Time-dependent electric quadrupole interactions in (NH4)3HfF7 View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

1973-08

AUTHORS

E. Gerdau, J. Birke, H. Winkler, J. Braunsfurth, M. Forker, G. Netz

ABSTRACT

Spinrotation spectra of polycrystalline (NH4)3HfF7 in which radioactive181Hf was incorporated have been measured in the temperature range from −196 °C to + 70 °C. The spectra were interpretated on the base of the stochastic model of M. Blume. It was assumed that reorientations of the [HfF7]3− polyhedra take place at random. The resulting fluctuation rates can be understood as to be caused by an activation process. The activation energy was determined to 0.324(12) eV in agreement with NMR measurements on19F in this compound. More... »

PAGES

5-14

References to SciGraph publications

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/bf02351857

DOI

http://dx.doi.org/10.1007/bf02351857

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1042561227


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