The use of14C,59Fe and65Ni radionuclides for the study of solvent effects on the extraction equilibria with n-caprylic acid View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

1976-09

AUTHORS

A. I. Kholkin, L. M. Gindin, K. S. Luboshnikova, P. Mühl, K. Gloe

ABSTRACT

The distribution of n-caprylic acid between an aqueous sodium sulphate solution and several organic diluents of various properties has been investigated, using14C-labelled n-caprylic acid. The distribution coefficients of the monomeric capyrlic acid and its dimerization constants in the organic phase were determined. The extraction of Fe(III) and Ni(II) with n-caprylic acid solutions in various diluents was studied using the AKUFVE solvent extraction equipment. The composition of the extracted compound of Fe(III) has been determined and the extraction constants for all the studied systems have been calculated. For the extraction of Ni(II) the constants of the extraction of nickel caprylate monomers and its dimerization constants in the organic phase have been calculated. More... »

PAGES

383-395

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/bf02516972

DOI

http://dx.doi.org/10.1007/bf02516972

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1052113581


Indexing Status Check whether this publication has been indexed by Scopus and Web Of Science using the SN Indexing Status Tool
Incoming Citations Browse incoming citations for this publication using opencitations.net

JSON-LD is the canonical representation for SciGraph data.

TIP: You can open this SciGraph record using an external JSON-LD service: JSON-LD Playground Google SDTT

[
  {
    "@context": "https://springernature.github.io/scigraph/jsonld/sgcontext.json", 
    "about": [
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/0402", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Geochemistry", 
        "type": "DefinedTerm"
      }, 
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/04", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Earth Sciences", 
        "type": "DefinedTerm"
      }
    ], 
    "author": [
      {
        "affiliation": {
          "name": [
            "Institute of Inorganic Chemistry, Sibirian Branch of the Academy of Science of the USSR, Novosibirsk, (USSR)"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Kholkin", 
        "givenName": "A. I.", 
        "id": "sg:person.012564636164.42", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.012564636164.42"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "name": [
            "Institute of Inorganic Chemistry, Sibirian Branch of the Academy of Science of the USSR, Novosibirsk, (USSR)"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Gindin", 
        "givenName": "L. M.", 
        "id": "sg:person.014135122764.88", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.014135122764.88"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "name": [
            "Institute of Inorganic Chemistry, Sibirian Branch of the Academy of Science of the USSR, Novosibirsk, (USSR)"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Luboshnikova", 
        "givenName": "K. S.", 
        "id": "sg:person.015111636033.24", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.015111636033.24"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "name": [
            "Central Institute of Solid State Physics and Material Research, Academy of Science of GDR, Dresden, (GDR)"
          ], 
          "type": "Organization"
        }, 
        "familyName": "M\u00fchl", 
        "givenName": "P.", 
        "id": "sg:person.016056317703.31", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.016056317703.31"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "name": [
            "Central Institute of Solid State Physics and Material Research, Academy of Science of GDR, Dresden, (GDR)"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Gloe", 
        "givenName": "K.", 
        "id": "sg:person.0701557164.18", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.0701557164.18"
        ], 
        "type": "Person"
      }
    ], 
    "citation": [
      {
        "id": "https://doi.org/10.1016/s0003-2670(00)89387-3", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1047958240"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/0022-1902(69)80592-0", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1053167496"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/0022-1902(69)80592-0", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1053167496"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/cr60081a002", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1054074177"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/ja01548a023", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1055806427"
        ], 
        "type": "CreativeWork"
      }
    ], 
    "datePublished": "1976-09", 
    "datePublishedReg": "1976-09-01", 
    "description": "The distribution of n-caprylic acid between an aqueous sodium sulphate solution and several organic diluents of various properties has been investigated, using14C-labelled n-caprylic acid. The distribution coefficients of the monomeric capyrlic acid and its dimerization constants in the organic phase were determined. The extraction of Fe(III) and Ni(II) with n-caprylic acid solutions in various diluents was studied using the AKUFVE solvent extraction equipment. The composition of the extracted compound of Fe(III) has been determined and the extraction constants for all the studied systems have been calculated. For the extraction of Ni(II) the constants of the extraction of nickel caprylate monomers and its dimerization constants in the organic phase have been calculated.", 
    "genre": "research_article", 
    "id": "sg:pub.10.1007/bf02516972", 
    "inLanguage": [
      "en"
    ], 
    "isAccessibleForFree": false, 
    "isPartOf": [
      {
        "id": "sg:journal.1083229", 
        "issn": [
          "0134-0719", 
          "2064-2857"
        ], 
        "name": "Journal of Radioanalytical Chemistry", 
        "type": "Periodical"
      }, 
      {
        "issueNumber": "2", 
        "type": "PublicationIssue"
      }, 
      {
        "type": "PublicationVolume", 
        "volumeNumber": "30"
      }
    ], 
    "name": "The use of14C,59Fe and65Ni radionuclides for the study of solvent effects on the extraction equilibria with n-caprylic acid", 
    "pagination": "383-395", 
    "productId": [
      {
        "name": "readcube_id", 
        "type": "PropertyValue", 
        "value": [
          "f83c112e5c6f1438a055660c290406b265556fdc6e94be3542c6a9d296a36537"
        ]
      }, 
      {
        "name": "doi", 
        "type": "PropertyValue", 
        "value": [
          "10.1007/bf02516972"
        ]
      }, 
      {
        "name": "dimensions_id", 
        "type": "PropertyValue", 
        "value": [
          "pub.1052113581"
        ]
      }
    ], 
    "sameAs": [
      "https://doi.org/10.1007/bf02516972", 
      "https://app.dimensions.ai/details/publication/pub.1052113581"
    ], 
    "sdDataset": "articles", 
    "sdDatePublished": "2019-04-11T13:30", 
    "sdLicense": "https://scigraph.springernature.com/explorer/license/", 
    "sdPublisher": {
      "name": "Springer Nature - SN SciGraph project", 
      "type": "Organization"
    }, 
    "sdSource": "s3://com-uberresearch-data-dimensions-target-20181106-alternative/cleanup/v134/2549eaecd7973599484d7c17b260dba0a4ecb94b/merge/v9/a6c9fde33151104705d4d7ff012ea9563521a3ce/jats-lookup/v90/0000000370_0000000370/records_46751_00000002.jsonl", 
    "type": "ScholarlyArticle", 
    "url": "http://link.springer.com/10.1007%2FBF02516972"
  }
]
 

Download the RDF metadata as:  json-ld nt turtle xml License info

HOW TO GET THIS DATA PROGRAMMATICALLY:

JSON-LD is a popular format for linked data which is fully compatible with JSON.

curl -H 'Accept: application/ld+json' 'https://scigraph.springernature.com/pub.10.1007/bf02516972'

N-Triples is a line-based linked data format ideal for batch operations.

curl -H 'Accept: application/n-triples' 'https://scigraph.springernature.com/pub.10.1007/bf02516972'

Turtle is a human-readable linked data format.

curl -H 'Accept: text/turtle' 'https://scigraph.springernature.com/pub.10.1007/bf02516972'

RDF/XML is a standard XML format for linked data.

curl -H 'Accept: application/rdf+xml' 'https://scigraph.springernature.com/pub.10.1007/bf02516972'


 

This table displays all metadata directly associated to this object as RDF triples.

108 TRIPLES      21 PREDICATES      31 URIs      19 LITERALS      7 BLANK NODES

Subject Predicate Object
1 sg:pub.10.1007/bf02516972 schema:about anzsrc-for:04
2 anzsrc-for:0402
3 schema:author N9993b28f941149adbe38566b492b18b8
4 schema:citation https://doi.org/10.1016/0022-1902(69)80592-0
5 https://doi.org/10.1016/s0003-2670(00)89387-3
6 https://doi.org/10.1021/cr60081a002
7 https://doi.org/10.1021/ja01548a023
8 schema:datePublished 1976-09
9 schema:datePublishedReg 1976-09-01
10 schema:description The distribution of n-caprylic acid between an aqueous sodium sulphate solution and several organic diluents of various properties has been investigated, using14C-labelled n-caprylic acid. The distribution coefficients of the monomeric capyrlic acid and its dimerization constants in the organic phase were determined. The extraction of Fe(III) and Ni(II) with n-caprylic acid solutions in various diluents was studied using the AKUFVE solvent extraction equipment. The composition of the extracted compound of Fe(III) has been determined and the extraction constants for all the studied systems have been calculated. For the extraction of Ni(II) the constants of the extraction of nickel caprylate monomers and its dimerization constants in the organic phase have been calculated.
11 schema:genre research_article
12 schema:inLanguage en
13 schema:isAccessibleForFree false
14 schema:isPartOf N21ac814a2aed420586ffdae5ae83aeeb
15 N6ca28a4c015d4f06ae06f03fc20380c3
16 sg:journal.1083229
17 schema:name The use of14C,59Fe and65Ni radionuclides for the study of solvent effects on the extraction equilibria with n-caprylic acid
18 schema:pagination 383-395
19 schema:productId Na70b94ba61ed4f80a81470ba9d7b6f19
20 Ncb615a1ee7d44c1caf5948de13954540
21 Nd1db008df7a64bac9bf255f03a438bea
22 schema:sameAs https://app.dimensions.ai/details/publication/pub.1052113581
23 https://doi.org/10.1007/bf02516972
24 schema:sdDatePublished 2019-04-11T13:30
25 schema:sdLicense https://scigraph.springernature.com/explorer/license/
26 schema:sdPublisher N805d57b3fb054abd96a247d4f736d2c9
27 schema:url http://link.springer.com/10.1007%2FBF02516972
28 sgo:license sg:explorer/license/
29 sgo:sdDataset articles
30 rdf:type schema:ScholarlyArticle
31 N077078e6a3a04b048dc1ebd4587c5181 schema:name Central Institute of Solid State Physics and Material Research, Academy of Science of GDR, Dresden, (GDR)
32 rdf:type schema:Organization
33 N21ac814a2aed420586ffdae5ae83aeeb schema:issueNumber 2
34 rdf:type schema:PublicationIssue
35 N3133f0dc88df47baa0ed7de86fc2fa3d schema:name Institute of Inorganic Chemistry, Sibirian Branch of the Academy of Science of the USSR, Novosibirsk, (USSR)
36 rdf:type schema:Organization
37 N45203c5e0ec34d4cbba9269570a70c5d rdf:first sg:person.0701557164.18
38 rdf:rest rdf:nil
39 N5746c7a5f88c49f7898023aa5711e332 rdf:first sg:person.014135122764.88
40 rdf:rest Nb3ee43b1ab0544e799d5bb505b32593c
41 N6ca28a4c015d4f06ae06f03fc20380c3 schema:volumeNumber 30
42 rdf:type schema:PublicationVolume
43 N805d57b3fb054abd96a247d4f736d2c9 schema:name Springer Nature - SN SciGraph project
44 rdf:type schema:Organization
45 N9993b28f941149adbe38566b492b18b8 rdf:first sg:person.012564636164.42
46 rdf:rest N5746c7a5f88c49f7898023aa5711e332
47 N9f1bd7cacbca4eb6873d42e8974701ea schema:name Institute of Inorganic Chemistry, Sibirian Branch of the Academy of Science of the USSR, Novosibirsk, (USSR)
48 rdf:type schema:Organization
49 Na70b94ba61ed4f80a81470ba9d7b6f19 schema:name dimensions_id
50 schema:value pub.1052113581
51 rdf:type schema:PropertyValue
52 Nb3ee43b1ab0544e799d5bb505b32593c rdf:first sg:person.015111636033.24
53 rdf:rest Nc4b75301f5754667a629b5060f564672
54 Nc4b75301f5754667a629b5060f564672 rdf:first sg:person.016056317703.31
55 rdf:rest N45203c5e0ec34d4cbba9269570a70c5d
56 Ncb615a1ee7d44c1caf5948de13954540 schema:name doi
57 schema:value 10.1007/bf02516972
58 rdf:type schema:PropertyValue
59 Nd1db008df7a64bac9bf255f03a438bea schema:name readcube_id
60 schema:value f83c112e5c6f1438a055660c290406b265556fdc6e94be3542c6a9d296a36537
61 rdf:type schema:PropertyValue
62 Nd575eb26de724d66bdd872322f06af66 schema:name Central Institute of Solid State Physics and Material Research, Academy of Science of GDR, Dresden, (GDR)
63 rdf:type schema:Organization
64 Ne208c4c3ae814e01b9a3e04e7d60e350 schema:name Institute of Inorganic Chemistry, Sibirian Branch of the Academy of Science of the USSR, Novosibirsk, (USSR)
65 rdf:type schema:Organization
66 anzsrc-for:04 schema:inDefinedTermSet anzsrc-for:
67 schema:name Earth Sciences
68 rdf:type schema:DefinedTerm
69 anzsrc-for:0402 schema:inDefinedTermSet anzsrc-for:
70 schema:name Geochemistry
71 rdf:type schema:DefinedTerm
72 sg:journal.1083229 schema:issn 0134-0719
73 2064-2857
74 schema:name Journal of Radioanalytical Chemistry
75 rdf:type schema:Periodical
76 sg:person.012564636164.42 schema:affiliation N9f1bd7cacbca4eb6873d42e8974701ea
77 schema:familyName Kholkin
78 schema:givenName A. I.
79 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.012564636164.42
80 rdf:type schema:Person
81 sg:person.014135122764.88 schema:affiliation Ne208c4c3ae814e01b9a3e04e7d60e350
82 schema:familyName Gindin
83 schema:givenName L. M.
84 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.014135122764.88
85 rdf:type schema:Person
86 sg:person.015111636033.24 schema:affiliation N3133f0dc88df47baa0ed7de86fc2fa3d
87 schema:familyName Luboshnikova
88 schema:givenName K. S.
89 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.015111636033.24
90 rdf:type schema:Person
91 sg:person.016056317703.31 schema:affiliation Nd575eb26de724d66bdd872322f06af66
92 schema:familyName Mühl
93 schema:givenName P.
94 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.016056317703.31
95 rdf:type schema:Person
96 sg:person.0701557164.18 schema:affiliation N077078e6a3a04b048dc1ebd4587c5181
97 schema:familyName Gloe
98 schema:givenName K.
99 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.0701557164.18
100 rdf:type schema:Person
101 https://doi.org/10.1016/0022-1902(69)80592-0 schema:sameAs https://app.dimensions.ai/details/publication/pub.1053167496
102 rdf:type schema:CreativeWork
103 https://doi.org/10.1016/s0003-2670(00)89387-3 schema:sameAs https://app.dimensions.ai/details/publication/pub.1047958240
104 rdf:type schema:CreativeWork
105 https://doi.org/10.1021/cr60081a002 schema:sameAs https://app.dimensions.ai/details/publication/pub.1054074177
106 rdf:type schema:CreativeWork
107 https://doi.org/10.1021/ja01548a023 schema:sameAs https://app.dimensions.ai/details/publication/pub.1055806427
108 rdf:type schema:CreativeWork
 




Preview window. Press ESC to close (or click here)


...