Determination of uranium isotopic composition in aqueous solutions by combined gamma-spectrometry and X-ray fluorescence View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

1983-09

AUTHORS

J. John, F. Šebesta, J. Sedláček

ABSTRACT

The possibility of use of combined gamma spectrometry and X-ray fluorescence for uranium isotopic analysis in dilute aqueous solutions has been studied. Uranium K X-rays were excited by gamma-rays of57Co radionuclide source and were measured together with 185.7 keV gamma-rays of235U using a planar pure Ge detector. Uranium Kα1 fluorescent X-rays were used for the evaluation. The method was proved to be independent of total uranium concentration in the region of 8–20 mg U/ml. The procedure making use of measurement of 7 ml samples and allowing to achieve an accuracy better then 1% in the region of 0.4–4.5 at. % of235U is proposed. More... »

PAGES

367-374

References to SciGraph publications

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/bf02530447

DOI

http://dx.doi.org/10.1007/bf02530447

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1042518411


Indexing Status Check whether this publication has been indexed by Scopus and Web Of Science using the SN Indexing Status Tool
Incoming Citations Browse incoming citations for this publication using opencitations.net

JSON-LD is the canonical representation for SciGraph data.

TIP: You can open this SciGraph record using an external JSON-LD service: JSON-LD Playground Google SDTT

[
  {
    "@context": "https://springernature.github.io/scigraph/jsonld/sgcontext.json", 
    "about": [
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/03", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Chemical Sciences", 
        "type": "DefinedTerm"
      }, 
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/0301", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Analytical Chemistry", 
        "type": "DefinedTerm"
      }, 
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/0302", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Inorganic Chemistry", 
        "type": "DefinedTerm"
      }, 
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/0306", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Physical Chemistry (incl. Structural)", 
        "type": "DefinedTerm"
      }
    ], 
    "author": [
      {
        "affiliation": {
          "alternateName": "Department of Nuclear Chemistry, Technical University of Prague, B\u0159ehov\u00e1 7, 115 19, Prague 1, (Czechoslovakia)", 
          "id": "http://www.grid.ac/institutes/grid.6652.7", 
          "name": [
            "Department of Nuclear Chemistry, Technical University of Prague, B\u0159ehov\u00e1 7, 115 19, Prague 1, (Czechoslovakia)"
          ], 
          "type": "Organization"
        }, 
        "familyName": "John", 
        "givenName": "J.", 
        "id": "sg:person.013243333231.24", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.013243333231.24"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Department of Nuclear Chemistry, Technical University of Prague, B\u0159ehov\u00e1 7, 115 19, Prague 1, (Czechoslovakia)", 
          "id": "http://www.grid.ac/institutes/grid.6652.7", 
          "name": [
            "Department of Nuclear Chemistry, Technical University of Prague, B\u0159ehov\u00e1 7, 115 19, Prague 1, (Czechoslovakia)"
          ], 
          "type": "Organization"
        }, 
        "familyName": "\u0160ebesta", 
        "givenName": "F.", 
        "id": "sg:person.014502716325.78", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.014502716325.78"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Department of Nuclear Chemistry, Technical University of Prague, B\u0159ehov\u00e1 7, 115 19, Prague 1, (Czechoslovakia)", 
          "id": "http://www.grid.ac/institutes/grid.6652.7", 
          "name": [
            "Department of Nuclear Chemistry, Technical University of Prague, B\u0159ehov\u00e1 7, 115 19, Prague 1, (Czechoslovakia)"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Sedl\u00e1\u010dek", 
        "givenName": "J.", 
        "id": "sg:person.015332676363.43", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.015332676363.43"
        ], 
        "type": "Person"
      }
    ], 
    "citation": [
      {
        "id": "sg:pub.10.1007/bf02515212", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1008416360", 
          "https://doi.org/10.1007/bf02515212"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1007/bf02518467", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1036545480", 
          "https://doi.org/10.1007/bf02518467"
        ], 
        "type": "CreativeWork"
      }
    ], 
    "datePublished": "1983-09", 
    "datePublishedReg": "1983-09-01", 
    "description": "The possibility of use of combined gamma spectrometry and X-ray fluorescence for uranium isotopic analysis in dilute aqueous solutions has been studied. Uranium K X-rays were excited by gamma-rays of57Co radionuclide source and were measured together with 185.7 keV gamma-rays of235U using a planar pure Ge detector. Uranium K\u03b11 fluorescent X-rays were used for the evaluation. The method was proved to be independent of total uranium concentration in the region of 8\u201320 mg U/ml. The procedure making use of measurement of 7 ml samples and allowing to achieve an accuracy better then 1% in the region of 0.4\u20134.5 at. % of235U is proposed.", 
    "genre": "article", 
    "id": "sg:pub.10.1007/bf02530447", 
    "inLanguage": "en", 
    "isAccessibleForFree": false, 
    "isPartOf": [
      {
        "id": "sg:journal.1094634", 
        "issn": [
          "0236-5731", 
          "1588-2780"
        ], 
        "name": "Journal of Radioanalytical and Nuclear Chemistry", 
        "publisher": "Springer Nature", 
        "type": "Periodical"
      }, 
      {
        "issueNumber": "2", 
        "type": "PublicationIssue"
      }, 
      {
        "type": "PublicationVolume", 
        "volumeNumber": "78"
      }
    ], 
    "keywords": [
      "pure Ge detector", 
      "ray fluorescence", 
      "Ge detector", 
      "fluorescent X", 
      "radionuclide sources", 
      "uranium isotopic analysis", 
      "rays", 
      "of235U", 
      "total uranium concentration", 
      "use of measurements", 
      "fluorescence", 
      "uranium isotopic composition", 
      "detector", 
      "gamma spectrometry", 
      "aqueous solution", 
      "dilute aqueous solutions", 
      "measurements", 
      "region", 
      "source", 
      "possibility of use", 
      "spectrometry", 
      "possibility", 
      "determination", 
      "solution", 
      "composition", 
      "isotopic analysis", 
      "isotopic composition", 
      "samples", 
      "method", 
      "accuracy", 
      "uranium concentration", 
      "use", 
      "analysis", 
      "concentration", 
      "procedure", 
      "evaluation", 
      "Uranium K X", 
      "K X", 
      "gamma-rays of57Co radionuclide source", 
      "of57Co radionuclide source", 
      "keV gamma-rays of235U", 
      "gamma-rays of235U", 
      "planar pure Ge detector", 
      "Uranium K\u03b11 fluorescent X", 
      "K\u03b11 fluorescent X"
    ], 
    "name": "Determination of uranium isotopic composition in aqueous solutions by combined gamma-spectrometry and X-ray fluorescence", 
    "pagination": "367-374", 
    "productId": [
      {
        "name": "dimensions_id", 
        "type": "PropertyValue", 
        "value": [
          "pub.1042518411"
        ]
      }, 
      {
        "name": "doi", 
        "type": "PropertyValue", 
        "value": [
          "10.1007/bf02530447"
        ]
      }
    ], 
    "sameAs": [
      "https://doi.org/10.1007/bf02530447", 
      "https://app.dimensions.ai/details/publication/pub.1042518411"
    ], 
    "sdDataset": "articles", 
    "sdDatePublished": "2021-12-01T19:05", 
    "sdLicense": "https://scigraph.springernature.com/explorer/license/", 
    "sdPublisher": {
      "name": "Springer Nature - SN SciGraph project", 
      "type": "Organization"
    }, 
    "sdSource": "s3://com-springernature-scigraph/baseset/20211201/entities/gbq_results/article/article_178.jsonl", 
    "type": "ScholarlyArticle", 
    "url": "https://doi.org/10.1007/bf02530447"
  }
]
 

Download the RDF metadata as:  json-ld nt turtle xml License info

HOW TO GET THIS DATA PROGRAMMATICALLY:

JSON-LD is a popular format for linked data which is fully compatible with JSON.

curl -H 'Accept: application/ld+json' 'https://scigraph.springernature.com/pub.10.1007/bf02530447'

N-Triples is a line-based linked data format ideal for batch operations.

curl -H 'Accept: application/n-triples' 'https://scigraph.springernature.com/pub.10.1007/bf02530447'

Turtle is a human-readable linked data format.

curl -H 'Accept: text/turtle' 'https://scigraph.springernature.com/pub.10.1007/bf02530447'

RDF/XML is a standard XML format for linked data.

curl -H 'Accept: application/rdf+xml' 'https://scigraph.springernature.com/pub.10.1007/bf02530447'


 

This table displays all metadata directly associated to this object as RDF triples.

133 TRIPLES      22 PREDICATES      75 URIs      63 LITERALS      6 BLANK NODES

Subject Predicate Object
1 sg:pub.10.1007/bf02530447 schema:about anzsrc-for:03
2 anzsrc-for:0301
3 anzsrc-for:0302
4 anzsrc-for:0306
5 schema:author Neca6d18700c84441bdbacfb97cd54176
6 schema:citation sg:pub.10.1007/bf02515212
7 sg:pub.10.1007/bf02518467
8 schema:datePublished 1983-09
9 schema:datePublishedReg 1983-09-01
10 schema:description The possibility of use of combined gamma spectrometry and X-ray fluorescence for uranium isotopic analysis in dilute aqueous solutions has been studied. Uranium K X-rays were excited by gamma-rays of57Co radionuclide source and were measured together with 185.7 keV gamma-rays of235U using a planar pure Ge detector. Uranium Kα1 fluorescent X-rays were used for the evaluation. The method was proved to be independent of total uranium concentration in the region of 8–20 mg U/ml. The procedure making use of measurement of 7 ml samples and allowing to achieve an accuracy better then 1% in the region of 0.4–4.5 at. % of235U is proposed.
11 schema:genre article
12 schema:inLanguage en
13 schema:isAccessibleForFree false
14 schema:isPartOf N51ccedfd13ae45818eea8427da612f72
15 Nfa2e8bda2ca048e39411a39b72265c51
16 sg:journal.1094634
17 schema:keywords Ge detector
18 K X
19 Kα1 fluorescent X
20 Uranium K X
21 Uranium Kα1 fluorescent X
22 accuracy
23 analysis
24 aqueous solution
25 composition
26 concentration
27 detector
28 determination
29 dilute aqueous solutions
30 evaluation
31 fluorescence
32 fluorescent X
33 gamma spectrometry
34 gamma-rays of235U
35 gamma-rays of57Co radionuclide source
36 isotopic analysis
37 isotopic composition
38 keV gamma-rays of235U
39 measurements
40 method
41 of235U
42 of57Co radionuclide source
43 planar pure Ge detector
44 possibility
45 possibility of use
46 procedure
47 pure Ge detector
48 radionuclide sources
49 ray fluorescence
50 rays
51 region
52 samples
53 solution
54 source
55 spectrometry
56 total uranium concentration
57 uranium concentration
58 uranium isotopic analysis
59 uranium isotopic composition
60 use
61 use of measurements
62 schema:name Determination of uranium isotopic composition in aqueous solutions by combined gamma-spectrometry and X-ray fluorescence
63 schema:pagination 367-374
64 schema:productId N95b420b43ca14ca79defa27d11abbdd8
65 Nc683b4483d60473290e951e04475cc43
66 schema:sameAs https://app.dimensions.ai/details/publication/pub.1042518411
67 https://doi.org/10.1007/bf02530447
68 schema:sdDatePublished 2021-12-01T19:05
69 schema:sdLicense https://scigraph.springernature.com/explorer/license/
70 schema:sdPublisher Nb491d529a54a4f6da18580b37ffc3979
71 schema:url https://doi.org/10.1007/bf02530447
72 sgo:license sg:explorer/license/
73 sgo:sdDataset articles
74 rdf:type schema:ScholarlyArticle
75 N00eaa20589044a77bf92364bf1f19003 rdf:first sg:person.015332676363.43
76 rdf:rest rdf:nil
77 N51ccedfd13ae45818eea8427da612f72 schema:issueNumber 2
78 rdf:type schema:PublicationIssue
79 N95b420b43ca14ca79defa27d11abbdd8 schema:name doi
80 schema:value 10.1007/bf02530447
81 rdf:type schema:PropertyValue
82 Nb491d529a54a4f6da18580b37ffc3979 schema:name Springer Nature - SN SciGraph project
83 rdf:type schema:Organization
84 Nc683b4483d60473290e951e04475cc43 schema:name dimensions_id
85 schema:value pub.1042518411
86 rdf:type schema:PropertyValue
87 Nd3c2d6d560894b63acee238e3ee646f5 rdf:first sg:person.014502716325.78
88 rdf:rest N00eaa20589044a77bf92364bf1f19003
89 Neca6d18700c84441bdbacfb97cd54176 rdf:first sg:person.013243333231.24
90 rdf:rest Nd3c2d6d560894b63acee238e3ee646f5
91 Nfa2e8bda2ca048e39411a39b72265c51 schema:volumeNumber 78
92 rdf:type schema:PublicationVolume
93 anzsrc-for:03 schema:inDefinedTermSet anzsrc-for:
94 schema:name Chemical Sciences
95 rdf:type schema:DefinedTerm
96 anzsrc-for:0301 schema:inDefinedTermSet anzsrc-for:
97 schema:name Analytical Chemistry
98 rdf:type schema:DefinedTerm
99 anzsrc-for:0302 schema:inDefinedTermSet anzsrc-for:
100 schema:name Inorganic Chemistry
101 rdf:type schema:DefinedTerm
102 anzsrc-for:0306 schema:inDefinedTermSet anzsrc-for:
103 schema:name Physical Chemistry (incl. Structural)
104 rdf:type schema:DefinedTerm
105 sg:journal.1094634 schema:issn 0236-5731
106 1588-2780
107 schema:name Journal of Radioanalytical and Nuclear Chemistry
108 schema:publisher Springer Nature
109 rdf:type schema:Periodical
110 sg:person.013243333231.24 schema:affiliation grid-institutes:grid.6652.7
111 schema:familyName John
112 schema:givenName J.
113 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.013243333231.24
114 rdf:type schema:Person
115 sg:person.014502716325.78 schema:affiliation grid-institutes:grid.6652.7
116 schema:familyName Šebesta
117 schema:givenName F.
118 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.014502716325.78
119 rdf:type schema:Person
120 sg:person.015332676363.43 schema:affiliation grid-institutes:grid.6652.7
121 schema:familyName Sedláček
122 schema:givenName J.
123 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.015332676363.43
124 rdf:type schema:Person
125 sg:pub.10.1007/bf02515212 schema:sameAs https://app.dimensions.ai/details/publication/pub.1008416360
126 https://doi.org/10.1007/bf02515212
127 rdf:type schema:CreativeWork
128 sg:pub.10.1007/bf02518467 schema:sameAs https://app.dimensions.ai/details/publication/pub.1036545480
129 https://doi.org/10.1007/bf02518467
130 rdf:type schema:CreativeWork
131 grid-institutes:grid.6652.7 schema:alternateName Department of Nuclear Chemistry, Technical University of Prague, Břehová 7, 115 19, Prague 1, (Czechoslovakia)
132 schema:name Department of Nuclear Chemistry, Technical University of Prague, Břehová 7, 115 19, Prague 1, (Czechoslovakia)
133 rdf:type schema:Organization
 




Preview window. Press ESC to close (or click here)


...