Structures of products of the reaction of dimethylsulfonium phenacylide with benzylidenecyanoacetamide View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

1999-07

AUTHORS

A. V. Samet, V. N. Nesterov, A. M. Shestopalov, V. V. Semenov

ABSTRACT

Benzylidenecyanoacetamide reacted with dimethylsulfonium phenacylide to form 2-benzoyl-1-cyano-3-phenylcyclopropanecarboxamide and a product of its intramolecular cyclization,viz., a derivative of 3-azabicyclo[3.2.1]hexan-2-one. The structures of the products were established by X-ray diffraction analysis.

PAGES

1310-1315

References to SciGraph publications

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/bf02495295

DOI

http://dx.doi.org/10.1007/bf02495295

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1018741082


Indexing Status Check whether this publication has been indexed by Scopus and Web Of Science using the SN Indexing Status Tool
Incoming Citations Browse incoming citations for this publication using opencitations.net

JSON-LD is the canonical representation for SciGraph data.

TIP: You can open this SciGraph record using an external JSON-LD service: JSON-LD Playground Google SDTT

[
  {
    "@context": "https://springernature.github.io/scigraph/jsonld/sgcontext.json", 
    "about": [
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/03", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Chemical Sciences", 
        "type": "DefinedTerm"
      }
    ], 
    "author": [
      {
        "affiliation": {
          "alternateName": "N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 47 Leninsky prosp., 117913, Moscow, Russian Federation", 
          "id": "http://www.grid.ac/institutes/grid.439283.7", 
          "name": [
            "N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 47 Leninsky prosp., 117913, Moscow, Russian Federation"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Samet", 
        "givenName": "A. V.", 
        "id": "sg:person.014127240534.29", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.014127240534.29"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, X-ray Crystallographic Center, 28 ul. Vavilova, 117813, Moscow, Russian Federation", 
          "id": "http://www.grid.ac/institutes/grid.431939.5", 
          "name": [
            "A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, X-ray Crystallographic Center, 28 ul. Vavilova, 117813, Moscow, Russian Federation"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Nesterov", 
        "givenName": "V. N.", 
        "id": "sg:person.0777374631.34", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.0777374631.34"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 47 Leninsky prosp., 117913, Moscow, Russian Federation", 
          "id": "http://www.grid.ac/institutes/grid.439283.7", 
          "name": [
            "N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 47 Leninsky prosp., 117913, Moscow, Russian Federation"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Shestopalov", 
        "givenName": "A. M.", 
        "id": "sg:person.0577505645.55", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.0577505645.55"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 47 Leninsky prosp., 117913, Moscow, Russian Federation", 
          "id": "http://www.grid.ac/institutes/grid.439283.7", 
          "name": [
            "N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 47 Leninsky prosp., 117913, Moscow, Russian Federation"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Semenov", 
        "givenName": "V. V.", 
        "id": "sg:person.0716636167.19", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.0716636167.19"
        ], 
        "type": "Person"
      }
    ], 
    "citation": [
      {
        "id": "sg:pub.10.1007/bf02495519", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1020928882", 
          "https://doi.org/10.1007/bf02495519"
        ], 
        "type": "CreativeWork"
      }
    ], 
    "datePublished": "1999-07", 
    "datePublishedReg": "1999-07-01", 
    "description": "Benzylidenecyanoacetamide reacted with dimethylsulfonium phenacylide to form 2-benzoyl-1-cyano-3-phenylcyclopropanecarboxamide and a product of its intramolecular cyclization,viz., a derivative of 3-azabicyclo[3.2.1]hexan-2-one. The structures of the products were established by X-ray diffraction analysis.", 
    "genre": "article", 
    "id": "sg:pub.10.1007/bf02495295", 
    "inLanguage": "en", 
    "isAccessibleForFree": false, 
    "isPartOf": [
      {
        "id": "sg:journal.1022309", 
        "issn": [
          "1063-5211", 
          "1026-3500"
        ], 
        "name": "Russian Chemical Bulletin", 
        "publisher": "Springer Nature", 
        "type": "Periodical"
      }, 
      {
        "issueNumber": "7", 
        "type": "PublicationIssue"
      }, 
      {
        "type": "PublicationVolume", 
        "volumeNumber": "48"
      }
    ], 
    "keywords": [
      "dimethylsulfonium phenacylide", 
      "ray diffraction analysis", 
      "structure of products", 
      "intramolecular cyclization", 
      "diffraction analysis", 
      "phenacylide", 
      "products", 
      "cyclization", 
      "structure", 
      "derivatives", 
      "reaction", 
      "viz", 
      "analysis", 
      "Benzylidenecyanoacetamide"
    ], 
    "name": "Structures of products of the reaction of dimethylsulfonium phenacylide with benzylidenecyanoacetamide", 
    "pagination": "1310-1315", 
    "productId": [
      {
        "name": "dimensions_id", 
        "type": "PropertyValue", 
        "value": [
          "pub.1018741082"
        ]
      }, 
      {
        "name": "doi", 
        "type": "PropertyValue", 
        "value": [
          "10.1007/bf02495295"
        ]
      }
    ], 
    "sameAs": [
      "https://doi.org/10.1007/bf02495295", 
      "https://app.dimensions.ai/details/publication/pub.1018741082"
    ], 
    "sdDataset": "articles", 
    "sdDatePublished": "2021-11-01T18:04", 
    "sdLicense": "https://scigraph.springernature.com/explorer/license/", 
    "sdPublisher": {
      "name": "Springer Nature - SN SciGraph project", 
      "type": "Organization"
    }, 
    "sdSource": "s3://com-springernature-scigraph/baseset/20211101/entities/gbq_results/article/article_333.jsonl", 
    "type": "ScholarlyArticle", 
    "url": "https://doi.org/10.1007/bf02495295"
  }
]
 

Download the RDF metadata as:  json-ld nt turtle xml License info

HOW TO GET THIS DATA PROGRAMMATICALLY:

JSON-LD is a popular format for linked data which is fully compatible with JSON.

curl -H 'Accept: application/ld+json' 'https://scigraph.springernature.com/pub.10.1007/bf02495295'

N-Triples is a line-based linked data format ideal for batch operations.

curl -H 'Accept: application/n-triples' 'https://scigraph.springernature.com/pub.10.1007/bf02495295'

Turtle is a human-readable linked data format.

curl -H 'Accept: text/turtle' 'https://scigraph.springernature.com/pub.10.1007/bf02495295'

RDF/XML is a standard XML format for linked data.

curl -H 'Accept: application/rdf+xml' 'https://scigraph.springernature.com/pub.10.1007/bf02495295'


 

This table displays all metadata directly associated to this object as RDF triples.

96 TRIPLES      22 PREDICATES      40 URIs      32 LITERALS      6 BLANK NODES

Subject Predicate Object
1 sg:pub.10.1007/bf02495295 schema:about anzsrc-for:03
2 schema:author N925ffa5000fb4be49de1bfcdb400c7a4
3 schema:citation sg:pub.10.1007/bf02495519
4 schema:datePublished 1999-07
5 schema:datePublishedReg 1999-07-01
6 schema:description Benzylidenecyanoacetamide reacted with dimethylsulfonium phenacylide to form 2-benzoyl-1-cyano-3-phenylcyclopropanecarboxamide and a product of its intramolecular cyclization,viz., a derivative of 3-azabicyclo[3.2.1]hexan-2-one. The structures of the products were established by X-ray diffraction analysis.
7 schema:genre article
8 schema:inLanguage en
9 schema:isAccessibleForFree false
10 schema:isPartOf N28dfb74b71ce47259613324ab8688df5
11 Nc519621e6e85430fa01938058a6aca82
12 sg:journal.1022309
13 schema:keywords Benzylidenecyanoacetamide
14 analysis
15 cyclization
16 derivatives
17 diffraction analysis
18 dimethylsulfonium phenacylide
19 intramolecular cyclization
20 phenacylide
21 products
22 ray diffraction analysis
23 reaction
24 structure
25 structure of products
26 viz
27 schema:name Structures of products of the reaction of dimethylsulfonium phenacylide with benzylidenecyanoacetamide
28 schema:pagination 1310-1315
29 schema:productId N958e8466671d438b8a53990c5d3ffbe5
30 Nd88ebebf2dac4aa9859ed7a55a4e9c18
31 schema:sameAs https://app.dimensions.ai/details/publication/pub.1018741082
32 https://doi.org/10.1007/bf02495295
33 schema:sdDatePublished 2021-11-01T18:04
34 schema:sdLicense https://scigraph.springernature.com/explorer/license/
35 schema:sdPublisher Nc77b820bc30c4596bdd4ad2c0d6c55c4
36 schema:url https://doi.org/10.1007/bf02495295
37 sgo:license sg:explorer/license/
38 sgo:sdDataset articles
39 rdf:type schema:ScholarlyArticle
40 N28dfb74b71ce47259613324ab8688df5 schema:volumeNumber 48
41 rdf:type schema:PublicationVolume
42 N3b14ad3013b044d490d5eab106586a5c rdf:first sg:person.0577505645.55
43 rdf:rest Ne296ac2d47534887b04e9376adf6546b
44 N84a91f36c7b6496fbcdee5ab11ca12b6 rdf:first sg:person.0777374631.34
45 rdf:rest N3b14ad3013b044d490d5eab106586a5c
46 N925ffa5000fb4be49de1bfcdb400c7a4 rdf:first sg:person.014127240534.29
47 rdf:rest N84a91f36c7b6496fbcdee5ab11ca12b6
48 N958e8466671d438b8a53990c5d3ffbe5 schema:name doi
49 schema:value 10.1007/bf02495295
50 rdf:type schema:PropertyValue
51 Nc519621e6e85430fa01938058a6aca82 schema:issueNumber 7
52 rdf:type schema:PublicationIssue
53 Nc77b820bc30c4596bdd4ad2c0d6c55c4 schema:name Springer Nature - SN SciGraph project
54 rdf:type schema:Organization
55 Nd88ebebf2dac4aa9859ed7a55a4e9c18 schema:name dimensions_id
56 schema:value pub.1018741082
57 rdf:type schema:PropertyValue
58 Ne296ac2d47534887b04e9376adf6546b rdf:first sg:person.0716636167.19
59 rdf:rest rdf:nil
60 anzsrc-for:03 schema:inDefinedTermSet anzsrc-for:
61 schema:name Chemical Sciences
62 rdf:type schema:DefinedTerm
63 sg:journal.1022309 schema:issn 1026-3500
64 1063-5211
65 schema:name Russian Chemical Bulletin
66 schema:publisher Springer Nature
67 rdf:type schema:Periodical
68 sg:person.014127240534.29 schema:affiliation grid-institutes:grid.439283.7
69 schema:familyName Samet
70 schema:givenName A. V.
71 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.014127240534.29
72 rdf:type schema:Person
73 sg:person.0577505645.55 schema:affiliation grid-institutes:grid.439283.7
74 schema:familyName Shestopalov
75 schema:givenName A. M.
76 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.0577505645.55
77 rdf:type schema:Person
78 sg:person.0716636167.19 schema:affiliation grid-institutes:grid.439283.7
79 schema:familyName Semenov
80 schema:givenName V. V.
81 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.0716636167.19
82 rdf:type schema:Person
83 sg:person.0777374631.34 schema:affiliation grid-institutes:grid.431939.5
84 schema:familyName Nesterov
85 schema:givenName V. N.
86 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.0777374631.34
87 rdf:type schema:Person
88 sg:pub.10.1007/bf02495519 schema:sameAs https://app.dimensions.ai/details/publication/pub.1020928882
89 https://doi.org/10.1007/bf02495519
90 rdf:type schema:CreativeWork
91 grid-institutes:grid.431939.5 schema:alternateName A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, X-ray Crystallographic Center, 28 ul. Vavilova, 117813, Moscow, Russian Federation
92 schema:name A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, X-ray Crystallographic Center, 28 ul. Vavilova, 117813, Moscow, Russian Federation
93 rdf:type schema:Organization
94 grid-institutes:grid.439283.7 schema:alternateName N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 47 Leninsky prosp., 117913, Moscow, Russian Federation
95 schema:name N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 47 Leninsky prosp., 117913, Moscow, Russian Federation
96 rdf:type schema:Organization
 




Preview window. Press ESC to close (or click here)


...