Hydroxylation of substituted diatomic phenols and their derivatives View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

1998-10

AUTHORS

V. B. Vol'eva, T. I. Prokofeva, I. S. Belostotskaya, N. L. Komissarova, V. V. Ershov

ABSTRACT

Oxidation of 3,6-di-tert-butylpyrocatechol in protic media is accompanied by the formation of 3,6-di-tert-butyl-2-hydroxy-para-benzoquinone. Hydroxylation of the 3,5-isomer results in dealkylation and isomerization with the formation of 6-tert-butyl-2-hydroxy-para-benzoquinone and the quinone mentioned above, respectively. Their ratio depends on the nature of the solvent. Analogous processes accompany redox transformations of 2,6-di-tert-butylhydroquinone, 2,6-diphenyl-para-benzoquinone, and 2,4,6-tri-tert-butylphenol adsorbed on silica gel. Derivatives of 3,5-substituted pyrocatechols formed under conditions of heterophase oxidation in air are capable of transformations to form nitrogen-containing compounds. More... »

PAGES

1952-1955

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/bf02494504

DOI

http://dx.doi.org/10.1007/bf02494504

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1012756902


Indexing Status Check whether this publication has been indexed by Scopus and Web Of Science using the SN Indexing Status Tool
Incoming Citations Browse incoming citations for this publication using opencitations.net

JSON-LD is the canonical representation for SciGraph data.

TIP: You can open this SciGraph record using an external JSON-LD service: JSON-LD Playground Google SDTT

[
  {
    "@context": "https://springernature.github.io/scigraph/jsonld/sgcontext.json", 
    "about": [
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/03", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Chemical Sciences", 
        "type": "DefinedTerm"
      }, 
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/0306", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Physical Chemistry (incl. Structural)", 
        "type": "DefinedTerm"
      }
    ], 
    "author": [
      {
        "affiliation": {
          "alternateName": "N. M. Emanuel Institute of Biochemical Physics, Russian Academy of Sciences, 4 ul. Kosygina, 117977, Moscow, Russian Federation", 
          "id": "http://www.grid.ac/institutes/grid.4886.2", 
          "name": [
            "N. M. Emanuel Institute of Biochemical Physics, Russian Academy of Sciences, 4 ul. Kosygina, 117977, Moscow, Russian Federation"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Vol'eva", 
        "givenName": "V. B.", 
        "id": "sg:person.014515631207.10", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.014515631207.10"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "N. M. Emanuel Institute of Biochemical Physics, Russian Academy of Sciences, 4 ul. Kosygina, 117977, Moscow, Russian Federation", 
          "id": "http://www.grid.ac/institutes/grid.4886.2", 
          "name": [
            "N. M. Emanuel Institute of Biochemical Physics, Russian Academy of Sciences, 4 ul. Kosygina, 117977, Moscow, Russian Federation"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Prokofeva", 
        "givenName": "T. I.", 
        "id": "sg:person.016162132527.56", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.016162132527.56"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "N. M. Emanuel Institute of Biochemical Physics, Russian Academy of Sciences, 4 ul. Kosygina, 117977, Moscow, Russian Federation", 
          "id": "http://www.grid.ac/institutes/grid.4886.2", 
          "name": [
            "N. M. Emanuel Institute of Biochemical Physics, Russian Academy of Sciences, 4 ul. Kosygina, 117977, Moscow, Russian Federation"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Belostotskaya", 
        "givenName": "I. S.", 
        "id": "sg:person.015523023503.99", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.015523023503.99"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "N. M. Emanuel Institute of Biochemical Physics, Russian Academy of Sciences, 4 ul. Kosygina, 117977, Moscow, Russian Federation", 
          "id": "http://www.grid.ac/institutes/grid.4886.2", 
          "name": [
            "N. M. Emanuel Institute of Biochemical Physics, Russian Academy of Sciences, 4 ul. Kosygina, 117977, Moscow, Russian Federation"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Komissarova", 
        "givenName": "N. L.", 
        "id": "sg:person.016121506364.44", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.016121506364.44"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "N. M. Emanuel Institute of Biochemical Physics, Russian Academy of Sciences, 4 ul. Kosygina, 117977, Moscow, Russian Federation", 
          "id": "http://www.grid.ac/institutes/grid.4886.2", 
          "name": [
            "N. M. Emanuel Institute of Biochemical Physics, Russian Academy of Sciences, 4 ul. Kosygina, 117977, Moscow, Russian Federation"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Ershov", 
        "givenName": "V. V.", 
        "id": "sg:person.010414742241.10", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.010414742241.10"
        ], 
        "type": "Person"
      }
    ], 
    "datePublished": "1998-10", 
    "datePublishedReg": "1998-10-01", 
    "description": "Oxidation of 3,6-di-tert-butylpyrocatechol in protic media is accompanied by the formation of 3,6-di-tert-butyl-2-hydroxy-para-benzoquinone. Hydroxylation of the 3,5-isomer results in dealkylation and isomerization with the formation of 6-tert-butyl-2-hydroxy-para-benzoquinone and the quinone mentioned above, respectively. Their ratio depends on the nature of the solvent. Analogous processes accompany redox transformations of 2,6-di-tert-butylhydroquinone, 2,6-diphenyl-para-benzoquinone, and 2,4,6-tri-tert-butylphenol adsorbed on silica gel. Derivatives of 3,5-substituted pyrocatechols formed under conditions of heterophase oxidation in air are capable of transformations to form nitrogen-containing compounds.", 
    "genre": "article", 
    "id": "sg:pub.10.1007/bf02494504", 
    "inLanguage": "en", 
    "isAccessibleForFree": false, 
    "isPartOf": [
      {
        "id": "sg:journal.1022309", 
        "issn": [
          "1026-3500", 
          "1066-5285"
        ], 
        "name": "Russian Chemical Bulletin", 
        "publisher": "Springer Nature", 
        "type": "Periodical"
      }, 
      {
        "issueNumber": "10", 
        "type": "PublicationIssue"
      }, 
      {
        "type": "PublicationVolume", 
        "volumeNumber": "47"
      }
    ], 
    "keywords": [
      "nitrogen-containing compounds", 
      "protic media", 
      "redox transformations", 
      "diatomic phenols", 
      "silica gel", 
      "isomer results", 
      "benzoquinone", 
      "oxidation", 
      "derivatives", 
      "hydroxylation", 
      "analogous process", 
      "solvent", 
      "butylphenol", 
      "isomerization", 
      "pyrocatechol", 
      "compounds", 
      "phenol", 
      "formation", 
      "gel", 
      "dealkylation", 
      "quinone", 
      "butylhydroquinone", 
      "transformation", 
      "air", 
      "nature", 
      "medium", 
      "process", 
      "ratio", 
      "conditions", 
      "results"
    ], 
    "name": "Hydroxylation of substituted diatomic phenols and their derivatives", 
    "pagination": "1952-1955", 
    "productId": [
      {
        "name": "dimensions_id", 
        "type": "PropertyValue", 
        "value": [
          "pub.1012756902"
        ]
      }, 
      {
        "name": "doi", 
        "type": "PropertyValue", 
        "value": [
          "10.1007/bf02494504"
        ]
      }
    ], 
    "sameAs": [
      "https://doi.org/10.1007/bf02494504", 
      "https://app.dimensions.ai/details/publication/pub.1012756902"
    ], 
    "sdDataset": "articles", 
    "sdDatePublished": "2022-06-01T22:01", 
    "sdLicense": "https://scigraph.springernature.com/explorer/license/", 
    "sdPublisher": {
      "name": "Springer Nature - SN SciGraph project", 
      "type": "Organization"
    }, 
    "sdSource": "s3://com-springernature-scigraph/baseset/20220601/entities/gbq_results/article/article_278.jsonl", 
    "type": "ScholarlyArticle", 
    "url": "https://doi.org/10.1007/bf02494504"
  }
]
 

Download the RDF metadata as:  json-ld nt turtle xml License info

HOW TO GET THIS DATA PROGRAMMATICALLY:

JSON-LD is a popular format for linked data which is fully compatible with JSON.

curl -H 'Accept: application/ld+json' 'https://scigraph.springernature.com/pub.10.1007/bf02494504'

N-Triples is a line-based linked data format ideal for batch operations.

curl -H 'Accept: application/n-triples' 'https://scigraph.springernature.com/pub.10.1007/bf02494504'

Turtle is a human-readable linked data format.

curl -H 'Accept: text/turtle' 'https://scigraph.springernature.com/pub.10.1007/bf02494504'

RDF/XML is a standard XML format for linked data.

curl -H 'Accept: application/rdf+xml' 'https://scigraph.springernature.com/pub.10.1007/bf02494504'


 

This table displays all metadata directly associated to this object as RDF triples.

116 TRIPLES      21 PREDICATES      56 URIs      48 LITERALS      6 BLANK NODES

Subject Predicate Object
1 sg:pub.10.1007/bf02494504 schema:about anzsrc-for:03
2 anzsrc-for:0306
3 schema:author Ndd0504d073284293ae4c2072c284aace
4 schema:datePublished 1998-10
5 schema:datePublishedReg 1998-10-01
6 schema:description Oxidation of 3,6-di-tert-butylpyrocatechol in protic media is accompanied by the formation of 3,6-di-tert-butyl-2-hydroxy-para-benzoquinone. Hydroxylation of the 3,5-isomer results in dealkylation and isomerization with the formation of 6-tert-butyl-2-hydroxy-para-benzoquinone and the quinone mentioned above, respectively. Their ratio depends on the nature of the solvent. Analogous processes accompany redox transformations of 2,6-di-tert-butylhydroquinone, 2,6-diphenyl-para-benzoquinone, and 2,4,6-tri-tert-butylphenol adsorbed on silica gel. Derivatives of 3,5-substituted pyrocatechols formed under conditions of heterophase oxidation in air are capable of transformations to form nitrogen-containing compounds.
7 schema:genre article
8 schema:inLanguage en
9 schema:isAccessibleForFree false
10 schema:isPartOf N2241a889920248639e4ed114f5f47c11
11 N5ba5da64beee4323afbf976a46fc32f1
12 sg:journal.1022309
13 schema:keywords air
14 analogous process
15 benzoquinone
16 butylhydroquinone
17 butylphenol
18 compounds
19 conditions
20 dealkylation
21 derivatives
22 diatomic phenols
23 formation
24 gel
25 hydroxylation
26 isomer results
27 isomerization
28 medium
29 nature
30 nitrogen-containing compounds
31 oxidation
32 phenol
33 process
34 protic media
35 pyrocatechol
36 quinone
37 ratio
38 redox transformations
39 results
40 silica gel
41 solvent
42 transformation
43 schema:name Hydroxylation of substituted diatomic phenols and their derivatives
44 schema:pagination 1952-1955
45 schema:productId Nc81e6cbec3c2460dbf11c15e01c9f155
46 Nd81cbfb1fcb547b2a3ac252fe57f1f26
47 schema:sameAs https://app.dimensions.ai/details/publication/pub.1012756902
48 https://doi.org/10.1007/bf02494504
49 schema:sdDatePublished 2022-06-01T22:01
50 schema:sdLicense https://scigraph.springernature.com/explorer/license/
51 schema:sdPublisher Nda783e1fb4674e87a8e4493cf1a0d5eb
52 schema:url https://doi.org/10.1007/bf02494504
53 sgo:license sg:explorer/license/
54 sgo:sdDataset articles
55 rdf:type schema:ScholarlyArticle
56 N2241a889920248639e4ed114f5f47c11 schema:issueNumber 10
57 rdf:type schema:PublicationIssue
58 N2e48b2251f574ea0800bbf2a5dd6eeaf rdf:first sg:person.015523023503.99
59 rdf:rest Nda7e090ee20a48d08d86458769da0791
60 N5ba5da64beee4323afbf976a46fc32f1 schema:volumeNumber 47
61 rdf:type schema:PublicationVolume
62 N7c599cdf5d94424bbd0c509dd0577166 rdf:first sg:person.016162132527.56
63 rdf:rest N2e48b2251f574ea0800bbf2a5dd6eeaf
64 N7c893ade5d28411daa2b6325b45b0514 rdf:first sg:person.010414742241.10
65 rdf:rest rdf:nil
66 Nc81e6cbec3c2460dbf11c15e01c9f155 schema:name dimensions_id
67 schema:value pub.1012756902
68 rdf:type schema:PropertyValue
69 Nd81cbfb1fcb547b2a3ac252fe57f1f26 schema:name doi
70 schema:value 10.1007/bf02494504
71 rdf:type schema:PropertyValue
72 Nda783e1fb4674e87a8e4493cf1a0d5eb schema:name Springer Nature - SN SciGraph project
73 rdf:type schema:Organization
74 Nda7e090ee20a48d08d86458769da0791 rdf:first sg:person.016121506364.44
75 rdf:rest N7c893ade5d28411daa2b6325b45b0514
76 Ndd0504d073284293ae4c2072c284aace rdf:first sg:person.014515631207.10
77 rdf:rest N7c599cdf5d94424bbd0c509dd0577166
78 anzsrc-for:03 schema:inDefinedTermSet anzsrc-for:
79 schema:name Chemical Sciences
80 rdf:type schema:DefinedTerm
81 anzsrc-for:0306 schema:inDefinedTermSet anzsrc-for:
82 schema:name Physical Chemistry (incl. Structural)
83 rdf:type schema:DefinedTerm
84 sg:journal.1022309 schema:issn 1026-3500
85 1066-5285
86 schema:name Russian Chemical Bulletin
87 schema:publisher Springer Nature
88 rdf:type schema:Periodical
89 sg:person.010414742241.10 schema:affiliation grid-institutes:grid.4886.2
90 schema:familyName Ershov
91 schema:givenName V. V.
92 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.010414742241.10
93 rdf:type schema:Person
94 sg:person.014515631207.10 schema:affiliation grid-institutes:grid.4886.2
95 schema:familyName Vol'eva
96 schema:givenName V. B.
97 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.014515631207.10
98 rdf:type schema:Person
99 sg:person.015523023503.99 schema:affiliation grid-institutes:grid.4886.2
100 schema:familyName Belostotskaya
101 schema:givenName I. S.
102 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.015523023503.99
103 rdf:type schema:Person
104 sg:person.016121506364.44 schema:affiliation grid-institutes:grid.4886.2
105 schema:familyName Komissarova
106 schema:givenName N. L.
107 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.016121506364.44
108 rdf:type schema:Person
109 sg:person.016162132527.56 schema:affiliation grid-institutes:grid.4886.2
110 schema:familyName Prokofeva
111 schema:givenName T. I.
112 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.016162132527.56
113 rdf:type schema:Person
114 grid-institutes:grid.4886.2 schema:alternateName N. M. Emanuel Institute of Biochemical Physics, Russian Academy of Sciences, 4 ul. Kosygina, 117977, Moscow, Russian Federation
115 schema:name N. M. Emanuel Institute of Biochemical Physics, Russian Academy of Sciences, 4 ul. Kosygina, 117977, Moscow, Russian Federation
116 rdf:type schema:Organization
 




Preview window. Press ESC to close (or click here)


...