Ontology type: schema:ScholarlyArticle
1998-10
AUTHORSV. B. Vol'eva, T. I. Prokofeva, I. S. Belostotskaya, N. L. Komissarova, V. V. Ershov
ABSTRACTOxidation of 3,6-di-tert-butylpyrocatechol in protic media is accompanied by the formation of 3,6-di-tert-butyl-2-hydroxy-para-benzoquinone. Hydroxylation of the 3,5-isomer results in dealkylation and isomerization with the formation of 6-tert-butyl-2-hydroxy-para-benzoquinone and the quinone mentioned above, respectively. Their ratio depends on the nature of the solvent. Analogous processes accompany redox transformations of 2,6-di-tert-butylhydroquinone, 2,6-diphenyl-para-benzoquinone, and 2,4,6-tri-tert-butylphenol adsorbed on silica gel. Derivatives of 3,5-substituted pyrocatechols formed under conditions of heterophase oxidation in air are capable of transformations to form nitrogen-containing compounds. More... »
PAGES1952-1955
http://scigraph.springernature.com/pub.10.1007/bf02494504
DOIhttp://dx.doi.org/10.1007/bf02494504
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