Effect of the type of linkage between phenyl groups on the structure and photochemical properties of 2,2-diaryl-substituted pyridoannelated [2H]-chromenes View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

1998-06

AUTHORS

S. M. Aldoshin, I. I. Chuev, O. S. Filipenko, A. N. Utenyshev, G. Harie, V. Lokshin, A. Samat, R. Guglielmetti, G. Pepe

ABSTRACT

Three 2,2-diaryl-substituted pyridoannelated [2H]-chromenes have been studied by X-ray diffraction analysis. Bonding of the benzene rings through bridges of different nature and with different length affects substantially the orientation of the benzene rings, steric interactions at the C center, the conformation of the molecule, and the C−O bond length. A correlation between the photocolorability of chromenes under study and the orientation of the benzene rings with respect to the C−O bond, which provides different prerequisites to stabilization of the C(1)-centered, cation formed upon cleavage of the C−O bond, was established. The effect of the orientation of the benzene rings on the dark reaction of ring closure was found. More... »

PAGES

1098-1104

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/bf02503478

DOI

http://dx.doi.org/10.1007/bf02503478

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1043555079


Indexing Status Check whether this publication has been indexed by Scopus and Web Of Science using the SN Indexing Status Tool
Incoming Citations Browse incoming citations for this publication using opencitations.net

JSON-LD is the canonical representation for SciGraph data.

TIP: You can open this SciGraph record using an external JSON-LD service: JSON-LD Playground Google SDTT

[
  {
    "@context": "https://springernature.github.io/scigraph/jsonld/sgcontext.json", 
    "about": [
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/03", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Chemical Sciences", 
        "type": "DefinedTerm"
      }, 
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/0306", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Physical Chemistry (incl. Structural)", 
        "type": "DefinedTerm"
      }
    ], 
    "author": [
      {
        "affiliation": {
          "alternateName": "Institute of Chemical Physics in Chernogolovka, Russian Academy of Sciences, 142432, Chernogolovka, Moscow Region, Russian Federation", 
          "id": "http://www.grid.ac/institutes/grid.4886.2", 
          "name": [
            "Institute of Chemical Physics in Chernogolovka, Russian Academy of Sciences, 142432, Chernogolovka, Moscow Region, Russian Federation"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Aldoshin", 
        "givenName": "S. M.", 
        "id": "sg:person.013232115673.09", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.013232115673.09"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Institute of Chemical Physics in Chernogolovka, Russian Academy of Sciences, 142432, Chernogolovka, Moscow Region, Russian Federation", 
          "id": "http://www.grid.ac/institutes/grid.4886.2", 
          "name": [
            "Institute of Chemical Physics in Chernogolovka, Russian Academy of Sciences, 142432, Chernogolovka, Moscow Region, Russian Federation"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Chuev", 
        "givenName": "I. I.", 
        "id": "sg:person.012555612421.75", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.012555612421.75"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Institute of Chemical Physics in Chernogolovka, Russian Academy of Sciences, 142432, Chernogolovka, Moscow Region, Russian Federation", 
          "id": "http://www.grid.ac/institutes/grid.4886.2", 
          "name": [
            "Institute of Chemical Physics in Chernogolovka, Russian Academy of Sciences, 142432, Chernogolovka, Moscow Region, Russian Federation"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Filipenko", 
        "givenName": "O. S.", 
        "id": "sg:person.013100520031.61", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.013100520031.61"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Institute of Chemical Physics in Chernogolovka, Russian Academy of Sciences, 142432, Chernogolovka, Moscow Region, Russian Federation", 
          "id": "http://www.grid.ac/institutes/grid.4886.2", 
          "name": [
            "Institute of Chemical Physics in Chernogolovka, Russian Academy of Sciences, 142432, Chernogolovka, Moscow Region, Russian Federation"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Utenyshev", 
        "givenName": "A. N.", 
        "id": "sg:person.015236213545.72", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.015236213545.72"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "ERS 158 CNRS, Mediterranean University at Luminy, Case 901, 13288, Cedex 9, France", 
          "id": "http://www.grid.ac/institutes/None", 
          "name": [
            "ERS 158 CNRS, Mediterranean University at Luminy, Case 901, 13288, Cedex 9, France"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Harie", 
        "givenName": "G.", 
        "id": "sg:person.016572054763.13", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.016572054763.13"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "ERS 158 CNRS, Mediterranean University at Luminy, Case 901, 13288, Cedex 9, France", 
          "id": "http://www.grid.ac/institutes/None", 
          "name": [
            "ERS 158 CNRS, Mediterranean University at Luminy, Case 901, 13288, Cedex 9, France"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Lokshin", 
        "givenName": "V.", 
        "id": "sg:person.01371710372.03", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01371710372.03"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "ERS 158 CNRS, Mediterranean University at Luminy, Case 901, 13288, Cedex 9, France", 
          "id": "http://www.grid.ac/institutes/None", 
          "name": [
            "ERS 158 CNRS, Mediterranean University at Luminy, Case 901, 13288, Cedex 9, France"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Samat", 
        "givenName": "A.", 
        "id": "sg:person.07653444232.27", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.07653444232.27"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "ERS 158 CNRS, Mediterranean University at Luminy, Case 901, 13288, Cedex 9, France", 
          "id": "http://www.grid.ac/institutes/None", 
          "name": [
            "ERS 158 CNRS, Mediterranean University at Luminy, Case 901, 13288, Cedex 9, France"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Guglielmetti", 
        "givenName": "R.", 
        "id": "sg:person.013726244175.79", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.013726244175.79"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "ERS 158 CNRS, Mediterranean University at Luminy, Case 901, 13288, Cedex 9, France", 
          "id": "http://www.grid.ac/institutes/None", 
          "name": [
            "ERS 158 CNRS, Mediterranean University at Luminy, Case 901, 13288, Cedex 9, France"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Pepe", 
        "givenName": "G.", 
        "id": "sg:person.0775565202.71", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.0775565202.71"
        ], 
        "type": "Person"
      }
    ], 
    "datePublished": "1998-06", 
    "datePublishedReg": "1998-06-01", 
    "description": "Three 2,2-diaryl-substituted pyridoannelated [2H]-chromenes have been studied by X-ray diffraction analysis. Bonding of the benzene rings through bridges of different nature and with different length affects substantially the orientation of the benzene rings, steric interactions at the C center, the conformation of the molecule, and the C\u2212O bond length. A correlation between the photocolorability of chromenes under study and the orientation of the benzene rings with respect to the C\u2212O bond, which provides different prerequisites to stabilization of the C(1)-centered, cation formed upon cleavage of the C\u2212O bond, was established. The effect of the orientation of the benzene rings on the dark reaction of ring closure was found.", 
    "genre": "article", 
    "id": "sg:pub.10.1007/bf02503478", 
    "isAccessibleForFree": false, 
    "isPartOf": [
      {
        "id": "sg:journal.1022309", 
        "issn": [
          "1066-5285", 
          "1573-9171"
        ], 
        "name": "Russian Chemical Bulletin", 
        "publisher": "Springer Nature", 
        "type": "Periodical"
      }, 
      {
        "issueNumber": "6", 
        "type": "PublicationIssue"
      }, 
      {
        "type": "PublicationVolume", 
        "volumeNumber": "47"
      }
    ], 
    "keywords": [
      "benzene ring", 
      "X-ray diffraction analysis", 
      "photochemical properties", 
      "bond lengths", 
      "phenyl group", 
      "steric interactions", 
      "diffraction analysis", 
      "type of linkage", 
      "ring closure", 
      "chromenes", 
      "dark reaction", 
      "C centers", 
      "bonds", 
      "ring", 
      "different nature", 
      "photocolorability", 
      "cations", 
      "bonding", 
      "molecules", 
      "conformation", 
      "reaction", 
      "cleavage", 
      "properties", 
      "structure", 
      "orientation", 
      "stabilization", 
      "bridge", 
      "interaction", 
      "linkage", 
      "nature", 
      "effect", 
      "different prerequisites", 
      "group", 
      "length", 
      "analysis", 
      "center", 
      "respect", 
      "prerequisite", 
      "types", 
      "study", 
      "correlation", 
      "closure", 
      "affect"
    ], 
    "name": "Effect of the type of linkage between phenyl groups on the structure and photochemical properties of 2,2-diaryl-substituted pyridoannelated [2H]-chromenes", 
    "pagination": "1098-1104", 
    "productId": [
      {
        "name": "dimensions_id", 
        "type": "PropertyValue", 
        "value": [
          "pub.1043555079"
        ]
      }, 
      {
        "name": "doi", 
        "type": "PropertyValue", 
        "value": [
          "10.1007/bf02503478"
        ]
      }
    ], 
    "sameAs": [
      "https://doi.org/10.1007/bf02503478", 
      "https://app.dimensions.ai/details/publication/pub.1043555079"
    ], 
    "sdDataset": "articles", 
    "sdDatePublished": "2022-11-24T20:48", 
    "sdLicense": "https://scigraph.springernature.com/explorer/license/", 
    "sdPublisher": {
      "name": "Springer Nature - SN SciGraph project", 
      "type": "Organization"
    }, 
    "sdSource": "s3://com-springernature-scigraph/baseset/20221124/entities/gbq_results/article/article_279.jsonl", 
    "type": "ScholarlyArticle", 
    "url": "https://doi.org/10.1007/bf02503478"
  }
]
 

Download the RDF metadata as:  json-ld nt turtle xml License info

HOW TO GET THIS DATA PROGRAMMATICALLY:

JSON-LD is a popular format for linked data which is fully compatible with JSON.

curl -H 'Accept: application/ld+json' 'https://scigraph.springernature.com/pub.10.1007/bf02503478'

N-Triples is a line-based linked data format ideal for batch operations.

curl -H 'Accept: application/n-triples' 'https://scigraph.springernature.com/pub.10.1007/bf02503478'

Turtle is a human-readable linked data format.

curl -H 'Accept: text/turtle' 'https://scigraph.springernature.com/pub.10.1007/bf02503478'

RDF/XML is a standard XML format for linked data.

curl -H 'Accept: application/rdf+xml' 'https://scigraph.springernature.com/pub.10.1007/bf02503478'


 

This table displays all metadata directly associated to this object as RDF triples.

159 TRIPLES      20 PREDICATES      68 URIs      60 LITERALS      6 BLANK NODES

Subject Predicate Object
1 sg:pub.10.1007/bf02503478 schema:about anzsrc-for:03
2 anzsrc-for:0306
3 schema:author Nd981225e908e43d5950075ae544195e5
4 schema:datePublished 1998-06
5 schema:datePublishedReg 1998-06-01
6 schema:description Three 2,2-diaryl-substituted pyridoannelated [2H]-chromenes have been studied by X-ray diffraction analysis. Bonding of the benzene rings through bridges of different nature and with different length affects substantially the orientation of the benzene rings, steric interactions at the C center, the conformation of the molecule, and the C−O bond length. A correlation between the photocolorability of chromenes under study and the orientation of the benzene rings with respect to the C−O bond, which provides different prerequisites to stabilization of the C(1)-centered, cation formed upon cleavage of the C−O bond, was established. The effect of the orientation of the benzene rings on the dark reaction of ring closure was found.
7 schema:genre article
8 schema:isAccessibleForFree false
9 schema:isPartOf N1af33f24db564d12bbff94de666727bd
10 N561412ad19ce4c9bb77f17f6852e1f0b
11 sg:journal.1022309
12 schema:keywords C centers
13 X-ray diffraction analysis
14 affect
15 analysis
16 benzene ring
17 bond lengths
18 bonding
19 bonds
20 bridge
21 cations
22 center
23 chromenes
24 cleavage
25 closure
26 conformation
27 correlation
28 dark reaction
29 different nature
30 different prerequisites
31 diffraction analysis
32 effect
33 group
34 interaction
35 length
36 linkage
37 molecules
38 nature
39 orientation
40 phenyl group
41 photochemical properties
42 photocolorability
43 prerequisite
44 properties
45 reaction
46 respect
47 ring
48 ring closure
49 stabilization
50 steric interactions
51 structure
52 study
53 type of linkage
54 types
55 schema:name Effect of the type of linkage between phenyl groups on the structure and photochemical properties of 2,2-diaryl-substituted pyridoannelated [2H]-chromenes
56 schema:pagination 1098-1104
57 schema:productId N8ad54aa90f3144c6ab10f94ebc7d6e52
58 Nde641897a31447afaf92b298d9be7ffa
59 schema:sameAs https://app.dimensions.ai/details/publication/pub.1043555079
60 https://doi.org/10.1007/bf02503478
61 schema:sdDatePublished 2022-11-24T20:48
62 schema:sdLicense https://scigraph.springernature.com/explorer/license/
63 schema:sdPublisher Nc5588035b78d40c595031732aa4be3da
64 schema:url https://doi.org/10.1007/bf02503478
65 sgo:license sg:explorer/license/
66 sgo:sdDataset articles
67 rdf:type schema:ScholarlyArticle
68 N15376f29cdf34b32a9d5ccdcf355a3cd rdf:first sg:person.012555612421.75
69 rdf:rest N7a33d140aa3c4166a62eb6787bea8545
70 N1af33f24db564d12bbff94de666727bd schema:volumeNumber 47
71 rdf:type schema:PublicationVolume
72 N23a16f4ef8444bd394234cb4308261a7 rdf:first sg:person.015236213545.72
73 rdf:rest Nac844dc67e9f46b2b87fbdb7396b611d
74 N561412ad19ce4c9bb77f17f6852e1f0b schema:issueNumber 6
75 rdf:type schema:PublicationIssue
76 N6b7df2cdc0064ea29b697afeeb150f06 rdf:first sg:person.01371710372.03
77 rdf:rest Nea8f5a92702a492bbdae01ce9c8da238
78 N7a33d140aa3c4166a62eb6787bea8545 rdf:first sg:person.013100520031.61
79 rdf:rest N23a16f4ef8444bd394234cb4308261a7
80 N8ad54aa90f3144c6ab10f94ebc7d6e52 schema:name doi
81 schema:value 10.1007/bf02503478
82 rdf:type schema:PropertyValue
83 N98c108c6e9f04e728a0aa6c7a581fda6 rdf:first sg:person.013726244175.79
84 rdf:rest Ne3289b95ba3a4ad5892f415f7bce4dc2
85 Nac844dc67e9f46b2b87fbdb7396b611d rdf:first sg:person.016572054763.13
86 rdf:rest N6b7df2cdc0064ea29b697afeeb150f06
87 Nc5588035b78d40c595031732aa4be3da schema:name Springer Nature - SN SciGraph project
88 rdf:type schema:Organization
89 Nd981225e908e43d5950075ae544195e5 rdf:first sg:person.013232115673.09
90 rdf:rest N15376f29cdf34b32a9d5ccdcf355a3cd
91 Nde641897a31447afaf92b298d9be7ffa schema:name dimensions_id
92 schema:value pub.1043555079
93 rdf:type schema:PropertyValue
94 Ne3289b95ba3a4ad5892f415f7bce4dc2 rdf:first sg:person.0775565202.71
95 rdf:rest rdf:nil
96 Nea8f5a92702a492bbdae01ce9c8da238 rdf:first sg:person.07653444232.27
97 rdf:rest N98c108c6e9f04e728a0aa6c7a581fda6
98 anzsrc-for:03 schema:inDefinedTermSet anzsrc-for:
99 schema:name Chemical Sciences
100 rdf:type schema:DefinedTerm
101 anzsrc-for:0306 schema:inDefinedTermSet anzsrc-for:
102 schema:name Physical Chemistry (incl. Structural)
103 rdf:type schema:DefinedTerm
104 sg:journal.1022309 schema:issn 1066-5285
105 1573-9171
106 schema:name Russian Chemical Bulletin
107 schema:publisher Springer Nature
108 rdf:type schema:Periodical
109 sg:person.012555612421.75 schema:affiliation grid-institutes:grid.4886.2
110 schema:familyName Chuev
111 schema:givenName I. I.
112 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.012555612421.75
113 rdf:type schema:Person
114 sg:person.013100520031.61 schema:affiliation grid-institutes:grid.4886.2
115 schema:familyName Filipenko
116 schema:givenName O. S.
117 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.013100520031.61
118 rdf:type schema:Person
119 sg:person.013232115673.09 schema:affiliation grid-institutes:grid.4886.2
120 schema:familyName Aldoshin
121 schema:givenName S. M.
122 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.013232115673.09
123 rdf:type schema:Person
124 sg:person.01371710372.03 schema:affiliation grid-institutes:None
125 schema:familyName Lokshin
126 schema:givenName V.
127 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01371710372.03
128 rdf:type schema:Person
129 sg:person.013726244175.79 schema:affiliation grid-institutes:None
130 schema:familyName Guglielmetti
131 schema:givenName R.
132 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.013726244175.79
133 rdf:type schema:Person
134 sg:person.015236213545.72 schema:affiliation grid-institutes:grid.4886.2
135 schema:familyName Utenyshev
136 schema:givenName A. N.
137 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.015236213545.72
138 rdf:type schema:Person
139 sg:person.016572054763.13 schema:affiliation grid-institutes:None
140 schema:familyName Harie
141 schema:givenName G.
142 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.016572054763.13
143 rdf:type schema:Person
144 sg:person.07653444232.27 schema:affiliation grid-institutes:None
145 schema:familyName Samat
146 schema:givenName A.
147 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.07653444232.27
148 rdf:type schema:Person
149 sg:person.0775565202.71 schema:affiliation grid-institutes:None
150 schema:familyName Pepe
151 schema:givenName G.
152 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.0775565202.71
153 rdf:type schema:Person
154 grid-institutes:None schema:alternateName ERS 158 CNRS, Mediterranean University at Luminy, Case 901, 13288, Cedex 9, France
155 schema:name ERS 158 CNRS, Mediterranean University at Luminy, Case 901, 13288, Cedex 9, France
156 rdf:type schema:Organization
157 grid-institutes:grid.4886.2 schema:alternateName Institute of Chemical Physics in Chernogolovka, Russian Academy of Sciences, 142432, Chernogolovka, Moscow Region, Russian Federation
158 schema:name Institute of Chemical Physics in Chernogolovka, Russian Academy of Sciences, 142432, Chernogolovka, Moscow Region, Russian Federation
159 rdf:type schema:Organization
 




Preview window. Press ESC to close (or click here)


...