JSON-LD is the canonical representation for SciGraph data.

TIP: You can open this SciGraph record using an external JSON-LD service: JSON-LD Playground Google SDTT

[
  {
    "@context": "https://springernature.github.io/scigraph/jsonld/sgcontext.json", 
    "about": [
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/03", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Chemical Sciences", 
        "type": "DefinedTerm"
      }, 
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/0306", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Physical Chemistry (incl. Structural)", 
        "type": "DefinedTerm"
      }
    ], 
    "author": [
      {
        "affiliation": {
          "alternateName": "Institute of Physical and Organic Chemistry, Rostov State University, 194/2 prosp. Stachki, 344090, Rostov-on-Don, Russian Federation", 
          "id": "http://www.grid.ac/institutes/grid.182798.d", 
          "name": [
            "Institute of Physical and Organic Chemistry, Rostov State University, 194/2 prosp. Stachki, 344090, Rostov-on-Don, Russian Federation"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Minyaev", 
        "givenName": "R. M.", 
        "id": "sg:person.01047475616.15", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01047475616.15"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Institute of Physical and Organic Chemistry, Rostov State University, 194/2 prosp. Stachki, 344090, Rostov-on-Don, Russian Federation", 
          "id": "http://www.grid.ac/institutes/grid.182798.d", 
          "name": [
            "Institute of Physical and Organic Chemistry, Rostov State University, 194/2 prosp. Stachki, 344090, Rostov-on-Don, Russian Federation"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Starikov", 
        "givenName": "A. G.", 
        "id": "sg:person.014454430517.25", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.014454430517.25"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Institute of Physical and Organic Chemistry, Rostov State University, 194/2 prosp. Stachki, 344090, Rostov-on-Don, Russian Federation", 
          "id": "http://www.grid.ac/institutes/grid.182798.d", 
          "name": [
            "Institute of Physical and Organic Chemistry, Rostov State University, 194/2 prosp. Stachki, 344090, Rostov-on-Don, Russian Federation"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Lepin", 
        "givenName": "E. A.", 
        "id": "sg:person.015512412246.54", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.015512412246.54"
        ], 
        "type": "Person"
      }
    ], 
    "citation": [
      {
        "id": "sg:pub.10.1007/978-3-642-85135-3", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1046948342", 
          "https://doi.org/10.1007/978-3-642-85135-3"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1007/bf00549608", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1002585686", 
          "https://doi.org/10.1007/bf00549608"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1007/978-3-642-75679-5", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1035676274", 
          "https://doi.org/10.1007/978-3-642-75679-5"
        ], 
        "type": "CreativeWork"
      }
    ], 
    "datePublished": "1998-11", 
    "datePublishedReg": "1998-11-01", 
    "description": "The gradient pathways of the reactions of nucleophilic addition of H2O and HF molecules to formaldehyde in the gas phase and in the XH\u2026H2CO\u2026HC(O)OH complex (X=OH, F) were calculated by theab initio RHF/6-31G**, MP2(fc)/6-31G**, and MP2(full)/6-311++G** methods. Both reactions proceed concertedly. The formation of H-bonded bimolecular pre-reaction complexes is the initial stage of the gas-phase reactions; at the same time, no indications of the formation of stable \u03c0-complexes were found on the potential energy surfaces of systems under study. The calculated energy barriers to the gasphase reactions exceed 40 kcal mol\u22121, while those to reactions in the complex XH\u2026H2CO\u2026HC(O)OH (X=OH, F) become more than halved.", 
    "genre": "article", 
    "id": "sg:pub.10.1007/bf02494259", 
    "inLanguage": "en", 
    "isAccessibleForFree": false, 
    "isPartOf": [
      {
        "id": "sg:journal.1022309", 
        "issn": [
          "1026-3500", 
          "1066-5285"
        ], 
        "name": "Russian Chemical Bulletin", 
        "publisher": "Springer Nature", 
        "type": "Periodical"
      }, 
      {
        "issueNumber": "11", 
        "type": "PublicationIssue"
      }, 
      {
        "type": "PublicationVolume", 
        "volumeNumber": "47"
      }
    ], 
    "keywords": [
      "nucleophilic addition", 
      "gas phase", 
      "HF molecules", 
      "pre-reaction complex", 
      "gas-phase reactions", 
      "RHF/6-31G", 
      "potential energy surface", 
      "ab initio calculations", 
      "gasphase reactions", 
      "formic acid", 
      "initio calculations", 
      "energy surface", 
      "energy barrier", 
      "reaction", 
      "complexes", 
      "molecules", 
      "H2CO", 
      "H2O", 
      "XH", 
      "formation", 
      "phase", 
      "initial stage", 
      "acid", 
      "surface", 
      "calculations", 
      "addition", 
      "method", 
      "pathway", 
      "barriers", 
      "system", 
      "same time", 
      "time", 
      "study", 
      "stage", 
      "indications"
    ], 
    "name": "Pathways of the reactions of nucleophilic addition of H2O and HF molecules to formaldehyde in the gas phase and in the complex with formic acid:ab initio calculations", 
    "pagination": "2078-2086", 
    "productId": [
      {
        "name": "dimensions_id", 
        "type": "PropertyValue", 
        "value": [
          "pub.1035661486"
        ]
      }, 
      {
        "name": "doi", 
        "type": "PropertyValue", 
        "value": [
          "10.1007/bf02494259"
        ]
      }
    ], 
    "sameAs": [
      "https://doi.org/10.1007/bf02494259", 
      "https://app.dimensions.ai/details/publication/pub.1035661486"
    ], 
    "sdDataset": "articles", 
    "sdDatePublished": "2022-05-20T07:20", 
    "sdLicense": "https://scigraph.springernature.com/explorer/license/", 
    "sdPublisher": {
      "name": "Springer Nature - SN SciGraph project", 
      "type": "Organization"
    }, 
    "sdSource": "s3://com-springernature-scigraph/baseset/20220519/entities/gbq_results/article/article_281.jsonl", 
    "type": "ScholarlyArticle", 
    "url": "https://doi.org/10.1007/bf02494259"
  }
]

Download the RDF metadata as:  json-ld nt turtle xml License info

This table displays all metadata directly associated to this object as RDF triples.

119 TRIPLES      22 PREDICATES      64 URIs      53 LITERALS      6 BLANK NODES