Specific features of the interaction of methyl ethers of methyl (methyl-α-D-galactopyranoside)uronate with trimethylsilyl ions in the gas phase View Full Text


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Article Info

DATE

1997-07

AUTHORS

V. I. Kadentsev, N. G. Kolotyrkina, A. A. Stomakhin, O. S. Chizhov

ABSTRACT

Specific features of the interaction between trimethylsilyl ions and methyl (methyl-α-d-galactopyranoside)uronate and its methyl ethers were revealed. It was shown that a hydrogen atom is generated when the trimethylsilyl ion is located at hydroxyl group. This atom migrates over the methoxy and hydroxyl groups toward the glycoside methoxy group, resulting in the formation of [Me+SiMe3−MeOH]+ ions. More... »

PAGES

1261-1263

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/bf02495924

DOI

http://dx.doi.org/10.1007/bf02495924

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1002123996


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