Synthesis and reactivity of metal-containing monomers View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

1999-06

AUTHORS

S. I. Pomogailo, I. I. Chuev, G. I. Dzhardimalieva, A. V. Yarmolenko, V. D. Makhaev, S. M. Aldoshin, A. D. Pomogailo

ABSTRACT

The reaction of Rh6(CO)15MeCN with allyldiphenylphosphine under mild conditions afforded the cluster-containing complex [Rh6(CO)14(μ,η2-PPh2Ch2CH=CH2)]. Its molecular structure was characterized. The resulting complex is an octahedral Rh cluster with ten terminal and four μ3-bridging CO ligands. The average Rh−Rh distance is 2.762(2) Å. The unsaturated ligand is additionally coordinated to the metal center (Rh(4)–C(232), 2.37(1) Å; and Rh(4)–C(233), 2.32(2) Å) to form a π-bond. More... »

PAGES

1174-1177

References to SciGraph publications

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/bf02496024

DOI

http://dx.doi.org/10.1007/bf02496024

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1013993773


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