Hydroxylation of substituted diatomic phenols and their derivatives View Full Text


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Article Info

DATE

1998-10

AUTHORS

V. B. Vol'eva, T. I. Prokofeva, I. S. Belostotskaya, N. L. Komissarova, V. V. Ershov

ABSTRACT

Oxidation of 3,6-di-tert-butylpyrocatechol in protic media is accompanied by the formation of 3,6-di-tert-butyl-2-hydroxy-para-benzoquinone. Hydroxylation of the 3,5-isomer results in dealkylation and isomerization with the formation of 6-tert-butyl-2-hydroxy-para-benzoquinone and the quinone mentioned above, respectively. Their ratio depends on the nature of the solvent. Analogous processes accompany redox transformations of 2,6-di-tert-butylhydroquinone, 2,6-diphenyl-para-benzoquinone, and 2,4,6-tri-tert-butylphenol adsorbed on silica gel. Derivatives of 3,5-substituted pyrocatechols formed under conditions of heterophase oxidation in air are capable of transformations to form nitrogen-containing compounds. More... »

PAGES

1952-1955

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/bf02494504

DOI

http://dx.doi.org/10.1007/bf02494504

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1012756902


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