Reaction of alkyne cluster Os3(μ-CO)(CO)9(μ3-η1:η1:η2-Me3SiC2Me) with HC≡CCOOMe. Molecular and crystal structures of Os3(CO)9{μ3-η1:η1:η2:η2-C(SiMe3)C(Me)C(COOMe)CH× and Os3(CO)8{μ3-η1:η1:η4:η1-C(SiMe3)C(Me)C(H)C(COOMe)CH× complexes View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

1999-09

AUTHORS

A. M. Sheloumov, A. A. Koridze, M. G. Ezernitskaya, P. V. Petrovskii, O. L. Tok, Z. A. Starikova, F. M. Dolgushin, A. I. Yanovsky

ABSTRACT

Reaction of the cluster Os3(μ-CO)(CO)9(μ3-η1:η1:η2-Me3SiC2Me) with HC≡CCOOMe in benzene at 70 °C results in Os3(CO)9{μ3-η1:η1:η2:η2-C(SiMe3)C(Me)C(COOMe)CH× (5), Os3(CO)9{μ3-η1:η1:η2:η2-C(SiMe3)C(Me)C(H)C(COOMe)CH× (6), Os3(CO)9{μ-η1:η1:η4-C(SiMe3)C(Me)C(H)C(COOMe)CH× (7), and Os3(CO)δ{μ3-η1:η1:η4:η1-C(SiMe3)C(Me)C(H)C(COOMe)× complexes (8), containing an osmacyclopentadiene moiety. Complexes5–8 were characterized by1H NMR and IR spectroscopy. The structure of clusters5 and8 was confirmed by X-ray analysis. Complex7 is formed from cluster5 as a result of a new intramolecular rearrangement and complex8 is obtained by decarbonylation of compound6. Complex8 adds PPh3 to give Os3(CO)δ(PPh3){μ-η1:η1:η4-C(SiMe3)C(Me)C(H)C(COOMe)×. More... »

PAGES

1767-1773

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/bf02494827

DOI

http://dx.doi.org/10.1007/bf02494827

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1016176671


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