of the triglyceride is more complex and does not appear to follow the same rate law at all substrate concentrations. This deviation from the usual kinetic rate expression may be due to lipid aggregation at low concentrations of the triglyceride. More... »

PAGES

299-304

References to SciGraph publications

  • 1947-04. The rates of oxidation of unsaturated fatty acids and esters in JOURNAL OF THE AMERICAN OIL CHEMISTS' SOCIETY
  • Identifiers

    URI

    http://scigraph.springernature.com/pub.10.1007/bf02533996

    DOI

    http://dx.doi.org/10.1007/bf02533996

    DIMENSIONS

    https://app.dimensions.ai/details/publication/pub.1050763736

    PUBMED

    https://www.ncbi.nlm.nih.gov/pubmed/3600206


    Indexing Status Check whether this publication has been indexed by Scopus and Web Of Science using the SN Indexing Status Tool
    Incoming Citations Browse incoming citations for this publication using opencitations.net

    JSON-LD is the canonical representation for SciGraph data.

    TIP: You can open this SciGraph record using an external JSON-LD service: JSON-LD Playground Google SDTT

    [
      {
        "@context": "https://springernature.github.io/scigraph/jsonld/sgcontext.json", 
        "about": [
          {
            "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/1101", 
            "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
            "name": "Medical Biochemistry and Metabolomics", 
            "type": "DefinedTerm"
          }, 
          {
            "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/11", 
            "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
            "name": "Medical and Health Sciences", 
            "type": "DefinedTerm"
          }, 
          {
            "inDefinedTermSet": "https://www.nlm.nih.gov/mesh/", 
            "name": "Chemical Phenomena", 
            "type": "DefinedTerm"
          }, 
          {
            "inDefinedTermSet": "https://www.nlm.nih.gov/mesh/", 
            "name": "Chemistry", 
            "type": "DefinedTerm"
          }, 
          {
            "inDefinedTermSet": "https://www.nlm.nih.gov/mesh/", 
            "name": "Fatty Acids, Unsaturated", 
            "type": "DefinedTerm"
          }, 
          {
            "inDefinedTermSet": "https://www.nlm.nih.gov/mesh/", 
            "name": "Kinetics", 
            "type": "DefinedTerm"
          }, 
          {
            "inDefinedTermSet": "https://www.nlm.nih.gov/mesh/", 
            "name": "Mathematics", 
            "type": "DefinedTerm"
          }, 
          {
            "inDefinedTermSet": "https://www.nlm.nih.gov/mesh/", 
            "name": "Oxidation-Reduction", 
            "type": "DefinedTerm"
          }, 
          {
            "inDefinedTermSet": "https://www.nlm.nih.gov/mesh/", 
            "name": "Triglycerides", 
            "type": "DefinedTerm"
          }, 
          {
            "inDefinedTermSet": "https://www.nlm.nih.gov/mesh/", 
            "name": "Vitamin E", 
            "type": "DefinedTerm"
          }
        ], 
        "author": [
          {
            "affiliation": {
              "alternateName": "Louisiana State University", 
              "id": "https://www.grid.ac/institutes/grid.64337.35", 
              "name": [
                "Department of Chemistry and Biochemistry, Louisiana State University, 70803, Baton Rouge, LA", 
                "The Biodynamics Institute, Louisiana State University, 70803, Baton Rouge, LA"
              ], 
              "type": "Organization"
            }, 
            "familyName": "Cosgrove", 
            "givenName": "John P.", 
            "id": "sg:person.0776175323.42", 
            "sameAs": [
              "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.0776175323.42"
            ], 
            "type": "Person"
          }, 
          {
            "affiliation": {
              "alternateName": "Louisiana State University", 
              "id": "https://www.grid.ac/institutes/grid.64337.35", 
              "name": [
                "Department of Chemistry and Biochemistry, Louisiana State University, 70803, Baton Rouge, LA", 
                "The Biodynamics Institute, Louisiana State University, 70803, Baton Rouge, LA"
              ], 
              "type": "Organization"
            }, 
            "familyName": "Church", 
            "givenName": "Daniel F.", 
            "id": "sg:person.01112423723.36", 
            "sameAs": [
              "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01112423723.36"
            ], 
            "type": "Person"
          }, 
          {
            "affiliation": {
              "alternateName": "Louisiana State University", 
              "id": "https://www.grid.ac/institutes/grid.64337.35", 
              "name": [
                "Department of Chemistry and Biochemistry, Louisiana State University, 70803, Baton Rouge, LA", 
                "The Biodynamics Institute, Louisiana State University, 70803, Baton Rouge, LA"
              ], 
              "type": "Organization"
            }, 
            "familyName": "Pryor", 
            "givenName": "William A.", 
            "id": "sg:person.01364324304.17", 
            "sameAs": [
              "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01364324304.17"
            ], 
            "type": "Person"
          }
        ], 
        "citation": [
          {
            "id": "https://doi.org/10.1016/b978-0-12-566501-8.50008-0", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1011663641"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "https://doi.org/10.1246/bcsj.57.1260", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1013262700"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "sg:pub.10.1007/bf02643258", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1016324062", 
              "https://doi.org/10.1007/bf02643258"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "https://doi.org/10.1016/s8755-9668(86)80024-2", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1016812592"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "https://doi.org/10.3109/02713688508999969", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1018488701"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "https://doi.org/10.1139/v66-169", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1031072026"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "https://doi.org/10.1139/v69-635", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1031400197"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "https://doi.org/10.1016/0005-2736(85)90192-0", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1034930791"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "https://doi.org/10.1016/0005-2736(85)90192-0", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1034930791"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "https://doi.org/10.1016/s0040-4039(00)70159-6", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1034955974"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "https://doi.org/10.1016/b978-0-12-566504-9.50008-8", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1038036543"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "https://doi.org/10.1139/v62-281", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1038950845"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "https://doi.org/10.1246/bcsj.59.497", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1045807940"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "https://doi.org/10.1139/v67-132", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1048639173"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "https://doi.org/10.1016/8755-9668(86)90016-5", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1054570642"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "https://doi.org/10.1016/8755-9668(86)90016-5", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1054570642"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "https://doi.org/10.1021/ja00334a045", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1055724271"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "https://doi.org/10.1021/ja00353a039", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1055725861"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "https://doi.org/10.1021/ja00411a035", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1055730410"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "https://doi.org/10.1021/ja00411a036", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1055730411"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "https://doi.org/10.1021/ja01066a014", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1055765441"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "https://doi.org/10.1021/ja01537a006", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1055805471"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "https://doi.org/10.1021/ja01617a026", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1055812986"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "https://doi.org/10.1021/ja01617a028", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1055812988"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "https://doi.org/10.1021/jo00202a028", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1055972758"
            ], 
            "type": "CreativeWork"
          }
        ], 
        "datePublished": "1987-05", 
        "datePublishedReg": "1987-05-01", 
        "description": "The kinetics of the autoxidation of a series of polyunsaturated fatty acids (PUFA) with increasing degrees of unsaturation and the mono-, di- and triglycerides of linoleate have been studied in homogeneous chlorobenzene solution at 37 C under 760 torr of oxygen. The autoxidations were initiated by thermal decomposition of azo initiators and followed by measuring the rate of oxygen uptake. The rate of chain initiation was determined by the induction period method using alpha-tocopherol as the chain-breaking antioxidant. The measured oxidizabilities of the PUFA are linearly dependent on the number of doubly allylic positions present in the molecule. Thus, the oxidizability of linoleate is 2.03 X 10(-2) M-1/2 sec-1/2, and the value for docosahexaenoate is five times greater, 10.15 X 10(-2) M-1/2 sec-1/2. The rate of autoxidation for all PUFA studied and for the mono- and diglyceride is proportional to the substrate concentration and to the square root of the rate of chain initiation, implying that the autoxidation of these compounds follows the usual kinetic rate law. The autoxidation of the triglyceride is more complex and does not appear to follow the same rate law at all substrate concentrations. This deviation from the usual kinetic rate expression may be due to lipid aggregation at low concentrations of the triglyceride.", 
        "genre": "research_article", 
        "id": "sg:pub.10.1007/bf02533996", 
        "inLanguage": [
          "en"
        ], 
        "isAccessibleForFree": false, 
        "isPartOf": [
          {
            "id": "sg:journal.1006395", 
            "issn": [
              "0024-4201", 
              "1558-9307"
            ], 
            "name": "Lipids", 
            "type": "Periodical"
          }, 
          {
            "issueNumber": "5", 
            "type": "PublicationIssue"
          }, 
          {
            "type": "PublicationVolume", 
            "volumeNumber": "22"
          }
        ], 
        "name": "The kinetics of the autoxidation of polyunsaturated fatty acids", 
        "pagination": "299-304", 
        "productId": [
          {
            "name": "readcube_id", 
            "type": "PropertyValue", 
            "value": [
              "f1d1669288bdd7d0386b4f7edf517a0f3d8d6d41f4b7e6329a96917f7f361b89"
            ]
          }, 
          {
            "name": "pubmed_id", 
            "type": "PropertyValue", 
            "value": [
              "3600206"
            ]
          }, 
          {
            "name": "nlm_unique_id", 
            "type": "PropertyValue", 
            "value": [
              "0060450"
            ]
          }, 
          {
            "name": "doi", 
            "type": "PropertyValue", 
            "value": [
              "10.1007/bf02533996"
            ]
          }, 
          {
            "name": "dimensions_id", 
            "type": "PropertyValue", 
            "value": [
              "pub.1050763736"
            ]
          }
        ], 
        "sameAs": [
          "https://doi.org/10.1007/bf02533996", 
          "https://app.dimensions.ai/details/publication/pub.1050763736"
        ], 
        "sdDataset": "articles", 
        "sdDatePublished": "2019-04-10T16:35", 
        "sdLicense": "https://scigraph.springernature.com/explorer/license/", 
        "sdPublisher": {
          "name": "Springer Nature - SN SciGraph project", 
          "type": "Organization"
        }, 
        "sdSource": "s3://com-uberresearch-data-dimensions-target-20181106-alternative/cleanup/v134/2549eaecd7973599484d7c17b260dba0a4ecb94b/merge/v9/a6c9fde33151104705d4d7ff012ea9563521a3ce/jats-lookup/v90/0000000001_0000000264/records_8669_00000483.jsonl", 
        "type": "ScholarlyArticle", 
        "url": "http://link.springer.com/10.1007/BF02533996"
      }
    ]
     

    Download the RDF metadata as:  json-ld nt turtle xml License info

    HOW TO GET THIS DATA PROGRAMMATICALLY:

    JSON-LD is a popular format for linked data which is fully compatible with JSON.

    curl -H 'Accept: application/ld+json' 'https://scigraph.springernature.com/pub.10.1007/bf02533996'

    N-Triples is a line-based linked data format ideal for batch operations.

    curl -H 'Accept: application/n-triples' 'https://scigraph.springernature.com/pub.10.1007/bf02533996'

    Turtle is a human-readable linked data format.

    curl -H 'Accept: text/turtle' 'https://scigraph.springernature.com/pub.10.1007/bf02533996'

    RDF/XML is a standard XML format for linked data.

    curl -H 'Accept: application/rdf+xml' 'https://scigraph.springernature.com/pub.10.1007/bf02533996'


     

    This table displays all metadata directly associated to this object as RDF triples.

    186 TRIPLES      21 PREDICATES      60 URIs      29 LITERALS      17 BLANK NODES

    Subject Predicate Object
    1 sg:pub.10.1007/bf02533996 schema:about N0f41ad5323f84f8ca99eb3095916cdea
    2 N0f59710342cf431fa3744f7f6443c044
    3 N149bc4a337364c749316ab00b6b03d8a
    4 N197a567b2a1a4dda8c966dc22da2f860
    5 N256e05521fdb4d8fae03a01b8dc765a1
    6 N3267943ab0114b858978cd2bf1961bb5
    7 N3f914b9f01714b038c3203dfe7087658
    8 Nf8551d43aa3041fc9fba8fed060b9ba5
    9 anzsrc-for:11
    10 anzsrc-for:1101
    11 schema:author N17cb01131cca4ea0b83e5c600358b647
    12 schema:citation sg:pub.10.1007/bf02643258
    13 https://doi.org/10.1016/0005-2736(85)90192-0
    14 https://doi.org/10.1016/8755-9668(86)90016-5
    15 https://doi.org/10.1016/b978-0-12-566501-8.50008-0
    16 https://doi.org/10.1016/b978-0-12-566504-9.50008-8
    17 https://doi.org/10.1016/s0040-4039(00)70159-6
    18 https://doi.org/10.1016/s8755-9668(86)80024-2
    19 https://doi.org/10.1021/ja00334a045
    20 https://doi.org/10.1021/ja00353a039
    21 https://doi.org/10.1021/ja00411a035
    22 https://doi.org/10.1021/ja00411a036
    23 https://doi.org/10.1021/ja01066a014
    24 https://doi.org/10.1021/ja01537a006
    25 https://doi.org/10.1021/ja01617a026
    26 https://doi.org/10.1021/ja01617a028
    27 https://doi.org/10.1021/jo00202a028
    28 https://doi.org/10.1139/v62-281
    29 https://doi.org/10.1139/v66-169
    30 https://doi.org/10.1139/v67-132
    31 https://doi.org/10.1139/v69-635
    32 https://doi.org/10.1246/bcsj.57.1260
    33 https://doi.org/10.1246/bcsj.59.497
    34 https://doi.org/10.3109/02713688508999969
    35 schema:datePublished 1987-05
    36 schema:datePublishedReg 1987-05-01
    37 schema:description The kinetics of the autoxidation of a series of polyunsaturated fatty acids (PUFA) with increasing degrees of unsaturation and the mono-, di- and triglycerides of linoleate have been studied in homogeneous chlorobenzene solution at 37 C under 760 torr of oxygen. The autoxidations were initiated by thermal decomposition of azo initiators and followed by measuring the rate of oxygen uptake. The rate of chain initiation was determined by the induction period method using alpha-tocopherol as the chain-breaking antioxidant. The measured oxidizabilities of the PUFA are linearly dependent on the number of doubly allylic positions present in the molecule. Thus, the oxidizability of linoleate is 2.03 X 10(-2) M-1/2 sec-1/2, and the value for docosahexaenoate is five times greater, 10.15 X 10(-2) M-1/2 sec-1/2. The rate of autoxidation for all PUFA studied and for the mono- and diglyceride is proportional to the substrate concentration and to the square root of the rate of chain initiation, implying that the autoxidation of these compounds follows the usual kinetic rate law. The autoxidation of the triglyceride is more complex and does not appear to follow the same rate law at all substrate concentrations. This deviation from the usual kinetic rate expression may be due to lipid aggregation at low concentrations of the triglyceride.
    38 schema:genre research_article
    39 schema:inLanguage en
    40 schema:isAccessibleForFree false
    41 schema:isPartOf N06837d5e6ce64675962861a5ddeb6ad7
    42 Ne4ffdb2a6aa445f6b7d58d4ec00e8659
    43 sg:journal.1006395
    44 schema:name The kinetics of the autoxidation of polyunsaturated fatty acids
    45 schema:pagination 299-304
    46 schema:productId N002e6f97b7d64bd3bb27423173109056
    47 N50492e0d9b9e41a095465e3b811c5623
    48 N694429eeacb646acb9ea3076400891fb
    49 N85e779c6b628431c9002f77508948946
    50 Nbaf7574c843547fe89a6ccadbe3cb405
    51 schema:sameAs https://app.dimensions.ai/details/publication/pub.1050763736
    52 https://doi.org/10.1007/bf02533996
    53 schema:sdDatePublished 2019-04-10T16:35
    54 schema:sdLicense https://scigraph.springernature.com/explorer/license/
    55 schema:sdPublisher Na56e4bb3afe14aa59d5e87c77e90afe8
    56 schema:url http://link.springer.com/10.1007/BF02533996
    57 sgo:license sg:explorer/license/
    58 sgo:sdDataset articles
    59 rdf:type schema:ScholarlyArticle
    60 N002e6f97b7d64bd3bb27423173109056 schema:name nlm_unique_id
    61 schema:value 0060450
    62 rdf:type schema:PropertyValue
    63 N06837d5e6ce64675962861a5ddeb6ad7 schema:issueNumber 5
    64 rdf:type schema:PublicationIssue
    65 N0f41ad5323f84f8ca99eb3095916cdea schema:inDefinedTermSet https://www.nlm.nih.gov/mesh/
    66 schema:name Chemistry
    67 rdf:type schema:DefinedTerm
    68 N0f59710342cf431fa3744f7f6443c044 schema:inDefinedTermSet https://www.nlm.nih.gov/mesh/
    69 schema:name Oxidation-Reduction
    70 rdf:type schema:DefinedTerm
    71 N103950efcc304515b574f6cf1ea5a8cf rdf:first sg:person.01112423723.36
    72 rdf:rest N3822b5e6afb94bdaab07affe3504dc93
    73 N149bc4a337364c749316ab00b6b03d8a schema:inDefinedTermSet https://www.nlm.nih.gov/mesh/
    74 schema:name Mathematics
    75 rdf:type schema:DefinedTerm
    76 N17cb01131cca4ea0b83e5c600358b647 rdf:first sg:person.0776175323.42
    77 rdf:rest N103950efcc304515b574f6cf1ea5a8cf
    78 N197a567b2a1a4dda8c966dc22da2f860 schema:inDefinedTermSet https://www.nlm.nih.gov/mesh/
    79 schema:name Chemical Phenomena
    80 rdf:type schema:DefinedTerm
    81 N256e05521fdb4d8fae03a01b8dc765a1 schema:inDefinedTermSet https://www.nlm.nih.gov/mesh/
    82 schema:name Fatty Acids, Unsaturated
    83 rdf:type schema:DefinedTerm
    84 N3267943ab0114b858978cd2bf1961bb5 schema:inDefinedTermSet https://www.nlm.nih.gov/mesh/
    85 schema:name Vitamin E
    86 rdf:type schema:DefinedTerm
    87 N3822b5e6afb94bdaab07affe3504dc93 rdf:first sg:person.01364324304.17
    88 rdf:rest rdf:nil
    89 N3f914b9f01714b038c3203dfe7087658 schema:inDefinedTermSet https://www.nlm.nih.gov/mesh/
    90 schema:name Triglycerides
    91 rdf:type schema:DefinedTerm
    92 N50492e0d9b9e41a095465e3b811c5623 schema:name doi
    93 schema:value 10.1007/bf02533996
    94 rdf:type schema:PropertyValue
    95 N694429eeacb646acb9ea3076400891fb schema:name dimensions_id
    96 schema:value pub.1050763736
    97 rdf:type schema:PropertyValue
    98 N85e779c6b628431c9002f77508948946 schema:name readcube_id
    99 schema:value f1d1669288bdd7d0386b4f7edf517a0f3d8d6d41f4b7e6329a96917f7f361b89
    100 rdf:type schema:PropertyValue
    101 Na56e4bb3afe14aa59d5e87c77e90afe8 schema:name Springer Nature - SN SciGraph project
    102 rdf:type schema:Organization
    103 Nbaf7574c843547fe89a6ccadbe3cb405 schema:name pubmed_id
    104 schema:value 3600206
    105 rdf:type schema:PropertyValue
    106 Ne4ffdb2a6aa445f6b7d58d4ec00e8659 schema:volumeNumber 22
    107 rdf:type schema:PublicationVolume
    108 Nf8551d43aa3041fc9fba8fed060b9ba5 schema:inDefinedTermSet https://www.nlm.nih.gov/mesh/
    109 schema:name Kinetics
    110 rdf:type schema:DefinedTerm
    111 anzsrc-for:11 schema:inDefinedTermSet anzsrc-for:
    112 schema:name Medical and Health Sciences
    113 rdf:type schema:DefinedTerm
    114 anzsrc-for:1101 schema:inDefinedTermSet anzsrc-for:
    115 schema:name Medical Biochemistry and Metabolomics
    116 rdf:type schema:DefinedTerm
    117 sg:journal.1006395 schema:issn 0024-4201
    118 1558-9307
    119 schema:name Lipids
    120 rdf:type schema:Periodical
    121 sg:person.01112423723.36 schema:affiliation https://www.grid.ac/institutes/grid.64337.35
    122 schema:familyName Church
    123 schema:givenName Daniel F.
    124 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01112423723.36
    125 rdf:type schema:Person
    126 sg:person.01364324304.17 schema:affiliation https://www.grid.ac/institutes/grid.64337.35
    127 schema:familyName Pryor
    128 schema:givenName William A.
    129 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01364324304.17
    130 rdf:type schema:Person
    131 sg:person.0776175323.42 schema:affiliation https://www.grid.ac/institutes/grid.64337.35
    132 schema:familyName Cosgrove
    133 schema:givenName John P.
    134 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.0776175323.42
    135 rdf:type schema:Person
    136 sg:pub.10.1007/bf02643258 schema:sameAs https://app.dimensions.ai/details/publication/pub.1016324062
    137 https://doi.org/10.1007/bf02643258
    138 rdf:type schema:CreativeWork
    139 https://doi.org/10.1016/0005-2736(85)90192-0 schema:sameAs https://app.dimensions.ai/details/publication/pub.1034930791
    140 rdf:type schema:CreativeWork
    141 https://doi.org/10.1016/8755-9668(86)90016-5 schema:sameAs https://app.dimensions.ai/details/publication/pub.1054570642
    142 rdf:type schema:CreativeWork
    143 https://doi.org/10.1016/b978-0-12-566501-8.50008-0 schema:sameAs https://app.dimensions.ai/details/publication/pub.1011663641
    144 rdf:type schema:CreativeWork
    145 https://doi.org/10.1016/b978-0-12-566504-9.50008-8 schema:sameAs https://app.dimensions.ai/details/publication/pub.1038036543
    146 rdf:type schema:CreativeWork
    147 https://doi.org/10.1016/s0040-4039(00)70159-6 schema:sameAs https://app.dimensions.ai/details/publication/pub.1034955974
    148 rdf:type schema:CreativeWork
    149 https://doi.org/10.1016/s8755-9668(86)80024-2 schema:sameAs https://app.dimensions.ai/details/publication/pub.1016812592
    150 rdf:type schema:CreativeWork
    151 https://doi.org/10.1021/ja00334a045 schema:sameAs https://app.dimensions.ai/details/publication/pub.1055724271
    152 rdf:type schema:CreativeWork
    153 https://doi.org/10.1021/ja00353a039 schema:sameAs https://app.dimensions.ai/details/publication/pub.1055725861
    154 rdf:type schema:CreativeWork
    155 https://doi.org/10.1021/ja00411a035 schema:sameAs https://app.dimensions.ai/details/publication/pub.1055730410
    156 rdf:type schema:CreativeWork
    157 https://doi.org/10.1021/ja00411a036 schema:sameAs https://app.dimensions.ai/details/publication/pub.1055730411
    158 rdf:type schema:CreativeWork
    159 https://doi.org/10.1021/ja01066a014 schema:sameAs https://app.dimensions.ai/details/publication/pub.1055765441
    160 rdf:type schema:CreativeWork
    161 https://doi.org/10.1021/ja01537a006 schema:sameAs https://app.dimensions.ai/details/publication/pub.1055805471
    162 rdf:type schema:CreativeWork
    163 https://doi.org/10.1021/ja01617a026 schema:sameAs https://app.dimensions.ai/details/publication/pub.1055812986
    164 rdf:type schema:CreativeWork
    165 https://doi.org/10.1021/ja01617a028 schema:sameAs https://app.dimensions.ai/details/publication/pub.1055812988
    166 rdf:type schema:CreativeWork
    167 https://doi.org/10.1021/jo00202a028 schema:sameAs https://app.dimensions.ai/details/publication/pub.1055972758
    168 rdf:type schema:CreativeWork
    169 https://doi.org/10.1139/v62-281 schema:sameAs https://app.dimensions.ai/details/publication/pub.1038950845
    170 rdf:type schema:CreativeWork
    171 https://doi.org/10.1139/v66-169 schema:sameAs https://app.dimensions.ai/details/publication/pub.1031072026
    172 rdf:type schema:CreativeWork
    173 https://doi.org/10.1139/v67-132 schema:sameAs https://app.dimensions.ai/details/publication/pub.1048639173
    174 rdf:type schema:CreativeWork
    175 https://doi.org/10.1139/v69-635 schema:sameAs https://app.dimensions.ai/details/publication/pub.1031400197
    176 rdf:type schema:CreativeWork
    177 https://doi.org/10.1246/bcsj.57.1260 schema:sameAs https://app.dimensions.ai/details/publication/pub.1013262700
    178 rdf:type schema:CreativeWork
    179 https://doi.org/10.1246/bcsj.59.497 schema:sameAs https://app.dimensions.ai/details/publication/pub.1045807940
    180 rdf:type schema:CreativeWork
    181 https://doi.org/10.3109/02713688508999969 schema:sameAs https://app.dimensions.ai/details/publication/pub.1018488701
    182 rdf:type schema:CreativeWork
    183 https://www.grid.ac/institutes/grid.64337.35 schema:alternateName Louisiana State University
    184 schema:name Department of Chemistry and Biochemistry, Louisiana State University, 70803, Baton Rouge, LA
    185 The Biodynamics Institute, Louisiana State University, 70803, Baton Rouge, LA
    186 rdf:type schema:Organization
     




    Preview window. Press ESC to close (or click here)


    ...