Synthesis of ferrocenylacetylide derivatives of gold-ruthenium and gold-osmium clusters. Crystal structures of M3(AuPPh3)(C≡CFc)(CO)9 (M=Ru or Os; Fc is ferrocenyl) View Full Text


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Article Info

DATE

2000-07

AUTHORS

A. M. Sheloumov, A. A. Koridze, F. M. Dolgushin, Z. A. Starikova, M. G. Ezernitskaya, P. V. Petrovskii

ABSTRACT

The synthesis and crystal structures of the clusters M3(AuPPh3)(C≡CFc)(CO)9 (M=Ru,3a; or M=Os,3b) are described. Compound3a was synthesized by deprotonation of Ru3H(C≡CFc)(CO)9 under the action of KOH/EtOH followed by treatment of the anionic complex [Ru3(C≡CFc)(CO)9]− with chloro(triphenylphosphine)gold. Compound3b was prepared by the reaction of Os3(CO)10(NCMe)2 with FcC≡CAuPPh3, which was synthesized by the reaction of FcC≡CNa with ClAuPPh3. The pentanuclear cluster Ru4(AuPPh3)(C≡CFc)(CO)12 (4a), which was prepared by the reaction of3a with Ru3(CO)12, was characterized by spectral methods. More... »

PAGES

1292-1296

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/bf02495777

DOI

http://dx.doi.org/10.1007/bf02495777

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1023503009


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