Progress in the lithium insertion mechanism in Cu3P View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2005-01

AUTHORS

B. Mauvernay, M. -P. Bichat, F. Favier, L. Monconduit, M. Morcrette, M. -L. Doublet

ABSTRACT

Copper phosphide, Cu3P has been synthesized using a ceramic route, and its electrochemical behaviour versus lithium has been studied studied galvanostatic and potentiodynamic measurements and in situ X-ray diffraction analysis. The insertion/extraction mechanism proceeds with the formation of at least three different LixCu3−xP (x=1, 2, 3) phases. The electrochemical behaviour of Cu3P samples obtained from ceramic and solvothermal syntheses are compared to further understanding of the complex redox mechanism occurring during insertion/extraction. First-principle electronic structure calculations show that discharge probably begins with the formation of a solid solution LixCu3−yP (x<0.5). More... »

PAGES

36-45

References to SciGraph publications

Journal

TITLE

Ionics

ISSUE

1-2

VOLUME

11

Author Affiliations

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/bf02430400

DOI

http://dx.doi.org/10.1007/bf02430400

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1048209265


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