Effect of the type of linkage between phenyl groups on the structure and photochemical properties of 2,2-diaryl-substituted pyridoannelated [2H]-chromenes View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

1998-06

AUTHORS

S. M. Aldoshin, I. I. Chuev, O. S. Filipenko, A. N. Utenyshev, G. Harie, V. Lokshin, A. Samat, R. Guglielmetti, G. Pepe

ABSTRACT

Three 2,2-diaryl-substituted pyridoannelated [2H]-chromenes have been studied by X-ray diffraction analysis. Bonding of the benzene rings through bridges of different nature and with different length affects substantially the orientation of the benzene rings, steric interactions at the C center, the conformation of the molecule, and the C−O bond length. A correlation between the photocolorability of chromenes under study and the orientation of the benzene rings with respect to the C−O bond, which provides different prerequisites to stabilization of the C(1)-centered, cation formed upon cleavage of the C−O bond, was established. The effect of the orientation of the benzene rings on the dark reaction of ring closure was found. More... »

PAGES

1098-1104

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/bf02503478

DOI

http://dx.doi.org/10.1007/bf02503478

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1043555079


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