TDPAC study on the thermal stability of zirconium tetrafluoride View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

1986-03

AUTHORS

P. C. Rivas, M. C. Caracoche, J. A. Martínez, M. T. Dova, A. R. López García

ABSTRACT

The thermal evolution of the hyperfine interaction in α-ZrF4 is investigated between 293 K and 788 K. The first change, observed ay 534 K, is attributed to the appearance of the non-stoichiometric compound ZrO1.3F1.4. During the transformation, the relative fraction of the latter shows an Arrhenius behaviour with an activation energyEa=(22.6±5.5) kJ/mol. At approximately 700 K, ZrO1.3F1.4 gives rise to the monoclinic phase of ZrO2 and to β-ZrF4. More... »

PAGES

49-55

Journal

TITLE

Hyperfine Interactions

ISSUE

1

VOLUME

30

Author Affiliations

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/bf02400100

DOI

http://dx.doi.org/10.1007/bf02400100

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1030334712


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