Synthesis, structures, and properties of spiro[6-azaperimidine-2,4′-cyclohexa-2′,5′-dien]-1′-one derivatives View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

1997-11

AUTHORS

V. N. Komissarov, E. N. Gruzdeva, L. P. Olekhnovich, G. S. Borodkin, V. N. Khrustalev, S. V. Lindeman, Yu. T. Struchkov, V. A. Kogan, V. I. Minkin

ABSTRACT

The reaction of 5-amino-4-chloroquinolines with 4-amino-2,6-di-tert-butylphenol yielded derivatives of spiro[6-azaperimidine-2,4′-cyclohexa-2′,5′-dien]-1′-one, which exhibit photo-and thermochromic properties in solutions. The structure of 2′,6′-di-tert-butyl-5,7,9-trimethylspiro[6-aza,-2,3-dihydroperimidine-2,4′-cyclohexa-2′,5′-dien]-1′-one was established by X-ray diffraction study. The ring-chain isomerization of 2′,6′-di-tert-butyl-5,7-dimethyl-and 2′,6′-di-tert-butyl-5,7,8-trimethylspiro[6-aza-2,3-dihydroperimidine-2,4′-cyclohexa-2′,5′-dien]-1′-ones was studied by dynamic NMR spectroscopy.

PAGES

1924-1930

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/bf02503788

DOI

http://dx.doi.org/10.1007/bf02503788

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1044355387


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