The effect of side substituents on rotation hindrance in polyheteroarylenes View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

1998-07

AUTHORS

I. A. Ronova, L. V. Dubrovina, A. Yu. Kovalevskii, C. Hamciuc, M. Bruma

ABSTRACT

Hindered rotation was considered in calculations of the conformational parameters of a series of polyheteroarylenes with bulky side substituents by the Monte-Carlo method. Within the range of experimental errors, the results of calculations for several polyarylates coincide with the values of conformational rigidity, determined from hydrodynamic experimental data. The proposed procedure was used to estimate the rigidities of a number of polymers with bulky side substuents for which experimental determination is difficult. More... »

PAGES

1248-1256

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/bf02495543

DOI

http://dx.doi.org/10.1007/bf02495543

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1002343621


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