Discussion of thermodynamic data obtained by adsorption gas chromatography of hydrocarbons on carbograph 4 View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2001-04

AUTHORS

A. R. Mastrogiacomo, E. Pierini

ABSTRACT

A new graphitized carbon black, Carbograph 4, with a specific surface area of 240 m2 g−1 was studied in terms of enthalpy, entropy and free energy of adsorption, determined by gas chromatographic method on a series of alkanes (C2−C6) and on benzene. The changes in the isosteric heat and entropy of adsorption when a non-polar stationary phase (squalane) was added to the adsorbent were also investigated. The data obtained are discussed and compared to those present in the literature for other graphitized carbon blacks. Some examples of separations obtained with Carbograph 4 are reported. More... »

PAGES

437-441

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/bf02491081

DOI

http://dx.doi.org/10.1007/bf02491081

DIMENSIONS

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