Ontology type: schema:ScholarlyArticle
2000-05
AUTHORSB. L. Korsounskii, V. V. Nedel'ko, N. V. Chukanov, T. S. Larikova, F. Volk
ABSTRACTThermal decomposition of hexanitrohexaazaisowurtzitane (HNIW) in the solid state and in solution was studied by thermogravimetry, manometry, optical microscopy, and IR spectroscopy. The kinetics of the reaction in the solid state is described by the first-order equation of autocatalysis. The rate constants and activation parameters of HNIW thermal decomposition in the solid state and solution were determined. The content of N2 amounts to approximately half of the gaseous products of HNIW thermolysis. The thermolysis of HNIW and its burning are accompanied by the formation of a condensed residue. During these processes, five of six nitro groups of the HNIW molecule are removed, and one NO2 group remains in the residue, which contains amino groups and no C−H bonds. More... »
PAGES812-818
http://scigraph.springernature.com/pub.10.1007/bf02494701
DOIhttp://dx.doi.org/10.1007/bf02494701
DIMENSIONShttps://app.dimensions.ai/details/publication/pub.1001894966
JSON-LD is the canonical representation for SciGraph data.
TIP: You can open this SciGraph record using an external JSON-LD service: JSON-LD Playground Google SDTT
[
{
"@context": "https://springernature.github.io/scigraph/jsonld/sgcontext.json",
"about": [
{
"id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/03",
"inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/",
"name": "Chemical Sciences",
"type": "DefinedTerm"
}
],
"author": [
{
"affiliation": {
"alternateName": "Institute of Problems of Chemical Physics, Russian Academy of Sciences, 142432, Chernogolovka, Moscow Region, Russian Federation",
"id": "http://www.grid.ac/institutes/grid.418949.9",
"name": [
"Institute of Problems of Chemical Physics, Russian Academy of Sciences, 142432, Chernogolovka, Moscow Region, Russian Federation"
],
"type": "Organization"
},
"familyName": "Korsounskii",
"givenName": "B. L.",
"id": "sg:person.07610506721.24",
"sameAs": [
"https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.07610506721.24"
],
"type": "Person"
},
{
"affiliation": {
"alternateName": "Institute of Problems of Chemical Physics, Russian Academy of Sciences, 142432, Chernogolovka, Moscow Region, Russian Federation",
"id": "http://www.grid.ac/institutes/grid.418949.9",
"name": [
"Institute of Problems of Chemical Physics, Russian Academy of Sciences, 142432, Chernogolovka, Moscow Region, Russian Federation"
],
"type": "Organization"
},
"familyName": "Nedel'ko",
"givenName": "V. V.",
"id": "sg:person.015344224713.16",
"sameAs": [
"https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.015344224713.16"
],
"type": "Person"
},
{
"affiliation": {
"alternateName": "Institute of Problems of Chemical Physics, Russian Academy of Sciences, 142432, Chernogolovka, Moscow Region, Russian Federation",
"id": "http://www.grid.ac/institutes/grid.418949.9",
"name": [
"Institute of Problems of Chemical Physics, Russian Academy of Sciences, 142432, Chernogolovka, Moscow Region, Russian Federation"
],
"type": "Organization"
},
"familyName": "Chukanov",
"givenName": "N. V.",
"id": "sg:person.0677073451.16",
"sameAs": [
"https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.0677073451.16"
],
"type": "Person"
},
{
"affiliation": {
"alternateName": "Institute of Problems of Chemical Physics, Russian Academy of Sciences, 142432, Chernogolovka, Moscow Region, Russian Federation",
"id": "http://www.grid.ac/institutes/grid.418949.9",
"name": [
"Institute of Problems of Chemical Physics, Russian Academy of Sciences, 142432, Chernogolovka, Moscow Region, Russian Federation"
],
"type": "Organization"
},
"familyName": "Larikova",
"givenName": "T. S.",
"id": "sg:person.010350343113.60",
"sameAs": [
"https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.010350343113.60"
],
"type": "Person"
},
{
"affiliation": {
"alternateName": "Fraunhofer Institut f\u00fcr Chemische Technologie, D-76327, Pfinztal-Berghausen, Germany",
"id": "http://www.grid.ac/institutes/None",
"name": [
"Fraunhofer Institut f\u00fcr Chemische Technologie, D-76327, Pfinztal-Berghausen, Germany"
],
"type": "Organization"
},
"familyName": "Volk",
"givenName": "F.",
"id": "sg:person.015605541151.91",
"sameAs": [
"https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.015605541151.91"
],
"type": "Person"
}
],
"datePublished": "2000-05",
"datePublishedReg": "2000-05-01",
"description": "Thermal decomposition of hexanitrohexaazaisowurtzitane (HNIW) in the solid state and in solution was studied by thermogravimetry, manometry, optical microscopy, and IR spectroscopy. The kinetics of the reaction in the solid state is described by the first-order equation of autocatalysis. The rate constants and activation parameters of HNIW thermal decomposition in the solid state and solution were determined. The content of N2 amounts to approximately half of the gaseous products of HNIW thermolysis. The thermolysis of HNIW and its burning are accompanied by the formation of a condensed residue. During these processes, five of six nitro groups of the HNIW molecule are removed, and one NO2 group remains in the residue, which contains amino groups and no C\u2212H bonds.",
"genre": "article",
"id": "sg:pub.10.1007/bf02494701",
"isAccessibleForFree": false,
"isPartOf": [
{
"id": "sg:journal.1022309",
"issn": [
"1063-5211",
"1026-3500"
],
"name": "Russian Chemical Bulletin",
"publisher": "Springer Nature",
"type": "Periodical"
},
{
"issueNumber": "5",
"type": "PublicationIssue"
},
{
"type": "PublicationVolume",
"volumeNumber": "49"
}
],
"keywords": [
"solid state",
"optical microscopy",
"first-order equations",
"state",
"spectroscopy",
"NO2 group",
"thermal decomposition",
"rate constants",
"microscopy",
"IR spectroscopy",
"N2 amount",
"constants",
"hexanitrohexaazaisowurtzitane",
"equations",
"solution",
"decomposition",
"molecules",
"bonds",
"parameters",
"formation",
"burning",
"kinetics",
"gaseous products",
"thermolysis",
"nitro group",
"reaction",
"activation parameters",
"process",
"autocatalysis",
"thermogravimetry",
"amino groups",
"amount",
"content",
"residues",
"products",
"half",
"group",
"manometry"
],
"name": "Kinetics of thermal decomposition of hexanitrohexaazaisowurtzitane",
"pagination": "812-818",
"productId": [
{
"name": "dimensions_id",
"type": "PropertyValue",
"value": [
"pub.1001894966"
]
},
{
"name": "doi",
"type": "PropertyValue",
"value": [
"10.1007/bf02494701"
]
}
],
"sameAs": [
"https://doi.org/10.1007/bf02494701",
"https://app.dimensions.ai/details/publication/pub.1001894966"
],
"sdDataset": "articles",
"sdDatePublished": "2022-08-04T16:53",
"sdLicense": "https://scigraph.springernature.com/explorer/license/",
"sdPublisher": {
"name": "Springer Nature - SN SciGraph project",
"type": "Organization"
},
"sdSource": "s3://com-springernature-scigraph/baseset/20220804/entities/gbq_results/article/article_341.jsonl",
"type": "ScholarlyArticle",
"url": "https://doi.org/10.1007/bf02494701"
}
]Download the RDF metadata as: json-ld nt turtle xml License info
JSON-LD is a popular format for linked data which is fully compatible with JSON.
curl -H 'Accept: application/ld+json' 'https://scigraph.springernature.com/pub.10.1007/bf02494701'
N-Triples is a line-based linked data format ideal for batch operations.
curl -H 'Accept: application/n-triples' 'https://scigraph.springernature.com/pub.10.1007/bf02494701'
Turtle is a human-readable linked data format.
curl -H 'Accept: text/turtle' 'https://scigraph.springernature.com/pub.10.1007/bf02494701'
RDF/XML is a standard XML format for linked data.
curl -H 'Accept: application/rdf+xml' 'https://scigraph.springernature.com/pub.10.1007/bf02494701'
This table displays all metadata directly associated to this object as RDF triples.
122 TRIPLES
20 PREDICATES
62 URIs
55 LITERALS
6 BLANK NODES