Reactivity of primary and secondary alcohols in nucleophilic addition to a triple bond: the vinylation of butane-1,3-diol View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

1999-12

AUTHORS

L. A. Oparina, L. N. Parshina, I. A. Ushakov, S. I. Shaikhudinova, B. A. Trofimov

ABSTRACT

Acetylene adds to butane-1,3-diol in the presence of KOH to give, along with the corresponding divinyl ether and 2,4-dimethyl-1,3-dioxane, 4-vinyloxybutan-2-ol and its structural isomer 3-vinyloxybutan-1-ol, the ratio between the latter two products, (5–8)∶1, depending on the reaction conditions.

PAGES

2347-2349

Journal

TITLE

Russian Chemical Bulletin

ISSUE

12

VOLUME

48

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/bf02498288

DOI

http://dx.doi.org/10.1007/bf02498288

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1002195668


Indexing Status Check whether this publication has been indexed by Scopus and Web Of Science using the SN Indexing Status Tool
Incoming Citations Browse incoming citations for this publication using opencitations.net

JSON-LD is the canonical representation for SciGraph data.

TIP: You can open this SciGraph record using an external JSON-LD service: JSON-LD Playground Google SDTT

[
  {
    "@context": "https://springernature.github.io/scigraph/jsonld/sgcontext.json", 
    "author": [
      {
        "affiliation": {
          "alternateName": "Siberian Branch of the Russian Academy of Sciences", 
          "id": "https://www.grid.ac/institutes/grid.415877.8", 
          "name": [
            "Irkutsk Institute of Chemistry, Siberian Branch of the Russian Academy of Sciences, 1 ul. Favorskogo, 664033, Irkutsk, Russian Federation"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Oparina", 
        "givenName": "L. A.", 
        "id": "sg:person.07713051317.88", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.07713051317.88"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Siberian Branch of the Russian Academy of Sciences", 
          "id": "https://www.grid.ac/institutes/grid.415877.8", 
          "name": [
            "Irkutsk Institute of Chemistry, Siberian Branch of the Russian Academy of Sciences, 1 ul. Favorskogo, 664033, Irkutsk, Russian Federation"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Parshina", 
        "givenName": "L. N.", 
        "id": "sg:person.012637640307.64", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.012637640307.64"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Siberian Branch of the Russian Academy of Sciences", 
          "id": "https://www.grid.ac/institutes/grid.415877.8", 
          "name": [
            "Irkutsk Institute of Chemistry, Siberian Branch of the Russian Academy of Sciences, 1 ul. Favorskogo, 664033, Irkutsk, Russian Federation"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Ushakov", 
        "givenName": "I. A.", 
        "id": "sg:person.012070450113.34", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.012070450113.34"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Siberian Branch of the Russian Academy of Sciences", 
          "id": "https://www.grid.ac/institutes/grid.415877.8", 
          "name": [
            "Irkutsk Institute of Chemistry, Siberian Branch of the Russian Academy of Sciences, 1 ul. Favorskogo, 664033, Irkutsk, Russian Federation"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Shaikhudinova", 
        "givenName": "S. I.", 
        "id": "sg:person.016126551161.91", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.016126551161.91"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Siberian Branch of the Russian Academy of Sciences", 
          "id": "https://www.grid.ac/institutes/grid.415877.8", 
          "name": [
            "Irkutsk Institute of Chemistry, Siberian Branch of the Russian Academy of Sciences, 1 ul. Favorskogo, 664033, Irkutsk, Russian Federation"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Trofimov", 
        "givenName": "B. A.", 
        "id": "sg:person.01333112300.52", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01333112300.52"
        ], 
        "type": "Person"
      }
    ], 
    "datePublished": "1999-12", 
    "datePublishedReg": "1999-12-01", 
    "description": "Acetylene adds to butane-1,3-diol in the presence of KOH to give, along with the corresponding divinyl ether and 2,4-dimethyl-1,3-dioxane, 4-vinyloxybutan-2-ol and its structural isomer 3-vinyloxybutan-1-ol, the ratio between the latter two products, (5\u20138)\u22361, depending on the reaction conditions.", 
    "genre": "non_research_article", 
    "id": "sg:pub.10.1007/bf02498288", 
    "inLanguage": [
      "en"
    ], 
    "isAccessibleForFree": false, 
    "isPartOf": [
      {
        "id": "sg:journal.1022309", 
        "issn": [
          "1066-5285", 
          "1573-9171"
        ], 
        "name": "Russian Chemical Bulletin", 
        "type": "Periodical"
      }, 
      {
        "issueNumber": "12", 
        "type": "PublicationIssue"
      }, 
      {
        "type": "PublicationVolume", 
        "volumeNumber": "48"
      }
    ], 
    "name": "Reactivity of primary and secondary alcohols in nucleophilic addition to a triple bond: the vinylation of butane-1,3-diol", 
    "pagination": "2347-2349", 
    "productId": [
      {
        "name": "readcube_id", 
        "type": "PropertyValue", 
        "value": [
          "0a747e9ee598de9038a6d96feefac24d61c562376231f219e5cbf75fc878e1be"
        ]
      }, 
      {
        "name": "doi", 
        "type": "PropertyValue", 
        "value": [
          "10.1007/bf02498288"
        ]
      }, 
      {
        "name": "dimensions_id", 
        "type": "PropertyValue", 
        "value": [
          "pub.1002195668"
        ]
      }
    ], 
    "sameAs": [
      "https://doi.org/10.1007/bf02498288", 
      "https://app.dimensions.ai/details/publication/pub.1002195668"
    ], 
    "sdDataset": "articles", 
    "sdDatePublished": "2019-04-10T18:24", 
    "sdLicense": "https://scigraph.springernature.com/explorer/license/", 
    "sdPublisher": {
      "name": "Springer Nature - SN SciGraph project", 
      "type": "Organization"
    }, 
    "sdSource": "s3://com-uberresearch-data-dimensions-target-20181106-alternative/cleanup/v134/2549eaecd7973599484d7c17b260dba0a4ecb94b/merge/v9/a6c9fde33151104705d4d7ff012ea9563521a3ce/jats-lookup/v90/0000000001_0000000264/records_8675_00000529.jsonl", 
    "type": "ScholarlyArticle", 
    "url": "http://link.springer.com/10.1007%2FBF02498288"
  }
]
 

Download the RDF metadata as:  json-ld nt turtle xml License info

HOW TO GET THIS DATA PROGRAMMATICALLY:

JSON-LD is a popular format for linked data which is fully compatible with JSON.

curl -H 'Accept: application/ld+json' 'https://scigraph.springernature.com/pub.10.1007/bf02498288'

N-Triples is a line-based linked data format ideal for batch operations.

curl -H 'Accept: application/n-triples' 'https://scigraph.springernature.com/pub.10.1007/bf02498288'

Turtle is a human-readable linked data format.

curl -H 'Accept: text/turtle' 'https://scigraph.springernature.com/pub.10.1007/bf02498288'

RDF/XML is a standard XML format for linked data.

curl -H 'Accept: application/rdf+xml' 'https://scigraph.springernature.com/pub.10.1007/bf02498288'


 

This table displays all metadata directly associated to this object as RDF triples.

81 TRIPLES      19 PREDICATES      25 URIs      19 LITERALS      7 BLANK NODES

Subject Predicate Object
1 sg:pub.10.1007/bf02498288 schema:author N1f3cd0f2a463467faf69ec0b5c692bb7
2 schema:datePublished 1999-12
3 schema:datePublishedReg 1999-12-01
4 schema:description Acetylene adds to butane-1,3-diol in the presence of KOH to give, along with the corresponding divinyl ether and 2,4-dimethyl-1,3-dioxane, 4-vinyloxybutan-2-ol and its structural isomer 3-vinyloxybutan-1-ol, the ratio between the latter two products, (5–8)∶1, depending on the reaction conditions.
5 schema:genre non_research_article
6 schema:inLanguage en
7 schema:isAccessibleForFree false
8 schema:isPartOf N5ce42fc45f8a49dbbd1ec3c391d84549
9 Ndd822226a5f049b49366d9ef756aa9ab
10 sg:journal.1022309
11 schema:name Reactivity of primary and secondary alcohols in nucleophilic addition to a triple bond: the vinylation of butane-1,3-diol
12 schema:pagination 2347-2349
13 schema:productId N038a8d83430e437ebcbb55eceaba3a0c
14 N9f977761f58945d796ea226e73406bfe
15 Nc3c46cb451d24cc9b049a0d944a3553b
16 schema:sameAs https://app.dimensions.ai/details/publication/pub.1002195668
17 https://doi.org/10.1007/bf02498288
18 schema:sdDatePublished 2019-04-10T18:24
19 schema:sdLicense https://scigraph.springernature.com/explorer/license/
20 schema:sdPublisher N949fd07f319c4a37a8630a88f7a676c1
21 schema:url http://link.springer.com/10.1007%2FBF02498288
22 sgo:license sg:explorer/license/
23 sgo:sdDataset articles
24 rdf:type schema:ScholarlyArticle
25 N038a8d83430e437ebcbb55eceaba3a0c schema:name readcube_id
26 schema:value 0a747e9ee598de9038a6d96feefac24d61c562376231f219e5cbf75fc878e1be
27 rdf:type schema:PropertyValue
28 N11d690e148c048e0b87fd115fda21b5f rdf:first sg:person.01333112300.52
29 rdf:rest rdf:nil
30 N1f3cd0f2a463467faf69ec0b5c692bb7 rdf:first sg:person.07713051317.88
31 rdf:rest N22d0b927c8ac4e9e85002f867de07af1
32 N22d0b927c8ac4e9e85002f867de07af1 rdf:first sg:person.012637640307.64
33 rdf:rest Nc3e57fa7038848e8ac7f91d06c7974c5
34 N5ce42fc45f8a49dbbd1ec3c391d84549 schema:issueNumber 12
35 rdf:type schema:PublicationIssue
36 N949fd07f319c4a37a8630a88f7a676c1 schema:name Springer Nature - SN SciGraph project
37 rdf:type schema:Organization
38 N9f977761f58945d796ea226e73406bfe schema:name doi
39 schema:value 10.1007/bf02498288
40 rdf:type schema:PropertyValue
41 Nc3c46cb451d24cc9b049a0d944a3553b schema:name dimensions_id
42 schema:value pub.1002195668
43 rdf:type schema:PropertyValue
44 Nc3e57fa7038848e8ac7f91d06c7974c5 rdf:first sg:person.012070450113.34
45 rdf:rest Nf4b7f0bb86bc4a3ca6b0cd02da0c7d56
46 Ndd822226a5f049b49366d9ef756aa9ab schema:volumeNumber 48
47 rdf:type schema:PublicationVolume
48 Nf4b7f0bb86bc4a3ca6b0cd02da0c7d56 rdf:first sg:person.016126551161.91
49 rdf:rest N11d690e148c048e0b87fd115fda21b5f
50 sg:journal.1022309 schema:issn 1066-5285
51 1573-9171
52 schema:name Russian Chemical Bulletin
53 rdf:type schema:Periodical
54 sg:person.012070450113.34 schema:affiliation https://www.grid.ac/institutes/grid.415877.8
55 schema:familyName Ushakov
56 schema:givenName I. A.
57 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.012070450113.34
58 rdf:type schema:Person
59 sg:person.012637640307.64 schema:affiliation https://www.grid.ac/institutes/grid.415877.8
60 schema:familyName Parshina
61 schema:givenName L. N.
62 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.012637640307.64
63 rdf:type schema:Person
64 sg:person.01333112300.52 schema:affiliation https://www.grid.ac/institutes/grid.415877.8
65 schema:familyName Trofimov
66 schema:givenName B. A.
67 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01333112300.52
68 rdf:type schema:Person
69 sg:person.016126551161.91 schema:affiliation https://www.grid.ac/institutes/grid.415877.8
70 schema:familyName Shaikhudinova
71 schema:givenName S. I.
72 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.016126551161.91
73 rdf:type schema:Person
74 sg:person.07713051317.88 schema:affiliation https://www.grid.ac/institutes/grid.415877.8
75 schema:familyName Oparina
76 schema:givenName L. A.
77 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.07713051317.88
78 rdf:type schema:Person
79 https://www.grid.ac/institutes/grid.415877.8 schema:alternateName Siberian Branch of the Russian Academy of Sciences
80 schema:name Irkutsk Institute of Chemistry, Siberian Branch of the Russian Academy of Sciences, 1 ul. Favorskogo, 664033, Irkutsk, Russian Federation
81 rdf:type schema:Organization
 




Preview window. Press ESC to close (or click here)


...