Formation and structure of diruthenium complexes Ru2(CO)6−n(PPh3)n{μ-C(CH=CHPh)C(Ph)C(CH=CHPh)C(Ph)} (n=1, 2) View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

1998-09

AUTHORS

V. I. Zdanovich, V. Yu. Lagunova, F. M. Dolgushin, A. I. Yanovsky, M. G. Ezernitskaya, P. V. Petrovskii, A. A. Koridze

ABSTRACT

Ruthenium carbonyl triphenylphosphine complexes Ru2(CO)6−n(PPh3)n{μ-C(CH=CHPh)C(Ph)C(CH=CHPh)C(Ph)} (n=1, 2) were obtained by the reaction of complex Ru2(CO)6{μ-C(CH=CHPh)C(Ph)C(CH=CHPh)C(Ph)} containing the ruthenacyclopentadiene moiety with PPh3 in refluxing toluene. The complexes were characterized by IR and by1H,13C, and31P NMR spectroscopy, and by X-ray analysis. The monophosphine derivative is identical to the complex formed by fragmentation of the Ru3(CO)8(PPh3){μ-C(CH=CHPh)C(Ph)C(CH=CHPh)C(Ph)} cluster and contains the PPh3 ligand at the ruthenium atom of the ruthenacyclopentadiene moiety. More... »

PAGES

1789-1796

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/bf02495707

DOI

http://dx.doi.org/10.1007/bf02495707

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1007311138


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