Synthesis and reactivity of metal-containing monomers View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

1999-06

AUTHORS

S. I. Pomogailo, I. I. Chuev, G. I. Dzhardimalieva, A. V. Yarmolenko, V. D. Makhaev, S. M. Aldoshin, A. D. Pomogailo

ABSTRACT

The reaction of Rh6(CO)15MeCN with allyldiphenylphosphine under mild conditions afforded the cluster-containing complex [Rh6(CO)14(μ,η2-PPh2Ch2CH=CH2)]. Its molecular structure was characterized. The resulting complex is an octahedral Rh cluster with ten terminal and four μ3-bridging CO ligands. The average Rh−Rh distance is 2.762(2) Å. The unsaturated ligand is additionally coordinated to the metal center (Rh(4)–C(232), 2.37(1) Å; and Rh(4)–C(233), 2.32(2) Å) to form a π-bond. More... »

PAGES

1174-1177

References to SciGraph publications

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/bf02496024

DOI

http://dx.doi.org/10.1007/bf02496024

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1013993773


Indexing Status Check whether this publication has been indexed by Scopus and Web Of Science using the SN Indexing Status Tool
Incoming Citations Browse incoming citations for this publication using opencitations.net

JSON-LD is the canonical representation for SciGraph data.

TIP: You can open this SciGraph record using an external JSON-LD service: JSON-LD Playground Google SDTT

[
  {
    "@context": "https://springernature.github.io/scigraph/jsonld/sgcontext.json", 
    "about": [
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/03", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Chemical Sciences", 
        "type": "DefinedTerm"
      }, 
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/0302", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Inorganic Chemistry", 
        "type": "DefinedTerm"
      }, 
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/0306", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Physical Chemistry (incl. Structural)", 
        "type": "DefinedTerm"
      }
    ], 
    "author": [
      {
        "affiliation": {
          "alternateName": "Institute of Problems of Chemical Physics, Russian Academy of Sciences, 1424432, Chernogolovka, Moscow Region, Russian Federation", 
          "id": "http://www.grid.ac/institutes/grid.418949.9", 
          "name": [
            "Institute of Problems of Chemical Physics, Russian Academy of Sciences, 1424432, Chernogolovka, Moscow Region, Russian Federation"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Pomogailo", 
        "givenName": "S. I.", 
        "id": "sg:person.014461773777.30", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.014461773777.30"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Institute of Problems of Chemical Physics, Russian Academy of Sciences, 1424432, Chernogolovka, Moscow Region, Russian Federation", 
          "id": "http://www.grid.ac/institutes/grid.418949.9", 
          "name": [
            "Institute of Problems of Chemical Physics, Russian Academy of Sciences, 1424432, Chernogolovka, Moscow Region, Russian Federation"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Chuev", 
        "givenName": "I. I.", 
        "id": "sg:person.012555612421.75", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.012555612421.75"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Institute of Problems of Chemical Physics, Russian Academy of Sciences, 1424432, Chernogolovka, Moscow Region, Russian Federation", 
          "id": "http://www.grid.ac/institutes/grid.418949.9", 
          "name": [
            "Institute of Problems of Chemical Physics, Russian Academy of Sciences, 1424432, Chernogolovka, Moscow Region, Russian Federation"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Dzhardimalieva", 
        "givenName": "G. I.", 
        "id": "sg:person.010475400761.64", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.010475400761.64"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Institute of Problems of Chemical Physics, Russian Academy of Sciences, 1424432, Chernogolovka, Moscow Region, Russian Federation", 
          "id": "http://www.grid.ac/institutes/grid.418949.9", 
          "name": [
            "Institute of Problems of Chemical Physics, Russian Academy of Sciences, 1424432, Chernogolovka, Moscow Region, Russian Federation"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Yarmolenko", 
        "givenName": "A. V.", 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Institute of Problems of Chemical Physics, Russian Academy of Sciences, 1424432, Chernogolovka, Moscow Region, Russian Federation", 
          "id": "http://www.grid.ac/institutes/grid.418949.9", 
          "name": [
            "Institute of Problems of Chemical Physics, Russian Academy of Sciences, 1424432, Chernogolovka, Moscow Region, Russian Federation"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Makhaev", 
        "givenName": "V. D.", 
        "id": "sg:person.015345565771.45", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.015345565771.45"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Institute of Problems of Chemical Physics, Russian Academy of Sciences, 1424432, Chernogolovka, Moscow Region, Russian Federation", 
          "id": "http://www.grid.ac/institutes/grid.418949.9", 
          "name": [
            "Institute of Problems of Chemical Physics, Russian Academy of Sciences, 1424432, Chernogolovka, Moscow Region, Russian Federation"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Aldoshin", 
        "givenName": "S. M.", 
        "id": "sg:person.013232115673.09", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.013232115673.09"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Institute of Problems of Chemical Physics, Russian Academy of Sciences, 1424432, Chernogolovka, Moscow Region, Russian Federation", 
          "id": "http://www.grid.ac/institutes/grid.418949.9", 
          "name": [
            "Institute of Problems of Chemical Physics, Russian Academy of Sciences, 1424432, Chernogolovka, Moscow Region, Russian Federation"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Pomogailo", 
        "givenName": "A. D.", 
        "id": "sg:person.016403071561.84", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.016403071561.84"
        ], 
        "type": "Person"
      }
    ], 
    "citation": [
      {
        "id": "sg:pub.10.1007/978-94-009-5267-6", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1053190191", 
          "https://doi.org/10.1007/978-94-009-5267-6"
        ], 
        "type": "CreativeWork"
      }
    ], 
    "datePublished": "1999-06", 
    "datePublishedReg": "1999-06-01", 
    "description": "The reaction of Rh6(CO)15MeCN with allyldiphenylphosphine under mild conditions afforded the cluster-containing complex [Rh6(CO)14(\u03bc,\u03b72-PPh2Ch2CH=CH2)]. Its molecular structure was characterized. The resulting complex is an octahedral Rh cluster with ten terminal and four \u03bc3-bridging CO ligands. The average Rh\u2212Rh distance is 2.762(2) \u00c5. The unsaturated ligand is additionally coordinated to the metal center (Rh(4)\u2013C(232), 2.37(1) \u00c5; and Rh(4)\u2013C(233), 2.32(2) \u00c5) to form a \u03c0-bond.", 
    "genre": "article", 
    "id": "sg:pub.10.1007/bf02496024", 
    "inLanguage": "en", 
    "isAccessibleForFree": false, 
    "isPartOf": [
      {
        "id": "sg:journal.1022309", 
        "issn": [
          "1063-5211", 
          "1026-3500"
        ], 
        "name": "Russian Chemical Bulletin", 
        "publisher": "Springer Nature", 
        "type": "Periodical"
      }, 
      {
        "issueNumber": "6", 
        "type": "PublicationIssue"
      }, 
      {
        "type": "PublicationVolume", 
        "volumeNumber": "48"
      }
    ], 
    "keywords": [
      "metal-containing monomers", 
      "unsaturated ligands", 
      "metal center", 
      "CO ligand", 
      "molecular structure", 
      "\u03c0 bonds", 
      "mild conditions", 
      "Rh clusters", 
      "ligands", 
      "complexes", 
      "allyldiphenylphosphine", 
      "\u03bc3", 
      "monomers", 
      "synthesis", 
      "reactivity", 
      "reaction", 
      "structure", 
      "clusters", 
      "conditions", 
      "center", 
      "distance", 
      "terminals"
    ], 
    "name": "Synthesis and reactivity of metal-containing monomers", 
    "pagination": "1174-1177", 
    "productId": [
      {
        "name": "dimensions_id", 
        "type": "PropertyValue", 
        "value": [
          "pub.1013993773"
        ]
      }, 
      {
        "name": "doi", 
        "type": "PropertyValue", 
        "value": [
          "10.1007/bf02496024"
        ]
      }
    ], 
    "sameAs": [
      "https://doi.org/10.1007/bf02496024", 
      "https://app.dimensions.ai/details/publication/pub.1013993773"
    ], 
    "sdDataset": "articles", 
    "sdDatePublished": "2022-05-20T07:21", 
    "sdLicense": "https://scigraph.springernature.com/explorer/license/", 
    "sdPublisher": {
      "name": "Springer Nature - SN SciGraph project", 
      "type": "Organization"
    }, 
    "sdSource": "s3://com-springernature-scigraph/baseset/20220519/entities/gbq_results/article/article_326.jsonl", 
    "type": "ScholarlyArticle", 
    "url": "https://doi.org/10.1007/bf02496024"
  }
]
 

Download the RDF metadata as:  json-ld nt turtle xml License info

HOW TO GET THIS DATA PROGRAMMATICALLY:

JSON-LD is a popular format for linked data which is fully compatible with JSON.

curl -H 'Accept: application/ld+json' 'https://scigraph.springernature.com/pub.10.1007/bf02496024'

N-Triples is a line-based linked data format ideal for batch operations.

curl -H 'Accept: application/n-triples' 'https://scigraph.springernature.com/pub.10.1007/bf02496024'

Turtle is a human-readable linked data format.

curl -H 'Accept: text/turtle' 'https://scigraph.springernature.com/pub.10.1007/bf02496024'

RDF/XML is a standard XML format for linked data.

curl -H 'Accept: application/rdf+xml' 'https://scigraph.springernature.com/pub.10.1007/bf02496024'


 

This table displays all metadata directly associated to this object as RDF triples.

129 TRIPLES      22 PREDICATES      50 URIs      40 LITERALS      6 BLANK NODES

Subject Predicate Object
1 sg:pub.10.1007/bf02496024 schema:about anzsrc-for:03
2 anzsrc-for:0302
3 anzsrc-for:0306
4 schema:author N077be9212c304bc18cc60b18a2076945
5 schema:citation sg:pub.10.1007/978-94-009-5267-6
6 schema:datePublished 1999-06
7 schema:datePublishedReg 1999-06-01
8 schema:description The reaction of Rh6(CO)15MeCN with allyldiphenylphosphine under mild conditions afforded the cluster-containing complex [Rh6(CO)14(μ,η2-PPh2Ch2CH=CH2)]. Its molecular structure was characterized. The resulting complex is an octahedral Rh cluster with ten terminal and four μ3-bridging CO ligands. The average Rh−Rh distance is 2.762(2) Å. The unsaturated ligand is additionally coordinated to the metal center (Rh(4)–C(232), 2.37(1) Å; and Rh(4)–C(233), 2.32(2) Å) to form a π-bond.
9 schema:genre article
10 schema:inLanguage en
11 schema:isAccessibleForFree false
12 schema:isPartOf N4db041004b9341f8b987d8b97e07a920
13 Nab2df64a37574653874396835b919251
14 sg:journal.1022309
15 schema:keywords CO ligand
16 Rh clusters
17 allyldiphenylphosphine
18 center
19 clusters
20 complexes
21 conditions
22 distance
23 ligands
24 metal center
25 metal-containing monomers
26 mild conditions
27 molecular structure
28 monomers
29 reaction
30 reactivity
31 structure
32 synthesis
33 terminals
34 unsaturated ligands
35 μ3
36 π bonds
37 schema:name Synthesis and reactivity of metal-containing monomers
38 schema:pagination 1174-1177
39 schema:productId N634573fde0084877ac88fd3f8656af8c
40 N6df0993872014196a37e71ee9b47079c
41 schema:sameAs https://app.dimensions.ai/details/publication/pub.1013993773
42 https://doi.org/10.1007/bf02496024
43 schema:sdDatePublished 2022-05-20T07:21
44 schema:sdLicense https://scigraph.springernature.com/explorer/license/
45 schema:sdPublisher N6da634490c9a46a3b7b1d7ccb774a59b
46 schema:url https://doi.org/10.1007/bf02496024
47 sgo:license sg:explorer/license/
48 sgo:sdDataset articles
49 rdf:type schema:ScholarlyArticle
50 N02014ae678af4430ae34702fb4231c74 schema:affiliation grid-institutes:grid.418949.9
51 schema:familyName Yarmolenko
52 schema:givenName A. V.
53 rdf:type schema:Person
54 N077be9212c304bc18cc60b18a2076945 rdf:first sg:person.014461773777.30
55 rdf:rest N82c6d3dde475416f86bae907446c35d7
56 N4db041004b9341f8b987d8b97e07a920 schema:issueNumber 6
57 rdf:type schema:PublicationIssue
58 N634573fde0084877ac88fd3f8656af8c schema:name dimensions_id
59 schema:value pub.1013993773
60 rdf:type schema:PropertyValue
61 N6c8d89af90024bce9b1251016bbb9c53 rdf:first sg:person.010475400761.64
62 rdf:rest Ne675ccce3a37477a8d5f4ea12f967110
63 N6da634490c9a46a3b7b1d7ccb774a59b schema:name Springer Nature - SN SciGraph project
64 rdf:type schema:Organization
65 N6df0993872014196a37e71ee9b47079c schema:name doi
66 schema:value 10.1007/bf02496024
67 rdf:type schema:PropertyValue
68 N82c6d3dde475416f86bae907446c35d7 rdf:first sg:person.012555612421.75
69 rdf:rest N6c8d89af90024bce9b1251016bbb9c53
70 N90c03b2717244faf958019afaaec8ce6 rdf:first sg:person.013232115673.09
71 rdf:rest Ne18178ba7bf04818993b9baffed4f48c
72 Nab2df64a37574653874396835b919251 schema:volumeNumber 48
73 rdf:type schema:PublicationVolume
74 Ne18178ba7bf04818993b9baffed4f48c rdf:first sg:person.016403071561.84
75 rdf:rest rdf:nil
76 Ne675ccce3a37477a8d5f4ea12f967110 rdf:first N02014ae678af4430ae34702fb4231c74
77 rdf:rest Ne96a0bc4d71345f8b35a661fa9a708cf
78 Ne96a0bc4d71345f8b35a661fa9a708cf rdf:first sg:person.015345565771.45
79 rdf:rest N90c03b2717244faf958019afaaec8ce6
80 anzsrc-for:03 schema:inDefinedTermSet anzsrc-for:
81 schema:name Chemical Sciences
82 rdf:type schema:DefinedTerm
83 anzsrc-for:0302 schema:inDefinedTermSet anzsrc-for:
84 schema:name Inorganic Chemistry
85 rdf:type schema:DefinedTerm
86 anzsrc-for:0306 schema:inDefinedTermSet anzsrc-for:
87 schema:name Physical Chemistry (incl. Structural)
88 rdf:type schema:DefinedTerm
89 sg:journal.1022309 schema:issn 1026-3500
90 1063-5211
91 schema:name Russian Chemical Bulletin
92 schema:publisher Springer Nature
93 rdf:type schema:Periodical
94 sg:person.010475400761.64 schema:affiliation grid-institutes:grid.418949.9
95 schema:familyName Dzhardimalieva
96 schema:givenName G. I.
97 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.010475400761.64
98 rdf:type schema:Person
99 sg:person.012555612421.75 schema:affiliation grid-institutes:grid.418949.9
100 schema:familyName Chuev
101 schema:givenName I. I.
102 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.012555612421.75
103 rdf:type schema:Person
104 sg:person.013232115673.09 schema:affiliation grid-institutes:grid.418949.9
105 schema:familyName Aldoshin
106 schema:givenName S. M.
107 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.013232115673.09
108 rdf:type schema:Person
109 sg:person.014461773777.30 schema:affiliation grid-institutes:grid.418949.9
110 schema:familyName Pomogailo
111 schema:givenName S. I.
112 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.014461773777.30
113 rdf:type schema:Person
114 sg:person.015345565771.45 schema:affiliation grid-institutes:grid.418949.9
115 schema:familyName Makhaev
116 schema:givenName V. D.
117 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.015345565771.45
118 rdf:type schema:Person
119 sg:person.016403071561.84 schema:affiliation grid-institutes:grid.418949.9
120 schema:familyName Pomogailo
121 schema:givenName A. D.
122 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.016403071561.84
123 rdf:type schema:Person
124 sg:pub.10.1007/978-94-009-5267-6 schema:sameAs https://app.dimensions.ai/details/publication/pub.1053190191
125 https://doi.org/10.1007/978-94-009-5267-6
126 rdf:type schema:CreativeWork
127 grid-institutes:grid.418949.9 schema:alternateName Institute of Problems of Chemical Physics, Russian Academy of Sciences, 1424432, Chernogolovka, Moscow Region, Russian Federation
128 schema:name Institute of Problems of Chemical Physics, Russian Academy of Sciences, 1424432, Chernogolovka, Moscow Region, Russian Federation
129 rdf:type schema:Organization
 




Preview window. Press ESC to close (or click here)


...