Interaction of the trimethylsilyl cation with molecules of aliphatic nitro compounds in the gas phase View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

1997-06

AUTHORS

V. I. Kadentsev, N. G. Kolotyrkina, A. A. Stomakhin, O. S. Chizhov, S. A. Shevelev

ABSTRACT

Interaction of mononitroalkanes with the trimethylsilyl cation in the gas phase under chemical ionization (CI) conditions results in the formation of [M+SiMe3]+ ions, which are more stable than the corresponding protonated molecular ions. In the case of 2-nitro-2-methylpropane and 2-nitropentane, fragmentation of the [M+SiMe3]+ ions occurs with the formation of C4H9+ and C5H11+ carbocations, respectively. In the case of 1,1-dinitroethane and 1-halo-1,1-dinitroethane, fragmentation of the [M+SiMe3]+ ions occurs with splitting off of a NO2. radical or an XNO2 molecule (X=H, F, or Cl). More... »

PAGES

1184-1185

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/bf02496228

DOI

http://dx.doi.org/10.1007/bf02496228

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1046742347


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