Synthesis and reactivity of metal-containing monomers View Full Text


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Article Info

DATE

1999-09

AUTHORS

E. I. Klabunovskii, E. I. Karpeiskaya, G. I. Dzhardimalieva, N. D. Golubeva, A. D. Pomogailo

ABSTRACT

Optically active mixed alkoxy orthotitanates with general formula Ti(OR1)2(OR2)(OR3) (R1=Et, Bun; R2=CH2CH2OCOC(Me)=CH2; R3=menthyl, CH(Me)CH2Me, CH(Ph)CH(NHMe)Me, CH(C9H6N)(C9H14N)) were obtained for the first time by transesterification. The TiIV monomers synthesized were characterized by elemental analysis, ozonolysis, and1H and13C NMR and IR spectroscopy. Polymer products with optical activity were obtained by liquid phase radical copolymerization of TiIV-containing monomers. More... »

PAGES

1717-1721

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/bf02494819

DOI

http://dx.doi.org/10.1007/bf02494819

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1043451613


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