Mechanism of the primary stages of decomposition of aliphatic nitro- and fluoronitronitramines View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

1998-02

AUTHORS

B. L. Korsounskii, V. G. Matveev, L. D. Nazina, G. M. Nazin

ABSTRACT

The primary stage of the decomposition of compounds RN(NO2)CH2C(NO2)2X is the homolytic cleavage of the C−NO2 bond, at X=NO2 and N−NO2 bond at X=F. The inductive effect of substituents decreases the dissociation energies of the C−N and N−N bonds by 1–2 kcal mol−1. Kinetic effects caused by the spatial interaction of groups and by stepwise decomposition of polyfunctional compounds are described. More... »

PAGES

253-258

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/bf02498944

DOI

http://dx.doi.org/10.1007/bf02498944

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1030183653


Indexing Status Check whether this publication has been indexed by Scopus and Web Of Science using the SN Indexing Status Tool
Incoming Citations Browse incoming citations for this publication using opencitations.net

JSON-LD is the canonical representation for SciGraph data.

TIP: You can open this SciGraph record using an external JSON-LD service: JSON-LD Playground Google SDTT

[
  {
    "@context": "https://springernature.github.io/scigraph/jsonld/sgcontext.json", 
    "about": [
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/03", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Chemical Sciences", 
        "type": "DefinedTerm"
      }, 
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/0302", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Inorganic Chemistry", 
        "type": "DefinedTerm"
      }
    ], 
    "author": [
      {
        "affiliation": {
          "alternateName": "Institute of Chemical Physics in Chernogolovka, Russian Academy of Sciences, 142432, Chernogolovka, Moscow Region, Russian Federation", 
          "id": "http://www.grid.ac/institutes/grid.4886.2", 
          "name": [
            "Institute of Chemical Physics in Chernogolovka, Russian Academy of Sciences, 142432, Chernogolovka, Moscow Region, Russian Federation"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Korsounskii", 
        "givenName": "B. L.", 
        "id": "sg:person.07610506721.24", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.07610506721.24"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Institute of Chemical Physics in Chernogolovka, Russian Academy of Sciences, 142432, Chernogolovka, Moscow Region, Russian Federation", 
          "id": "http://www.grid.ac/institutes/grid.4886.2", 
          "name": [
            "Institute of Chemical Physics in Chernogolovka, Russian Academy of Sciences, 142432, Chernogolovka, Moscow Region, Russian Federation"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Matveev", 
        "givenName": "V. G.", 
        "id": "sg:person.012605012602.81", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.012605012602.81"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Institute of Chemical Physics in Chernogolovka, Russian Academy of Sciences, 142432, Chernogolovka, Moscow Region, Russian Federation", 
          "id": "http://www.grid.ac/institutes/grid.4886.2", 
          "name": [
            "Institute of Chemical Physics in Chernogolovka, Russian Academy of Sciences, 142432, Chernogolovka, Moscow Region, Russian Federation"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Nazina", 
        "givenName": "L. D.", 
        "id": "sg:person.015420540067.37", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.015420540067.37"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Institute of Chemical Physics in Chernogolovka, Russian Academy of Sciences, 142432, Chernogolovka, Moscow Region, Russian Federation", 
          "id": "http://www.grid.ac/institutes/grid.4886.2", 
          "name": [
            "Institute of Chemical Physics in Chernogolovka, Russian Academy of Sciences, 142432, Chernogolovka, Moscow Region, Russian Federation"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Nazin", 
        "givenName": "G. M.", 
        "id": "sg:person.012160215350.16", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.012160215350.16"
        ], 
        "type": "Person"
      }
    ], 
    "datePublished": "1998-02", 
    "datePublishedReg": "1998-02-01", 
    "description": "The primary stage of the decomposition of compounds RN(NO2)CH2C(NO2)2X is the homolytic cleavage of the C\u2212NO2 bond, at X=NO2 and N\u2212NO2 bond at X=F. The inductive effect of substituents decreases the dissociation energies of the C\u2212N and N\u2212N bonds by 1\u20132 kcal mol\u22121. Kinetic effects caused by the spatial interaction of groups and by stepwise decomposition of polyfunctional compounds are described.", 
    "genre": "article", 
    "id": "sg:pub.10.1007/bf02498944", 
    "isAccessibleForFree": false, 
    "isPartOf": [
      {
        "id": "sg:journal.1022309", 
        "issn": [
          "1066-5285", 
          "1573-9171"
        ], 
        "name": "Russian Chemical Bulletin", 
        "publisher": "Springer Nature", 
        "type": "Periodical"
      }, 
      {
        "issueNumber": "2", 
        "type": "PublicationIssue"
      }, 
      {
        "type": "PublicationVolume", 
        "volumeNumber": "47"
      }
    ], 
    "keywords": [
      "decomposition of compounds", 
      "aliphatic nitro", 
      "polyfunctional compounds", 
      "homolytic cleavage", 
      "dissociation energies", 
      "stepwise decomposition", 
      "bonds", 
      "inductive effect", 
      "compounds", 
      "kinetic effects", 
      "decomposition", 
      "substituents", 
      "nitro", 
      "NO2", 
      "cleavage", 
      "primary stage", 
      "energy", 
      "interaction", 
      "effect", 
      "mechanism", 
      "group", 
      "stage", 
      "spatial interactions"
    ], 
    "name": "Mechanism of the primary stages of decomposition of aliphatic nitro- and fluoronitronitramines", 
    "pagination": "253-258", 
    "productId": [
      {
        "name": "dimensions_id", 
        "type": "PropertyValue", 
        "value": [
          "pub.1030183653"
        ]
      }, 
      {
        "name": "doi", 
        "type": "PropertyValue", 
        "value": [
          "10.1007/bf02498944"
        ]
      }
    ], 
    "sameAs": [
      "https://doi.org/10.1007/bf02498944", 
      "https://app.dimensions.ai/details/publication/pub.1030183653"
    ], 
    "sdDataset": "articles", 
    "sdDatePublished": "2022-12-01T06:21", 
    "sdLicense": "https://scigraph.springernature.com/explorer/license/", 
    "sdPublisher": {
      "name": "Springer Nature - SN SciGraph project", 
      "type": "Organization"
    }, 
    "sdSource": "s3://com-springernature-scigraph/baseset/20221201/entities/gbq_results/article/article_296.jsonl", 
    "type": "ScholarlyArticle", 
    "url": "https://doi.org/10.1007/bf02498944"
  }
]
 

Download the RDF metadata as:  json-ld nt turtle xml License info

HOW TO GET THIS DATA PROGRAMMATICALLY:

JSON-LD is a popular format for linked data which is fully compatible with JSON.

curl -H 'Accept: application/ld+json' 'https://scigraph.springernature.com/pub.10.1007/bf02498944'

N-Triples is a line-based linked data format ideal for batch operations.

curl -H 'Accept: application/n-triples' 'https://scigraph.springernature.com/pub.10.1007/bf02498944'

Turtle is a human-readable linked data format.

curl -H 'Accept: text/turtle' 'https://scigraph.springernature.com/pub.10.1007/bf02498944'

RDF/XML is a standard XML format for linked data.

curl -H 'Accept: application/rdf+xml' 'https://scigraph.springernature.com/pub.10.1007/bf02498944'


 

This table displays all metadata directly associated to this object as RDF triples.

101 TRIPLES      20 PREDICATES      48 URIs      40 LITERALS      6 BLANK NODES

Subject Predicate Object
1 sg:pub.10.1007/bf02498944 schema:about anzsrc-for:03
2 anzsrc-for:0302
3 schema:author N4d3c147a76dc4b5a9465c73f0ec851eb
4 schema:datePublished 1998-02
5 schema:datePublishedReg 1998-02-01
6 schema:description The primary stage of the decomposition of compounds RN(NO2)CH2C(NO2)2X is the homolytic cleavage of the C−NO2 bond, at X=NO2 and N−NO2 bond at X=F. The inductive effect of substituents decreases the dissociation energies of the C−N and N−N bonds by 1–2 kcal mol−1. Kinetic effects caused by the spatial interaction of groups and by stepwise decomposition of polyfunctional compounds are described.
7 schema:genre article
8 schema:isAccessibleForFree false
9 schema:isPartOf N5b65df3de22b46d392e1fdf89eb666e1
10 N86cffb34e88649b4a811f038c54f075e
11 sg:journal.1022309
12 schema:keywords NO2
13 aliphatic nitro
14 bonds
15 cleavage
16 compounds
17 decomposition
18 decomposition of compounds
19 dissociation energies
20 effect
21 energy
22 group
23 homolytic cleavage
24 inductive effect
25 interaction
26 kinetic effects
27 mechanism
28 nitro
29 polyfunctional compounds
30 primary stage
31 spatial interactions
32 stage
33 stepwise decomposition
34 substituents
35 schema:name Mechanism of the primary stages of decomposition of aliphatic nitro- and fluoronitronitramines
36 schema:pagination 253-258
37 schema:productId N201ee2cb7a60453c89bf93603b0f4a19
38 Ne13b22c2b9a64810b7c953e1fed958ce
39 schema:sameAs https://app.dimensions.ai/details/publication/pub.1030183653
40 https://doi.org/10.1007/bf02498944
41 schema:sdDatePublished 2022-12-01T06:21
42 schema:sdLicense https://scigraph.springernature.com/explorer/license/
43 schema:sdPublisher N3cb4599e59d24029ba3490c4760c38b1
44 schema:url https://doi.org/10.1007/bf02498944
45 sgo:license sg:explorer/license/
46 sgo:sdDataset articles
47 rdf:type schema:ScholarlyArticle
48 N201ee2cb7a60453c89bf93603b0f4a19 schema:name doi
49 schema:value 10.1007/bf02498944
50 rdf:type schema:PropertyValue
51 N3cb4599e59d24029ba3490c4760c38b1 schema:name Springer Nature - SN SciGraph project
52 rdf:type schema:Organization
53 N4d3c147a76dc4b5a9465c73f0ec851eb rdf:first sg:person.07610506721.24
54 rdf:rest Nbb67fd64020c44b68ee085ff8d73d618
55 N5b65df3de22b46d392e1fdf89eb666e1 schema:volumeNumber 47
56 rdf:type schema:PublicationVolume
57 N6c52c0cb2c5644b3a2a805ccb41a94ac rdf:first sg:person.012160215350.16
58 rdf:rest rdf:nil
59 N86cffb34e88649b4a811f038c54f075e schema:issueNumber 2
60 rdf:type schema:PublicationIssue
61 Nbb67fd64020c44b68ee085ff8d73d618 rdf:first sg:person.012605012602.81
62 rdf:rest Ncf6225dcc8c345e79d33042179640cdd
63 Ncf6225dcc8c345e79d33042179640cdd rdf:first sg:person.015420540067.37
64 rdf:rest N6c52c0cb2c5644b3a2a805ccb41a94ac
65 Ne13b22c2b9a64810b7c953e1fed958ce schema:name dimensions_id
66 schema:value pub.1030183653
67 rdf:type schema:PropertyValue
68 anzsrc-for:03 schema:inDefinedTermSet anzsrc-for:
69 schema:name Chemical Sciences
70 rdf:type schema:DefinedTerm
71 anzsrc-for:0302 schema:inDefinedTermSet anzsrc-for:
72 schema:name Inorganic Chemistry
73 rdf:type schema:DefinedTerm
74 sg:journal.1022309 schema:issn 1066-5285
75 1573-9171
76 schema:name Russian Chemical Bulletin
77 schema:publisher Springer Nature
78 rdf:type schema:Periodical
79 sg:person.012160215350.16 schema:affiliation grid-institutes:grid.4886.2
80 schema:familyName Nazin
81 schema:givenName G. M.
82 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.012160215350.16
83 rdf:type schema:Person
84 sg:person.012605012602.81 schema:affiliation grid-institutes:grid.4886.2
85 schema:familyName Matveev
86 schema:givenName V. G.
87 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.012605012602.81
88 rdf:type schema:Person
89 sg:person.015420540067.37 schema:affiliation grid-institutes:grid.4886.2
90 schema:familyName Nazina
91 schema:givenName L. D.
92 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.015420540067.37
93 rdf:type schema:Person
94 sg:person.07610506721.24 schema:affiliation grid-institutes:grid.4886.2
95 schema:familyName Korsounskii
96 schema:givenName B. L.
97 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.07610506721.24
98 rdf:type schema:Person
99 grid-institutes:grid.4886.2 schema:alternateName Institute of Chemical Physics in Chernogolovka, Russian Academy of Sciences, 142432, Chernogolovka, Moscow Region, Russian Federation
100 schema:name Institute of Chemical Physics in Chernogolovka, Russian Academy of Sciences, 142432, Chernogolovka, Moscow Region, Russian Federation
101 rdf:type schema:Organization
 




Preview window. Press ESC to close (or click here)


...