Preparation and reactivity of metal-containing monomers 53. Synthesis and stability of a cluster monomer (μ-H)Os3(μ-OCNMe2)(CO)9PPh2CH2CH=CH2 in solution View Full Text


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Article Info

DATE

2000-08

AUTHORS

V. A. Ershova, A. V. Golovin, L. A. Sheludyakova, P. P. Semyannikov, S. I. Pomogailo, A. D. Pomogailo

ABSTRACT

The stability of the complex (μ-H)Os3(μ-OCNMe2)(CO)9PPh2CH2CH=CH2 (1), which contains a free unsaturated functional group in the terminal ligand PPh2CH2CH=CH2, with respect to isomerization, chelation of the ligand, and other transformations in solutions was examined. No transformations of complex1 were observed in the course of synthesis from (μ-H)Os3(μ-OCNMe2)(CO)9NMe3 or upon heating in solution. Complex1 as well as complexes (μ-H)Os3(μ-OCNMe2)(CO)9PHPh2 and (μ-H)Os3(μ-OCNMe2)(CO)9PPh3, which were formed as admixtures, were isolated in the solid state and identified by1H,1H-{31P}, and1H-{1H} NMR, IR, and Raman spectroscopy and mass spectrometry. More... »

PAGES

1448-1453

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/bf02495095

DOI

http://dx.doi.org/10.1007/bf02495095

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1007583181


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