TDPAC study of the thermal evolution of the quadrupole parameters in NiTiF6·6H2O between 30 and 400 K View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

1993-12

AUTHORS

M. Ceolín, M. A. Taylor, J. A. Martínez, A. M. Rodriguez, H. Saitovitch, P. R. J. Silva

ABSTRACT

The thermal evolution of the quadrupole parameters determined using the time differential perturbed angular correlation technique at titanium sites, in NiTiF6·6H2O is presented. The study of the thermal behavior of the hyperfine quadrupole interaction allows one to observe the occurrence of a structural phase transition around 140 K. The thermal evolution of the hyperfine quadrupole frequency of the high temperature phase was interpreted in terms of the flip motion of the water molecules through an ad hoc model. Parameters associated with the model are in good agreement with independent data obtained by Raman scattering. The agreement gives support to the model to be a valuable tool to study the dynamics of molecular groups in crystalline hydrates. More... »

PAGES

307-314

References to SciGraph publications

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/bf02320320

DOI

http://dx.doi.org/10.1007/bf02320320

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1031519174


Indexing Status Check whether this publication has been indexed by Scopus and Web Of Science using the SN Indexing Status Tool
Incoming Citations Browse incoming citations for this publication using opencitations.net

JSON-LD is the canonical representation for SciGraph data.

TIP: You can open this SciGraph record using an external JSON-LD service: JSON-LD Playground Google SDTT

[
  {
    "@context": "https://springernature.github.io/scigraph/jsonld/sgcontext.json", 
    "about": [
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/0299", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Other Physical Sciences", 
        "type": "DefinedTerm"
      }, 
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/02", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Physical Sciences", 
        "type": "DefinedTerm"
      }
    ], 
    "author": [
      {
        "affiliation": {
          "alternateName": "National University of La Plata", 
          "id": "https://www.grid.ac/institutes/grid.9499.d", 
          "name": [
            "Departamento de F\u00edsica, Universidad Nacional de La Plata, CC67 (1900), La Plata, Argentina"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Ceol\u00edn", 
        "givenName": "M.", 
        "id": "sg:person.0632521167.48", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.0632521167.48"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "National University of La Plata", 
          "id": "https://www.grid.ac/institutes/grid.9499.d", 
          "name": [
            "Departamento de F\u00edsica, Universidad Nacional de La Plata, CC67 (1900), La Plata, Argentina"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Taylor", 
        "givenName": "M. A.", 
        "id": "sg:person.012102172515.75", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.012102172515.75"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Comisi\u00f3n de Investigaciones Cient\u00edficas", 
          "id": "https://www.grid.ac/institutes/grid.452362.4", 
          "name": [
            "Departamento de F\u00edsica, Universidad Nacional de La Plata, CC67 (1900), La Plata, Argentina", 
            "CICPBA, Argentina"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Mart\u00ednez", 
        "givenName": "J. A.", 
        "id": "sg:person.015745323505.02", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.015745323505.02"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "National Scientific and Technical Research Council", 
          "id": "https://www.grid.ac/institutes/grid.423606.5", 
          "name": [
            "Departamento de F\u00edsica, Universidad Nacional de La Plata, CC67 (1900), La Plata, Argentina", 
            "CONICET, Argentina"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Rodriguez", 
        "givenName": "A. M.", 
        "id": "sg:person.012411010031.65", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.012411010031.65"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Centro Brasileiro de Pesquisas F\u00edsicas", 
          "id": "https://www.grid.ac/institutes/grid.418228.5", 
          "name": [
            "Centro Brasileiro de Pesquisas Fisicas, Rua Xavier Sigaud 150, 22290, Rio de Janeiro, Brazil"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Saitovitch", 
        "givenName": "H.", 
        "id": "sg:person.011665640415.04", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.011665640415.04"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Centro Brasileiro de Pesquisas F\u00edsicas", 
          "id": "https://www.grid.ac/institutes/grid.418228.5", 
          "name": [
            "Centro Brasileiro de Pesquisas Fisicas, Rua Xavier Sigaud 150, 22290, Rio de Janeiro, Brazil"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Silva", 
        "givenName": "P. R. J.", 
        "id": "sg:person.010650333325.52", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.010650333325.52"
        ], 
        "type": "Person"
      }
    ], 
    "citation": [
      {
        "id": "https://doi.org/10.1016/0022-4596(89)90105-9", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1006461159"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/0584-8539(81)80132-8", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1016594305"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1007/bf01337696", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1028147274", 
          "https://doi.org/10.1007/bf01337696"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1002/jrs.1250110103", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1038341339"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1107/s056774087300748x", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1052948403"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1063/1.1679102", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1057755187"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1063/1.432624", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1058010656"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1063/1.444722", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1058022744"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1103/physrev.104.1364", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1060418093"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1103/physrev.104.1364", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1060418093"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1103/physrevb.35.6619", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1060542740"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1103/physrevb.35.6619", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1060542740"
        ], 
        "type": "CreativeWork"
      }
    ], 
    "datePublished": "1993-12", 
    "datePublishedReg": "1993-12-01", 
    "description": "The thermal evolution of the quadrupole parameters determined using the time differential perturbed angular correlation technique at titanium sites, in NiTiF6\u00b76H2O is presented. The study of the thermal behavior of the hyperfine quadrupole interaction allows one to observe the occurrence of a structural phase transition around 140 K. The thermal evolution of the hyperfine quadrupole frequency of the high temperature phase was interpreted in terms of the flip motion of the water molecules through an ad hoc model. Parameters associated with the model are in good agreement with independent data obtained by Raman scattering. The agreement gives support to the model to be a valuable tool to study the dynamics of molecular groups in crystalline hydrates.", 
    "genre": "research_article", 
    "id": "sg:pub.10.1007/bf02320320", 
    "inLanguage": [
      "en"
    ], 
    "isAccessibleForFree": false, 
    "isPartOf": [
      {
        "id": "sg:journal.1038685", 
        "issn": [
          "0304-3843", 
          "1572-9540"
        ], 
        "name": "Hyperfine Interactions", 
        "type": "Periodical"
      }, 
      {
        "issueNumber": "1", 
        "type": "PublicationIssue"
      }, 
      {
        "type": "PublicationVolume", 
        "volumeNumber": "77"
      }
    ], 
    "name": "TDPAC study of the thermal evolution of the quadrupole parameters in NiTiF6\u00b76H2O between 30 and 400 K", 
    "pagination": "307-314", 
    "productId": [
      {
        "name": "readcube_id", 
        "type": "PropertyValue", 
        "value": [
          "9626ca2955a525ae5ebd613cf4b140fb30d59fbb4a854375143a43f4f6a80b87"
        ]
      }, 
      {
        "name": "doi", 
        "type": "PropertyValue", 
        "value": [
          "10.1007/bf02320320"
        ]
      }, 
      {
        "name": "dimensions_id", 
        "type": "PropertyValue", 
        "value": [
          "pub.1031519174"
        ]
      }
    ], 
    "sameAs": [
      "https://doi.org/10.1007/bf02320320", 
      "https://app.dimensions.ai/details/publication/pub.1031519174"
    ], 
    "sdDataset": "articles", 
    "sdDatePublished": "2019-04-11T12:52", 
    "sdLicense": "https://scigraph.springernature.com/explorer/license/", 
    "sdPublisher": {
      "name": "Springer Nature - SN SciGraph project", 
      "type": "Organization"
    }, 
    "sdSource": "s3://com-uberresearch-data-dimensions-target-20181106-alternative/cleanup/v134/2549eaecd7973599484d7c17b260dba0a4ecb94b/merge/v9/a6c9fde33151104705d4d7ff012ea9563521a3ce/jats-lookup/v90/0000000364_0000000364/records_72834_00000000.jsonl", 
    "type": "ScholarlyArticle", 
    "url": "http://link.springer.com/10.1007%2FBF02320320"
  }
]
 

Download the RDF metadata as:  json-ld nt turtle xml License info

HOW TO GET THIS DATA PROGRAMMATICALLY:

JSON-LD is a popular format for linked data which is fully compatible with JSON.

curl -H 'Accept: application/ld+json' 'https://scigraph.springernature.com/pub.10.1007/bf02320320'

N-Triples is a line-based linked data format ideal for batch operations.

curl -H 'Accept: application/n-triples' 'https://scigraph.springernature.com/pub.10.1007/bf02320320'

Turtle is a human-readable linked data format.

curl -H 'Accept: text/turtle' 'https://scigraph.springernature.com/pub.10.1007/bf02320320'

RDF/XML is a standard XML format for linked data.

curl -H 'Accept: application/rdf+xml' 'https://scigraph.springernature.com/pub.10.1007/bf02320320'


 

This table displays all metadata directly associated to this object as RDF triples.

138 TRIPLES      21 PREDICATES      37 URIs      19 LITERALS      7 BLANK NODES

Subject Predicate Object
1 sg:pub.10.1007/bf02320320 schema:about anzsrc-for:02
2 anzsrc-for:0299
3 schema:author N6e4c86f28c834371a364b6689ba29f61
4 schema:citation sg:pub.10.1007/bf01337696
5 https://doi.org/10.1002/jrs.1250110103
6 https://doi.org/10.1016/0022-4596(89)90105-9
7 https://doi.org/10.1016/0584-8539(81)80132-8
8 https://doi.org/10.1063/1.1679102
9 https://doi.org/10.1063/1.432624
10 https://doi.org/10.1063/1.444722
11 https://doi.org/10.1103/physrev.104.1364
12 https://doi.org/10.1103/physrevb.35.6619
13 https://doi.org/10.1107/s056774087300748x
14 schema:datePublished 1993-12
15 schema:datePublishedReg 1993-12-01
16 schema:description The thermal evolution of the quadrupole parameters determined using the time differential perturbed angular correlation technique at titanium sites, in NiTiF6·6H2O is presented. The study of the thermal behavior of the hyperfine quadrupole interaction allows one to observe the occurrence of a structural phase transition around 140 K. The thermal evolution of the hyperfine quadrupole frequency of the high temperature phase was interpreted in terms of the flip motion of the water molecules through an ad hoc model. Parameters associated with the model are in good agreement with independent data obtained by Raman scattering. The agreement gives support to the model to be a valuable tool to study the dynamics of molecular groups in crystalline hydrates.
17 schema:genre research_article
18 schema:inLanguage en
19 schema:isAccessibleForFree false
20 schema:isPartOf Ncde2d6d5565a4282b27ba1e68d40cbbf
21 Nd5a3925ba0fa423a854d9394e33c0d7c
22 sg:journal.1038685
23 schema:name TDPAC study of the thermal evolution of the quadrupole parameters in NiTiF6·6H2O between 30 and 400 K
24 schema:pagination 307-314
25 schema:productId N00017e284f074339a19c565bead4cbf3
26 N5cbb60b7dbcf411eb57e1d5708354601
27 N8b1a36c3e64a49188a8559f99d8929e7
28 schema:sameAs https://app.dimensions.ai/details/publication/pub.1031519174
29 https://doi.org/10.1007/bf02320320
30 schema:sdDatePublished 2019-04-11T12:52
31 schema:sdLicense https://scigraph.springernature.com/explorer/license/
32 schema:sdPublisher N13f892a5f26141f98d9387b7f0cdbfa3
33 schema:url http://link.springer.com/10.1007%2FBF02320320
34 sgo:license sg:explorer/license/
35 sgo:sdDataset articles
36 rdf:type schema:ScholarlyArticle
37 N00017e284f074339a19c565bead4cbf3 schema:name dimensions_id
38 schema:value pub.1031519174
39 rdf:type schema:PropertyValue
40 N000807610da440e3a8ddeab436ff18a2 rdf:first sg:person.015745323505.02
41 rdf:rest N22f7c416b2df4567a599dd6cc237c58c
42 N13f892a5f26141f98d9387b7f0cdbfa3 schema:name Springer Nature - SN SciGraph project
43 rdf:type schema:Organization
44 N177c5255fdd74e589fee07abdfeb8100 rdf:first sg:person.012102172515.75
45 rdf:rest N000807610da440e3a8ddeab436ff18a2
46 N22f7c416b2df4567a599dd6cc237c58c rdf:first sg:person.012411010031.65
47 rdf:rest Nc2a7cd0edc8e4f1ca0e9fda53029ba57
48 N5cbb60b7dbcf411eb57e1d5708354601 schema:name doi
49 schema:value 10.1007/bf02320320
50 rdf:type schema:PropertyValue
51 N6e4c86f28c834371a364b6689ba29f61 rdf:first sg:person.0632521167.48
52 rdf:rest N177c5255fdd74e589fee07abdfeb8100
53 N80d07e0bf90945efbda16d129bbc1029 rdf:first sg:person.010650333325.52
54 rdf:rest rdf:nil
55 N8b1a36c3e64a49188a8559f99d8929e7 schema:name readcube_id
56 schema:value 9626ca2955a525ae5ebd613cf4b140fb30d59fbb4a854375143a43f4f6a80b87
57 rdf:type schema:PropertyValue
58 Nc2a7cd0edc8e4f1ca0e9fda53029ba57 rdf:first sg:person.011665640415.04
59 rdf:rest N80d07e0bf90945efbda16d129bbc1029
60 Ncde2d6d5565a4282b27ba1e68d40cbbf schema:volumeNumber 77
61 rdf:type schema:PublicationVolume
62 Nd5a3925ba0fa423a854d9394e33c0d7c schema:issueNumber 1
63 rdf:type schema:PublicationIssue
64 anzsrc-for:02 schema:inDefinedTermSet anzsrc-for:
65 schema:name Physical Sciences
66 rdf:type schema:DefinedTerm
67 anzsrc-for:0299 schema:inDefinedTermSet anzsrc-for:
68 schema:name Other Physical Sciences
69 rdf:type schema:DefinedTerm
70 sg:journal.1038685 schema:issn 0304-3843
71 1572-9540
72 schema:name Hyperfine Interactions
73 rdf:type schema:Periodical
74 sg:person.010650333325.52 schema:affiliation https://www.grid.ac/institutes/grid.418228.5
75 schema:familyName Silva
76 schema:givenName P. R. J.
77 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.010650333325.52
78 rdf:type schema:Person
79 sg:person.011665640415.04 schema:affiliation https://www.grid.ac/institutes/grid.418228.5
80 schema:familyName Saitovitch
81 schema:givenName H.
82 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.011665640415.04
83 rdf:type schema:Person
84 sg:person.012102172515.75 schema:affiliation https://www.grid.ac/institutes/grid.9499.d
85 schema:familyName Taylor
86 schema:givenName M. A.
87 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.012102172515.75
88 rdf:type schema:Person
89 sg:person.012411010031.65 schema:affiliation https://www.grid.ac/institutes/grid.423606.5
90 schema:familyName Rodriguez
91 schema:givenName A. M.
92 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.012411010031.65
93 rdf:type schema:Person
94 sg:person.015745323505.02 schema:affiliation https://www.grid.ac/institutes/grid.452362.4
95 schema:familyName Martínez
96 schema:givenName J. A.
97 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.015745323505.02
98 rdf:type schema:Person
99 sg:person.0632521167.48 schema:affiliation https://www.grid.ac/institutes/grid.9499.d
100 schema:familyName Ceolín
101 schema:givenName M.
102 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.0632521167.48
103 rdf:type schema:Person
104 sg:pub.10.1007/bf01337696 schema:sameAs https://app.dimensions.ai/details/publication/pub.1028147274
105 https://doi.org/10.1007/bf01337696
106 rdf:type schema:CreativeWork
107 https://doi.org/10.1002/jrs.1250110103 schema:sameAs https://app.dimensions.ai/details/publication/pub.1038341339
108 rdf:type schema:CreativeWork
109 https://doi.org/10.1016/0022-4596(89)90105-9 schema:sameAs https://app.dimensions.ai/details/publication/pub.1006461159
110 rdf:type schema:CreativeWork
111 https://doi.org/10.1016/0584-8539(81)80132-8 schema:sameAs https://app.dimensions.ai/details/publication/pub.1016594305
112 rdf:type schema:CreativeWork
113 https://doi.org/10.1063/1.1679102 schema:sameAs https://app.dimensions.ai/details/publication/pub.1057755187
114 rdf:type schema:CreativeWork
115 https://doi.org/10.1063/1.432624 schema:sameAs https://app.dimensions.ai/details/publication/pub.1058010656
116 rdf:type schema:CreativeWork
117 https://doi.org/10.1063/1.444722 schema:sameAs https://app.dimensions.ai/details/publication/pub.1058022744
118 rdf:type schema:CreativeWork
119 https://doi.org/10.1103/physrev.104.1364 schema:sameAs https://app.dimensions.ai/details/publication/pub.1060418093
120 rdf:type schema:CreativeWork
121 https://doi.org/10.1103/physrevb.35.6619 schema:sameAs https://app.dimensions.ai/details/publication/pub.1060542740
122 rdf:type schema:CreativeWork
123 https://doi.org/10.1107/s056774087300748x schema:sameAs https://app.dimensions.ai/details/publication/pub.1052948403
124 rdf:type schema:CreativeWork
125 https://www.grid.ac/institutes/grid.418228.5 schema:alternateName Centro Brasileiro de Pesquisas Físicas
126 schema:name Centro Brasileiro de Pesquisas Fisicas, Rua Xavier Sigaud 150, 22290, Rio de Janeiro, Brazil
127 rdf:type schema:Organization
128 https://www.grid.ac/institutes/grid.423606.5 schema:alternateName National Scientific and Technical Research Council
129 schema:name CONICET, Argentina
130 Departamento de Física, Universidad Nacional de La Plata, CC67 (1900), La Plata, Argentina
131 rdf:type schema:Organization
132 https://www.grid.ac/institutes/grid.452362.4 schema:alternateName Comisión de Investigaciones Científicas
133 schema:name CICPBA, Argentina
134 Departamento de Física, Universidad Nacional de La Plata, CC67 (1900), La Plata, Argentina
135 rdf:type schema:Organization
136 https://www.grid.ac/institutes/grid.9499.d schema:alternateName National University of La Plata
137 schema:name Departamento de Física, Universidad Nacional de La Plata, CC67 (1900), La Plata, Argentina
138 rdf:type schema:Organization
 




Preview window. Press ESC to close (or click here)


...