57Fe Mössbauer spectroscopic and magnetic study of a spin-crossover polymer complex, Fe(3-chloropyridine)2Ni(CN)4 View Full Text


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Article Info

DATE

1999-02

AUTHORS

T. Kitazawa, Mi. Takahashi, Ma. Takahashi, M. Enomoto, A. Miyazaki, T. Enoki, M. Takeda

ABSTRACT

The coordination polymer Fe(3-chloropyridine)2Ni(CN)4 (2) has been prepared by a method similar to that for Fe(pyridine)2Ni(CN)4 (1). The complex (2) has been characterized by57Fe Mössbauer spectroscopy and a SQUID technique.57Fe Mössbauer and magnetic susceptibility data show that complex (2) exhibits spin-crossover behavior. The spin transition of (2) occurs between 120 and 80 K with very small hysteresis or without hysteresis. The temperature range of the spin transition in (2) is lower than that in (1). A residual high spin iron(II) fraction is observed at low temperatures in (2), being different from (1). SQUID data also show that samples treated differently yield different spin transition curves. More... »

PAGES

285-290

References to SciGraph publications

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/bf02349498

DOI

http://dx.doi.org/10.1007/bf02349498

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1034409303


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