Modelling and simulation of sorption selectivity in the bentonite-HCO3−−CO32−−233U(VI) species system View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

1999-09

AUTHORS

K. Štamberg, J. Škrkal, P. Beneš, K. Chalupská, D. Vopálka

ABSTRACT

A surface complexation model, the so-called diffuse double layer model (DLM), was used in the description of the multicomponent system consisting of Czech sodium bentonite SABENYL and synthetic granitic water spiked with233U(VI). The experimental data were evaluated and the characteristic parameters, e.g., the equilibrium constants of all the reactions considered, were obtained and used for the numerical simulation of sorption selectivity of the uranium in relation to the total carbonate concentration. The values of separation factors indicate that the selectivity of uranium sorption in such multicomponent systems can depend not only on the pH and composition of both phases, but also on the phase ratio and starting concentrations of participating components. More... »

PAGES

487-492

References to SciGraph publications

  • 1985. Reversibility and Performances in Productive Ion-Exchange Chromatography in FUNDAMENTALS AND APPLICATIONS OF ION EXCHANGE
  • Identifiers

    URI

    http://scigraph.springernature.com/pub.10.1007/bf02347202

    DOI

    http://dx.doi.org/10.1007/bf02347202

    DIMENSIONS

    https://app.dimensions.ai/details/publication/pub.1053477281


    Indexing Status Check whether this publication has been indexed by Scopus and Web Of Science using the SN Indexing Status Tool
    Incoming Citations Browse incoming citations for this publication using opencitations.net

    JSON-LD is the canonical representation for SciGraph data.

    TIP: You can open this SciGraph record using an external JSON-LD service: JSON-LD Playground Google SDTT

    [
      {
        "@context": "https://springernature.github.io/scigraph/jsonld/sgcontext.json", 
        "about": [
          {
            "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/03", 
            "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
            "name": "Chemical Sciences", 
            "type": "DefinedTerm"
          }, 
          {
            "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/0306", 
            "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
            "name": "Physical Chemistry (incl. Structural)", 
            "type": "DefinedTerm"
          }
        ], 
        "author": [
          {
            "affiliation": {
              "alternateName": "Faculty of Nuclear Science and Physical Engineering, Department of Nuclear Chemistry, Czech Technical University, B\u0159ehov\u00e1 7, 11519, Praha 1, Czech Republic", 
              "id": "http://www.grid.ac/institutes/grid.6652.7", 
              "name": [
                "Faculty of Nuclear Science and Physical Engineering, Department of Nuclear Chemistry, Czech Technical University, B\u0159ehov\u00e1 7, 11519, Praha 1, Czech Republic"
              ], 
              "type": "Organization"
            }, 
            "familyName": "\u0160tamberg", 
            "givenName": "K.", 
            "id": "sg:person.013724421353.14", 
            "sameAs": [
              "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.013724421353.14"
            ], 
            "type": "Person"
          }, 
          {
            "affiliation": {
              "alternateName": "Faculty of Nuclear Science and Physical Engineering, Department of Nuclear Chemistry, Czech Technical University, B\u0159ehov\u00e1 7, 11519, Praha 1, Czech Republic", 
              "id": "http://www.grid.ac/institutes/grid.6652.7", 
              "name": [
                "Faculty of Nuclear Science and Physical Engineering, Department of Nuclear Chemistry, Czech Technical University, B\u0159ehov\u00e1 7, 11519, Praha 1, Czech Republic"
              ], 
              "type": "Organization"
            }, 
            "familyName": "\u0160krkal", 
            "givenName": "J.", 
            "id": "sg:person.012273177333.01", 
            "sameAs": [
              "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.012273177333.01"
            ], 
            "type": "Person"
          }, 
          {
            "affiliation": {
              "alternateName": "Faculty of Nuclear Science and Physical Engineering, Department of Nuclear Chemistry, Czech Technical University, B\u0159ehov\u00e1 7, 11519, Praha 1, Czech Republic", 
              "id": "http://www.grid.ac/institutes/grid.6652.7", 
              "name": [
                "Faculty of Nuclear Science and Physical Engineering, Department of Nuclear Chemistry, Czech Technical University, B\u0159ehov\u00e1 7, 11519, Praha 1, Czech Republic"
              ], 
              "type": "Organization"
            }, 
            "familyName": "Bene\u0161", 
            "givenName": "P.", 
            "id": "sg:person.01237712015.74", 
            "sameAs": [
              "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01237712015.74"
            ], 
            "type": "Person"
          }, 
          {
            "affiliation": {
              "alternateName": "Faculty of Nuclear Science and Physical Engineering, Department of Nuclear Chemistry, Czech Technical University, B\u0159ehov\u00e1 7, 11519, Praha 1, Czech Republic", 
              "id": "http://www.grid.ac/institutes/grid.6652.7", 
              "name": [
                "Faculty of Nuclear Science and Physical Engineering, Department of Nuclear Chemistry, Czech Technical University, B\u0159ehov\u00e1 7, 11519, Praha 1, Czech Republic"
              ], 
              "type": "Organization"
            }, 
            "familyName": "Chalupsk\u00e1", 
            "givenName": "K.", 
            "id": "sg:person.015261101333.52", 
            "sameAs": [
              "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.015261101333.52"
            ], 
            "type": "Person"
          }, 
          {
            "affiliation": {
              "alternateName": "Faculty of Nuclear Science and Physical Engineering, Department of Nuclear Chemistry, Czech Technical University, B\u0159ehov\u00e1 7, 11519, Praha 1, Czech Republic", 
              "id": "http://www.grid.ac/institutes/grid.6652.7", 
              "name": [
                "Faculty of Nuclear Science and Physical Engineering, Department of Nuclear Chemistry, Czech Technical University, B\u0159ehov\u00e1 7, 11519, Praha 1, Czech Republic"
              ], 
              "type": "Organization"
            }, 
            "familyName": "Vop\u00e1lka", 
            "givenName": "D.", 
            "id": "sg:person.012651030553.25", 
            "sameAs": [
              "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.012651030553.25"
            ], 
            "type": "Person"
          }
        ], 
        "citation": [
          {
            "id": "sg:pub.10.1007/978-94-009-5161-7_24", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1003916858", 
              "https://doi.org/10.1007/978-94-009-5161-7_24"
            ], 
            "type": "CreativeWork"
          }
        ], 
        "datePublished": "1999-09", 
        "datePublishedReg": "1999-09-01", 
        "description": "A surface complexation model, the so-called diffuse double layer model (DLM), was used in the description of the multicomponent system consisting of Czech sodium bentonite SABENYL and synthetic granitic water spiked with233U(VI). The experimental data were evaluated and the characteristic parameters, e.g., the equilibrium constants of all the reactions considered, were obtained and used for the numerical simulation of sorption selectivity of the uranium in relation to the total carbonate concentration. The values of separation factors indicate that the selectivity of uranium sorption in such multicomponent systems can depend not only on the pH and composition of both phases, but also on the phase ratio and starting concentrations of participating components.", 
        "genre": "article", 
        "id": "sg:pub.10.1007/bf02347202", 
        "inLanguage": "en", 
        "isAccessibleForFree": false, 
        "isPartOf": [
          {
            "id": "sg:journal.1094634", 
            "issn": [
              "0236-5731", 
              "1588-2780"
            ], 
            "name": "Journal of Radioanalytical and Nuclear Chemistry", 
            "publisher": "Springer Nature", 
            "type": "Periodical"
          }, 
          {
            "issueNumber": "3", 
            "type": "PublicationIssue"
          }, 
          {
            "type": "PublicationVolume", 
            "volumeNumber": "241"
          }
        ], 
        "keywords": [
          "diffuse double layer model", 
          "sorption selectivity", 
          "surface complexation model", 
          "such multicomponent systems", 
          "double layer model", 
          "multicomponent systems", 
          "total carbonate concentration", 
          "complexation model", 
          "synthetic granitic water", 
          "separation factor", 
          "uranium sorption", 
          "equilibrium constants", 
          "carbonate concentration", 
          "selectivity", 
          "phase ratio", 
          "granitic water", 
          "layer model", 
          "numerical simulations", 
          "characteristic parameters", 
          "experimental data", 
          "sorption", 
          "simulations", 
          "bentonite", 
          "reaction", 
          "uranium", 
          "concentration", 
          "pH", 
          "water", 
          "constants", 
          "composition", 
          "system", 
          "phase", 
          "modelling", 
          "model", 
          "parameters", 
          "ratio", 
          "components", 
          "values", 
          "description", 
          "data", 
          "factors", 
          "relation", 
          "Czech sodium bentonite SABENYL", 
          "sodium bentonite SABENYL", 
          "bentonite SABENYL", 
          "SABENYL"
        ], 
        "name": "Modelling and simulation of sorption selectivity in the bentonite-HCO3\u2212\u2212CO32\u2212\u2212233U(VI) species system", 
        "pagination": "487-492", 
        "productId": [
          {
            "name": "dimensions_id", 
            "type": "PropertyValue", 
            "value": [
              "pub.1053477281"
            ]
          }, 
          {
            "name": "doi", 
            "type": "PropertyValue", 
            "value": [
              "10.1007/bf02347202"
            ]
          }
        ], 
        "sameAs": [
          "https://doi.org/10.1007/bf02347202", 
          "https://app.dimensions.ai/details/publication/pub.1053477281"
        ], 
        "sdDataset": "articles", 
        "sdDatePublished": "2021-11-01T18:03", 
        "sdLicense": "https://scigraph.springernature.com/explorer/license/", 
        "sdPublisher": {
          "name": "Springer Nature - SN SciGraph project", 
          "type": "Organization"
        }, 
        "sdSource": "s3://com-springernature-scigraph/baseset/20211101/entities/gbq_results/article/article_330.jsonl", 
        "type": "ScholarlyArticle", 
        "url": "https://doi.org/10.1007/bf02347202"
      }
    ]
     

    Download the RDF metadata as:  json-ld nt turtle xml License info

    HOW TO GET THIS DATA PROGRAMMATICALLY:

    JSON-LD is a popular format for linked data which is fully compatible with JSON.

    curl -H 'Accept: application/ld+json' 'https://scigraph.springernature.com/pub.10.1007/bf02347202'

    N-Triples is a line-based linked data format ideal for batch operations.

    curl -H 'Accept: application/n-triples' 'https://scigraph.springernature.com/pub.10.1007/bf02347202'

    Turtle is a human-readable linked data format.

    curl -H 'Accept: text/turtle' 'https://scigraph.springernature.com/pub.10.1007/bf02347202'

    RDF/XML is a standard XML format for linked data.

    curl -H 'Accept: application/rdf+xml' 'https://scigraph.springernature.com/pub.10.1007/bf02347202'


     

    This table displays all metadata directly associated to this object as RDF triples.

    136 TRIPLES      22 PREDICATES      73 URIs      64 LITERALS      6 BLANK NODES

    Subject Predicate Object
    1 sg:pub.10.1007/bf02347202 schema:about anzsrc-for:03
    2 anzsrc-for:0306
    3 schema:author Naf6260e7b2724ecc9d0667e8d9235a80
    4 schema:citation sg:pub.10.1007/978-94-009-5161-7_24
    5 schema:datePublished 1999-09
    6 schema:datePublishedReg 1999-09-01
    7 schema:description A surface complexation model, the so-called diffuse double layer model (DLM), was used in the description of the multicomponent system consisting of Czech sodium bentonite SABENYL and synthetic granitic water spiked with233U(VI). The experimental data were evaluated and the characteristic parameters, e.g., the equilibrium constants of all the reactions considered, were obtained and used for the numerical simulation of sorption selectivity of the uranium in relation to the total carbonate concentration. The values of separation factors indicate that the selectivity of uranium sorption in such multicomponent systems can depend not only on the pH and composition of both phases, but also on the phase ratio and starting concentrations of participating components.
    8 schema:genre article
    9 schema:inLanguage en
    10 schema:isAccessibleForFree false
    11 schema:isPartOf N60707d91cfac4f9e80bdd62937543d20
    12 N6fabebe50808417aac7776df7ddb1cd5
    13 sg:journal.1094634
    14 schema:keywords Czech sodium bentonite SABENYL
    15 SABENYL
    16 bentonite
    17 bentonite SABENYL
    18 carbonate concentration
    19 characteristic parameters
    20 complexation model
    21 components
    22 composition
    23 concentration
    24 constants
    25 data
    26 description
    27 diffuse double layer model
    28 double layer model
    29 equilibrium constants
    30 experimental data
    31 factors
    32 granitic water
    33 layer model
    34 model
    35 modelling
    36 multicomponent systems
    37 numerical simulations
    38 pH
    39 parameters
    40 phase
    41 phase ratio
    42 ratio
    43 reaction
    44 relation
    45 selectivity
    46 separation factor
    47 simulations
    48 sodium bentonite SABENYL
    49 sorption
    50 sorption selectivity
    51 such multicomponent systems
    52 surface complexation model
    53 synthetic granitic water
    54 system
    55 total carbonate concentration
    56 uranium
    57 uranium sorption
    58 values
    59 water
    60 schema:name Modelling and simulation of sorption selectivity in the bentonite-HCO3−−CO32−−233U(VI) species system
    61 schema:pagination 487-492
    62 schema:productId N2fb36df0f99442f0aa2749d58992fead
    63 Nc3daf40b4aa24e7b82f6b5eb41475585
    64 schema:sameAs https://app.dimensions.ai/details/publication/pub.1053477281
    65 https://doi.org/10.1007/bf02347202
    66 schema:sdDatePublished 2021-11-01T18:03
    67 schema:sdLicense https://scigraph.springernature.com/explorer/license/
    68 schema:sdPublisher Nbf8b647b83c8403197a0f35a55ce58bc
    69 schema:url https://doi.org/10.1007/bf02347202
    70 sgo:license sg:explorer/license/
    71 sgo:sdDataset articles
    72 rdf:type schema:ScholarlyArticle
    73 N2c99c1a1826c4e09b2315ee4df72984a rdf:first sg:person.015261101333.52
    74 rdf:rest N8059a8bc526640229a7e3da9f07fc3c0
    75 N2fb36df0f99442f0aa2749d58992fead schema:name dimensions_id
    76 schema:value pub.1053477281
    77 rdf:type schema:PropertyValue
    78 N60707d91cfac4f9e80bdd62937543d20 schema:issueNumber 3
    79 rdf:type schema:PublicationIssue
    80 N6fabebe50808417aac7776df7ddb1cd5 schema:volumeNumber 241
    81 rdf:type schema:PublicationVolume
    82 N8059a8bc526640229a7e3da9f07fc3c0 rdf:first sg:person.012651030553.25
    83 rdf:rest rdf:nil
    84 Na4df33ecc83242f6abee06bae1a4b3f1 rdf:first sg:person.01237712015.74
    85 rdf:rest N2c99c1a1826c4e09b2315ee4df72984a
    86 Naf6260e7b2724ecc9d0667e8d9235a80 rdf:first sg:person.013724421353.14
    87 rdf:rest Necdfc4e9b1e74a65a5041376ef36cd99
    88 Nbf8b647b83c8403197a0f35a55ce58bc schema:name Springer Nature - SN SciGraph project
    89 rdf:type schema:Organization
    90 Nc3daf40b4aa24e7b82f6b5eb41475585 schema:name doi
    91 schema:value 10.1007/bf02347202
    92 rdf:type schema:PropertyValue
    93 Necdfc4e9b1e74a65a5041376ef36cd99 rdf:first sg:person.012273177333.01
    94 rdf:rest Na4df33ecc83242f6abee06bae1a4b3f1
    95 anzsrc-for:03 schema:inDefinedTermSet anzsrc-for:
    96 schema:name Chemical Sciences
    97 rdf:type schema:DefinedTerm
    98 anzsrc-for:0306 schema:inDefinedTermSet anzsrc-for:
    99 schema:name Physical Chemistry (incl. Structural)
    100 rdf:type schema:DefinedTerm
    101 sg:journal.1094634 schema:issn 0236-5731
    102 1588-2780
    103 schema:name Journal of Radioanalytical and Nuclear Chemistry
    104 schema:publisher Springer Nature
    105 rdf:type schema:Periodical
    106 sg:person.012273177333.01 schema:affiliation grid-institutes:grid.6652.7
    107 schema:familyName Škrkal
    108 schema:givenName J.
    109 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.012273177333.01
    110 rdf:type schema:Person
    111 sg:person.01237712015.74 schema:affiliation grid-institutes:grid.6652.7
    112 schema:familyName Beneš
    113 schema:givenName P.
    114 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01237712015.74
    115 rdf:type schema:Person
    116 sg:person.012651030553.25 schema:affiliation grid-institutes:grid.6652.7
    117 schema:familyName Vopálka
    118 schema:givenName D.
    119 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.012651030553.25
    120 rdf:type schema:Person
    121 sg:person.013724421353.14 schema:affiliation grid-institutes:grid.6652.7
    122 schema:familyName Štamberg
    123 schema:givenName K.
    124 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.013724421353.14
    125 rdf:type schema:Person
    126 sg:person.015261101333.52 schema:affiliation grid-institutes:grid.6652.7
    127 schema:familyName Chalupská
    128 schema:givenName K.
    129 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.015261101333.52
    130 rdf:type schema:Person
    131 sg:pub.10.1007/978-94-009-5161-7_24 schema:sameAs https://app.dimensions.ai/details/publication/pub.1003916858
    132 https://doi.org/10.1007/978-94-009-5161-7_24
    133 rdf:type schema:CreativeWork
    134 grid-institutes:grid.6652.7 schema:alternateName Faculty of Nuclear Science and Physical Engineering, Department of Nuclear Chemistry, Czech Technical University, Břehová 7, 11519, Praha 1, Czech Republic
    135 schema:name Faculty of Nuclear Science and Physical Engineering, Department of Nuclear Chemistry, Czech Technical University, Břehová 7, 11519, Praha 1, Czech Republic
    136 rdf:type schema:Organization
     




    Preview window. Press ESC to close (or click here)


    ...