Unusual rearrangement of the Ru3(μ-CO)2(CO)6{μ3-η1:η1:η4:η4-C4Ph2(CH=CHPh)2} complex containing an open triruthenium framework to the Ru3-triangular cluster Ru3(CO)8{μ3-η1:η1:η4:η2-C4Ph2(CH=CHPh)2}. Reactions of Ru3(CO)8{μ3-η1:η1:η4:η2-C4Ph2(CH=CHPh)2} with ... View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

1998-05

AUTHORS

A. A. Koridze, V. I. Zdanovich, V. Yu. Lagunova, M. G. Ezernitskaya, P. V. Petrovskii, F. M. Dolgushin, A. I. Yanovsky

ABSTRACT

Complex Ru3(μ-CO)2(CO)6{μ3-η1:η1:η4:η4-C4Ph2(CH=CHPh)2} containing an open triruthenium framework undergoes rearrangement to the Ru3-triangular Ru3(CO)8{μ3-η1:η1:η4:η2-C4Ph2(CH=CHPh)2) cluster when heated in refluxing hexane. Reactions of the latter complex with PPh3, P(OPri)3, and CO were studied. The structure of one of the reaction products, the Ru3(CO)8(PPh3{μ3-η1:η1:η4-C4Ph2(CH=CHPh)2} cluster, was established by X-ray structural analysis.

PAGES

988-994

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/bf02498173

DOI

http://dx.doi.org/10.1007/bf02498173

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1045603325


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