Synthesis and reactivity of metal-containing monomers View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

1998-08

AUTHORS

A. T. Shuvaev, A. S. Rozenberg, G. I. Dzhardimalieva, N. P. Ivleva, V. G. Vlasenko, T. I. Nedoseikina, T. A. Lyubeznova, I. E. Uflyand, A. D. Pomogailo

ABSTRACT

Thermal transformations of FeIII maleate, [Fe3O(OOCCH=CHCOOH)6]OH·3H2O (1), in an autogenerated atmosphere and the change in the short-range surrounding of Fe atoms during thermolysis were studied. The thermal transformations of1 are accompanied by the following processes: dehydration with simultaneous rearrangement of the ligand environment and formation of maleic acid, and polymerization of the rearranged monomer and its decarboxylation at high temperatures. In the initial stage of decarboxylation, the destruction of the metal-carboxylate Fe3O complex occurs followed by the formation of the Fe−Fe bond (r=0.246 nm). The oxidation of the Fe atoms is observed when the thermolysis duration increases. More... »

PAGES

1460-1465

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/bf02495593

DOI

http://dx.doi.org/10.1007/bf02495593

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1025863791


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