Tetramethylsilane as reagent gas: mass spectra of nitrocarboxylic acid esters and nitroalcohols View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

1998-06

AUTHORS

V. I. Kadentsev, N. G. Kolotyrkina, A. A. Stomakhin, O S. Chizhov, S. L. Ioffe, I. M. Lypkalo, A. D. Dil'man, A. A. Tishkov

ABSTRACT

Nitrocarboxylic acid esters and nitroalcohols react with trimethylsilyl cation in the gas phase under conditions of chemical ionization to form stable [M+SiMe3]+ ions. The pathways of their fragmentation were established and characteristic distinctions in the mass spectra caused by mutual arrangement of functional groups were found.

PAGES

1225-1228

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/bf02503504

DOI

http://dx.doi.org/10.1007/bf02503504

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1028018486


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