Hyperfine interactions in Li2ZrF6 and Li2HfF6 View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

1986-08

AUTHORS

M. T. Dova, P. C. Rivas, J. A. Martínez, M. C. Caracoche, A. R. López García

ABSTRACT

The quadrupole hyperfine interaction in Li2ZrF6 and Li2HfF6 has been studied as a function of temperature. Both lattices are characterized by very similar low and symmetric electric field gradients at probe sites and no phase transitions were observed up to 770 K. On heating, between 700 and 830 K, the Li2ZrF6 undergoes chemical reactions which give rise to ZrO2 and then to Li3ZrF7 (high temperature α-phase) and Li2ZrO3. On cooling, below 750 K, the α→β transition in Li3 ZrF7 already reported is found to take place. An analogous behaviour is determined for Li2HfF6. Accordingly, the same decomposition steps and exstence of high and low temperature phases for Li3HfF7 can be inferred. More... »

PAGES

199-204

Journal

TITLE

Hyperfine Interactions

ISSUE

3

VOLUME

30

Author Affiliations

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/bf02396915

DOI

http://dx.doi.org/10.1007/bf02396915

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1000742741


Indexing Status Check whether this publication has been indexed by Scopus and Web Of Science using the SN Indexing Status Tool
Incoming Citations Browse incoming citations for this publication using opencitations.net

JSON-LD is the canonical representation for SciGraph data.

TIP: You can open this SciGraph record using an external JSON-LD service: JSON-LD Playground Google SDTT

[
  {
    "@context": "https://springernature.github.io/scigraph/jsonld/sgcontext.json", 
    "about": [
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/0912", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Materials Engineering", 
        "type": "DefinedTerm"
      }, 
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/09", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Engineering", 
        "type": "DefinedTerm"
      }
    ], 
    "author": [
      {
        "affiliation": {
          "alternateName": "National University of La Plata", 
          "id": "https://www.grid.ac/institutes/grid.9499.d", 
          "name": [
            "Departamento de F\u00edsica, Facultad de Ciencias Exactas, Universidad Nacional de La Plata, CC 67, 1900, La Plata, Argentina"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Dova", 
        "givenName": "M. T.", 
        "id": "sg:person.011635004202.28", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.011635004202.28"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "National University of La Plata", 
          "id": "https://www.grid.ac/institutes/grid.9499.d", 
          "name": [
            "Departamento de F\u00edsica, Facultad de Ciencias Exactas, Universidad Nacional de La Plata, CC 67, 1900, La Plata, Argentina"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Rivas", 
        "givenName": "P. C.", 
        "id": "sg:person.015526554405.93", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.015526554405.93"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "National University of La Plata", 
          "id": "https://www.grid.ac/institutes/grid.9499.d", 
          "name": [
            "Departamento de F\u00edsica, Facultad de Ciencias Exactas, Universidad Nacional de La Plata, CC 67, 1900, La Plata, Argentina"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Mart\u00ednez", 
        "givenName": "J. A.", 
        "id": "sg:person.015745323505.02", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.015745323505.02"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "National University of La Plata", 
          "id": "https://www.grid.ac/institutes/grid.9499.d", 
          "name": [
            "Departamento de F\u00edsica, Facultad de Ciencias Exactas, Universidad Nacional de La Plata, CC 67, 1900, La Plata, Argentina"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Caracoche", 
        "givenName": "M. C.", 
        "id": "sg:person.013631260505.16", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.013631260505.16"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "National University of La Plata", 
          "id": "https://www.grid.ac/institutes/grid.9499.d", 
          "name": [
            "Departamento de F\u00edsica, Facultad de Ciencias Exactas, Universidad Nacional de La Plata, CC 67, 1900, La Plata, Argentina"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Garc\u00eda", 
        "givenName": "A. R. L\u00f3pez", 
        "id": "sg:person.013041714551.79", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.013041714551.79"
        ], 
        "type": "Person"
      }
    ], 
    "citation": [
      {
        "id": "https://doi.org/10.1107/s0567740873006515", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1038294213"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1088/0022-3719/7/2/021", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1058967289"
        ], 
        "type": "CreativeWork"
      }
    ], 
    "datePublished": "1986-08", 
    "datePublishedReg": "1986-08-01", 
    "description": "The quadrupole hyperfine interaction in Li2ZrF6 and Li2HfF6 has been studied as a function of temperature. Both lattices are characterized by very similar low and symmetric electric field gradients at probe sites and no phase transitions were observed up to 770 K. On heating, between 700 and 830 K, the Li2ZrF6 undergoes chemical reactions which give rise to ZrO2 and then to Li3ZrF7 (high temperature \u03b1-phase) and Li2ZrO3. On cooling, below 750 K, the \u03b1\u2192\u03b2 transition in Li3 ZrF7 already reported is found to take place. An analogous behaviour is determined for Li2HfF6. Accordingly, the same decomposition steps and exstence of high and low temperature phases for Li3HfF7 can be inferred.", 
    "genre": "research_article", 
    "id": "sg:pub.10.1007/bf02396915", 
    "inLanguage": [
      "en"
    ], 
    "isAccessibleForFree": false, 
    "isPartOf": [
      {
        "id": "sg:journal.1038685", 
        "issn": [
          "0304-3843", 
          "1572-9540"
        ], 
        "name": "Hyperfine Interactions", 
        "type": "Periodical"
      }, 
      {
        "issueNumber": "3", 
        "type": "PublicationIssue"
      }, 
      {
        "type": "PublicationVolume", 
        "volumeNumber": "30"
      }
    ], 
    "name": "Hyperfine interactions in Li2ZrF6 and Li2HfF6", 
    "pagination": "199-204", 
    "productId": [
      {
        "name": "readcube_id", 
        "type": "PropertyValue", 
        "value": [
          "0389790cfb1b59a7cca2b3e459f74ce36105405604839fb6c658599a4419e712"
        ]
      }, 
      {
        "name": "doi", 
        "type": "PropertyValue", 
        "value": [
          "10.1007/bf02396915"
        ]
      }, 
      {
        "name": "dimensions_id", 
        "type": "PropertyValue", 
        "value": [
          "pub.1000742741"
        ]
      }
    ], 
    "sameAs": [
      "https://doi.org/10.1007/bf02396915", 
      "https://app.dimensions.ai/details/publication/pub.1000742741"
    ], 
    "sdDataset": "articles", 
    "sdDatePublished": "2019-04-10T17:24", 
    "sdLicense": "https://scigraph.springernature.com/explorer/license/", 
    "sdPublisher": {
      "name": "Springer Nature - SN SciGraph project", 
      "type": "Organization"
    }, 
    "sdSource": "s3://com-uberresearch-data-dimensions-target-20181106-alternative/cleanup/v134/2549eaecd7973599484d7c17b260dba0a4ecb94b/merge/v9/a6c9fde33151104705d4d7ff012ea9563521a3ce/jats-lookup/v90/0000000001_0000000264/records_8672_00000479.jsonl", 
    "type": "ScholarlyArticle", 
    "url": "http://link.springer.com/10.1007/BF02396915"
  }
]
 

Download the RDF metadata as:  json-ld nt turtle xml License info

HOW TO GET THIS DATA PROGRAMMATICALLY:

JSON-LD is a popular format for linked data which is fully compatible with JSON.

curl -H 'Accept: application/ld+json' 'https://scigraph.springernature.com/pub.10.1007/bf02396915'

N-Triples is a line-based linked data format ideal for batch operations.

curl -H 'Accept: application/n-triples' 'https://scigraph.springernature.com/pub.10.1007/bf02396915'

Turtle is a human-readable linked data format.

curl -H 'Accept: text/turtle' 'https://scigraph.springernature.com/pub.10.1007/bf02396915'

RDF/XML is a standard XML format for linked data.

curl -H 'Accept: application/rdf+xml' 'https://scigraph.springernature.com/pub.10.1007/bf02396915'


 

This table displays all metadata directly associated to this object as RDF triples.

95 TRIPLES      21 PREDICATES      29 URIs      19 LITERALS      7 BLANK NODES

Subject Predicate Object
1 sg:pub.10.1007/bf02396915 schema:about anzsrc-for:09
2 anzsrc-for:0912
3 schema:author N8679fde42cd346409c43c7648860fd58
4 schema:citation https://doi.org/10.1088/0022-3719/7/2/021
5 https://doi.org/10.1107/s0567740873006515
6 schema:datePublished 1986-08
7 schema:datePublishedReg 1986-08-01
8 schema:description The quadrupole hyperfine interaction in Li2ZrF6 and Li2HfF6 has been studied as a function of temperature. Both lattices are characterized by very similar low and symmetric electric field gradients at probe sites and no phase transitions were observed up to 770 K. On heating, between 700 and 830 K, the Li2ZrF6 undergoes chemical reactions which give rise to ZrO2 and then to Li3ZrF7 (high temperature α-phase) and Li2ZrO3. On cooling, below 750 K, the α→β transition in Li3 ZrF7 already reported is found to take place. An analogous behaviour is determined for Li2HfF6. Accordingly, the same decomposition steps and exstence of high and low temperature phases for Li3HfF7 can be inferred.
9 schema:genre research_article
10 schema:inLanguage en
11 schema:isAccessibleForFree false
12 schema:isPartOf N4ab98260009744d5a9808d2631fd5c24
13 Ncca8bee5225b4ae4a180efce7f5836f9
14 sg:journal.1038685
15 schema:name Hyperfine interactions in Li2ZrF6 and Li2HfF6
16 schema:pagination 199-204
17 schema:productId N450b807b055c49939fceaa28ce4d9b77
18 N7ee11ef43bba4ab5b9b069e9b8ac0745
19 Nf8f18d13add941aa8540d74147cf2829
20 schema:sameAs https://app.dimensions.ai/details/publication/pub.1000742741
21 https://doi.org/10.1007/bf02396915
22 schema:sdDatePublished 2019-04-10T17:24
23 schema:sdLicense https://scigraph.springernature.com/explorer/license/
24 schema:sdPublisher Na82b55a7bfc94244afee82f3c583dc9f
25 schema:url http://link.springer.com/10.1007/BF02396915
26 sgo:license sg:explorer/license/
27 sgo:sdDataset articles
28 rdf:type schema:ScholarlyArticle
29 N450b807b055c49939fceaa28ce4d9b77 schema:name dimensions_id
30 schema:value pub.1000742741
31 rdf:type schema:PropertyValue
32 N4ab98260009744d5a9808d2631fd5c24 schema:issueNumber 3
33 rdf:type schema:PublicationIssue
34 N6b4518879f2a46799391a4da9711b79e rdf:first sg:person.013041714551.79
35 rdf:rest rdf:nil
36 N77fe7276f09647eebc4f5ebe21879c59 rdf:first sg:person.015745323505.02
37 rdf:rest Nf0d8955642484968b9ed1fbe9c5baa95
38 N7ee11ef43bba4ab5b9b069e9b8ac0745 schema:name readcube_id
39 schema:value 0389790cfb1b59a7cca2b3e459f74ce36105405604839fb6c658599a4419e712
40 rdf:type schema:PropertyValue
41 N8679fde42cd346409c43c7648860fd58 rdf:first sg:person.011635004202.28
42 rdf:rest Na73f8cb58ff64df09277fe2de5b5bd9a
43 Na73f8cb58ff64df09277fe2de5b5bd9a rdf:first sg:person.015526554405.93
44 rdf:rest N77fe7276f09647eebc4f5ebe21879c59
45 Na82b55a7bfc94244afee82f3c583dc9f schema:name Springer Nature - SN SciGraph project
46 rdf:type schema:Organization
47 Ncca8bee5225b4ae4a180efce7f5836f9 schema:volumeNumber 30
48 rdf:type schema:PublicationVolume
49 Nf0d8955642484968b9ed1fbe9c5baa95 rdf:first sg:person.013631260505.16
50 rdf:rest N6b4518879f2a46799391a4da9711b79e
51 Nf8f18d13add941aa8540d74147cf2829 schema:name doi
52 schema:value 10.1007/bf02396915
53 rdf:type schema:PropertyValue
54 anzsrc-for:09 schema:inDefinedTermSet anzsrc-for:
55 schema:name Engineering
56 rdf:type schema:DefinedTerm
57 anzsrc-for:0912 schema:inDefinedTermSet anzsrc-for:
58 schema:name Materials Engineering
59 rdf:type schema:DefinedTerm
60 sg:journal.1038685 schema:issn 0304-3843
61 1572-9540
62 schema:name Hyperfine Interactions
63 rdf:type schema:Periodical
64 sg:person.011635004202.28 schema:affiliation https://www.grid.ac/institutes/grid.9499.d
65 schema:familyName Dova
66 schema:givenName M. T.
67 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.011635004202.28
68 rdf:type schema:Person
69 sg:person.013041714551.79 schema:affiliation https://www.grid.ac/institutes/grid.9499.d
70 schema:familyName García
71 schema:givenName A. R. López
72 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.013041714551.79
73 rdf:type schema:Person
74 sg:person.013631260505.16 schema:affiliation https://www.grid.ac/institutes/grid.9499.d
75 schema:familyName Caracoche
76 schema:givenName M. C.
77 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.013631260505.16
78 rdf:type schema:Person
79 sg:person.015526554405.93 schema:affiliation https://www.grid.ac/institutes/grid.9499.d
80 schema:familyName Rivas
81 schema:givenName P. C.
82 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.015526554405.93
83 rdf:type schema:Person
84 sg:person.015745323505.02 schema:affiliation https://www.grid.ac/institutes/grid.9499.d
85 schema:familyName Martínez
86 schema:givenName J. A.
87 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.015745323505.02
88 rdf:type schema:Person
89 https://doi.org/10.1088/0022-3719/7/2/021 schema:sameAs https://app.dimensions.ai/details/publication/pub.1058967289
90 rdf:type schema:CreativeWork
91 https://doi.org/10.1107/s0567740873006515 schema:sameAs https://app.dimensions.ai/details/publication/pub.1038294213
92 rdf:type schema:CreativeWork
93 https://www.grid.ac/institutes/grid.9499.d schema:alternateName National University of La Plata
94 schema:name Departamento de Física, Facultad de Ciencias Exactas, Universidad Nacional de La Plata, CC 67, 1900, La Plata, Argentina
95 rdf:type schema:Organization
 




Preview window. Press ESC to close (or click here)


...