Interaction of carbonylferrate- and hydridocarbonylferrate anions with Brønstad and Lewis acids View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

1997-05

AUTHORS

Yu. A. Belousov

ABSTRACT

Interaction of carbonylferrate anions Fen(CO)m−1/2− and hydridocarbonylferrate anions HFen(CO)m−1/− (wheren=1−4;m=5, 9, 12, 14, respectively) with Brønstad and Lewis acids HX (X=AcO, CF3CO2, HSO4) and RX (R=Alk, Ac, Bn, Bz; X=Cl, Br) is a radical-chain process, occuringvia a one-electron redox-initiation stage, including preliminary activating complex formation. A common approach to the description of the processes of reduction and carbonylation of different organic compounds was suggested. It is based upon the exchange reactions and the interconversions within the coordination spheres of 17-electron coordinatively unsaturated iron carbonyl radical anions, Fen(CO)m−1/−. More... »

PAGES

1010-1017

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/bf02496136

DOI

http://dx.doi.org/10.1007/bf02496136

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1033397312


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